In situ oxygen uptake rates by coastal sediments under the influence of the Rhône River (NW Mediterranean Sea)     

Bruno Lansard  Christophe Rabouille  Lionel Denis  Christian Grenz 《Continental Shelf Research》2008

The influence of riverine inputs on biogeochemical cycling and organic matter recycling in sediments on the continental shelf off the Rhône River mouth (NW Mediterranean Sea) was investigated by measuring sediment oxygen uptake rates using a combination of in situ and laboratory techniques. Four stations were investigated during two cruises in June 2001 and June 2002, with depths ranging from 9 to 192 m and over a distance to the Rhône River mouth ranging from 4 to 36 km. Diffusive oxygen uptake (DOU) rates were determined using an in situ sediment microprofiler and total oxygen uptake (TOU) rates were measured using sediment core incubations. There was good agreement between these two techniques which indicates that the non-diffusive fraction of the oxygen flux was minimal at the investigated stations. DOU rates ranged from 3.7±0.4 mmol O₂ m⁻² d⁻¹ at the continental shelf break to 19.3±0.5 mmol O₂ m⁻² d⁻¹ in front of the Rhône River mouth. Sediment oxygen uptake rates mostly decreased with increasing depth and with distance from the Rhône mouth. The highest oxygen uptake rate was observed at 63 m on the Rhône prodelta, corresponding to intense remineralization of organic matter. This oxygen uptake rate was much larger than expected for the increasing bathymetry, which indicates that biogeochemical cycles and benthic deposition are largely influenced by the Rhône River inputs. This functioning was also supported by the detailed spatial distribution of total organic carbon (TOC), total nitrogen (TN) and C/N atomic ratio in surficial sediments. Sediments of the Rhône prodelta are enriched in organic carbon (2–2.2%) relative to the continental shelf sediments (<1%) and showed C/N ratios exceeding Redfield stoichiometry for fresh marine organic matter. A positive exponential correlation was found between DOU and TOC contents (r²=0.98, n=4). South-westward of the Rhône River mouth, sediments contained highly degraded organic matter of both terrestrial and marine origin, due to direct inputs from the Rhône River, sedimentation of marine organic matter and organic material redeposition after resuspension events.  相似文献   

In situ and high frequency monitoring of suspended sediment properties using a spectrophotometric sensor          下载免费PDF全文

Núria Martínez‐Carreras  Michael P. Schwab  Julian Klaus  Christophe Hissler 《水文研究》2016,30(19):3533-3540

It is well known that sediment properties, including sediment‐associated chemical constituents and sediment physical properties, can exhibit significant variations within and between storm runoff events. However, the number of samples included in suspended sediment studies is often limited by time‐consuming and expensive laboratory procedures after stream water sampling. This restricts high frequency sampling campaigns to a limited number of events and reduces accuracy when aiming to estimate fluxes and loads of sediment‐associated chemical constituents. In this study, we address the potential of a portable ultraviolet–visible spectrophotometer (220–730 nm) to estimate suspended sediment properties in a resource efficient way. Several field deployable spectrophotometers are currently available for in‐stream measurements of environmental variables at high temporal resolution. These instruments have primarily been developed and used to quantify solute concentrations (e.g. dissolved organic carbon and NO₃‐N), total concentrations of dissolved and particulate forms (e.g. total organic carbon) and turbidity. Here we argue that light absorbance values can be calibrated to estimate sediment properties. We present light absorbance data collected at 15‐min intervals in the Weierbach catchment (NW Luxembourg, 0.45 km²) from December 2013 to January 2015. In this proof‐of‐concept study, we performed a local calibration using suspended sediment loss‐on‐ignition (LOI) measurements as an example of suspended sediment property. We assessed the performance of several regression models that relate light absorbance measurements with the percentage weight LOI. The MM‐robust regression method presented the lowest standard error of prediction (0.48%) and was selected for calibration (adjusted r² = 0.76 between observed and predicted values). The model was then used to predict LOI during a storm runoff event in December 2014. This study demonstrates that spectrophotometers can be used to estimate suspended sediment properties at high temporal resolution and for long‐time spans in a simple, non‐destructive and affordable manner. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

Sedimentation,tectonism and volcanism relationships in two Andean basins of southern Peru     

René Marocco  Christophe Noblet 《International Journal of Earth Sciences》1990,79(1):111-120

The intermontane basins of the Central Andes, formed from the first episode of the andine tectonic (peruvian phase, Santonian), are characterized by a clastic continental sedimentation, settled in a compressive tectonic context and containing volcanic intercalations. The two basins presented in this paper, have distinct ages and a different geodynamic context, each:

1. The Cuzco-Sicuam Basin, Maestrichtian-Paleocene in age, is a back-arc basin. A coarse grained red bed sedimentation appeared at the same time as the synsedimentary tectonic and volcanic activity increased in the source area.
2. The Moquegua Basin, Oligocene in age, is a fore-arc basin. After a compressive phase, the northeastern border of the basin shows high mobility, characterized by superposed alluvial fans. Within the basin, the coarse grained sediments are associated with volcanic tuffs.

In the two basins, the tectonism, the volcanism and the coarse grained sedimentation occured simultaneously. The coarse grained sedimentation does not appear to be linked with climatic changes, but with the increasing mobility of the source area. The relationship between tectonic regime and volcanic activity in the basin and in the source area is considered.  相似文献   

Fe(II)-Na(I)-Ca(II) Cation Exchange on Montmorillonite in Chloride Medium: Evidence for Preferential Clay Adsorption of Chloride – Metal Ion Pairs in Seawater     

Laurent?Charlet  Christophe?TournassatEmail author 《Aquatic Geochemistry》2005,11(2):115-137

Fe(II)–Ca(II), Fe(II)–Na(I), and Fe(II)–Ca(II)–Na(I) exchange experiments on montmorillonite were performed in chloride background. These experiments show the possible sorption of Fe²⁺ and FeCl⁺ ion pairs in exchange site positions, a result confirmed with 77 K ⁵⁷Fe Mössbauer experiments. The sorption data were modeled and the cation exchange selectivity for Fe(II) were found to be nearly equal to that of Ca(II). Vanselow selectivity coefficients, for Na–Fe²⁺ and Na–FeCl⁺ reactions, were found to be equal to 0.4 (0.5 for Ca²⁺) and 2.3 (2.5 for CaCl⁺) respectively. High affinity of montmorillonite for chloride ion pairs seems to be a common mechanism as first stated by Sposito et al., (Soil Sci. Soc. Am. J. 47, 51–56, 1983a), and should have implications e.g., on the chemistry of suspended particles in seawater. Exchange selectivity coefficients derived from this study and others were used to model experimental data on river water and seawater equilibrated particles. The agreement between simulations and experimental data is very good. The simulation shows the predominance of monovalent ion (Na⁺ and chloride ion pairs) sorption on clay particles in seawater. This sorption of monovalent ions leads to the dispersion of particles in seawater and to the extension of a plume of particles spreading away from river deltas, such as that of the River Amazon.  相似文献   

Paramètres statistiques de la houle au large de la côte sud-aquitaine     

Stéphane Abadie  Rémi Butel  Hélène Dupuis  Christophe Brière 《Comptes Rendus Geoscience》2005,337(8):769-776

Statistical parameters of waves on the south Aquitaine coast have been determined by comparison of two datasets: in situ local measurements on a short duration and numerical simulation outputs from the WAVEWATCH III model over a period of 6 years and 9 months. Data and simulation results are well correlated in the case of the significant wave height, whereas in the case of the peak periods $(T_{\mathrm{p}})$ and directions $(D_{\mathrm{p}})$, this correlation is lower. This is due respectively to the intrinsic unstable nature of $T_{\mathrm{p}}$ and the narrow distribution of $D_{\mathrm{p}}$. An adjustment of simulation data on measurement is then used to give an evaluation of the wave statistics for the southern fraction of the French Atlantic coast. Eventually, the relationships between the three statistical variables $(H_{\mathrm{s}},T_{\mathrm{p}},D_{\mathrm{p}})$ are analysed in order to determine representative sea states. The classification obtained shows the predominance of swell regimes, distributed on a very narrow angular sector over wind sea regimes. To cite this article: S. Abadie et al., C. R. Geoscience 337 (2005).  相似文献   

Biological evidence of sea-level rise during the last 4500 years on the rocky coasts of continental southwestern France and Corsica     

Jacques Laborel  Christophe Morhange  Raymond Lafont  Joë  l Le Campion  Fran  oise Laborel-Deguen  Stephane Sartoretto 《Marine Geology》1994,120(3-4):203-223

On the rocky coasts of the northwestern Mediterranean basin, biogenic littoral rims built by the coralline rhodophyte Lithophyllum lichenoides develop, whose remains may be preserved for millennia when submerged in a rising sea environment. These remains can be used as biological indicators of recent sea-level variations. Our survey of the continental coasts of Var and Bouches du Rhône, west of Marseilles (southern France) and of northern Corsica shows that relative sea level rose about 1.6 m in the study area during the last 4500 years without exceeding the present datum. The rate of sea-level rise was 0.4 mm per year between 4500 and 1500 yr B.P. and slowed down to 0.2 mm per year from 1500 yr B.P. to present time. There are also morphological indications of an acceleration of the rate of sea-level rise during the last century, supporting the evidence of tide gauges. Regions at the periphery of the above zone (Alpes Maritimes, Italian border zone, and the French and Spanish Catalonia regions) were also surveyed, but a weaker development of Lithophyllum rims and bad preservation of algal remains led to unconvincing dates which could also be linked to regional tectonic trends.  相似文献   

Arctic salinity anomalies and their link to the North Atlantic during a positive phase of the Arctic Oscillation   总被引：1，自引：0，他引：1  

Marie-Noelle Houssais  Christophe Herbaut  Clément Rousset 《Progress in Oceanography》2007,73(2):160-189

Many of the changes observed during the last two decades in the Arctic Ocean and adjacent seas have been linked to the concomitant abrupt decrease of the sea level pressure in the central Arctic at the end of the 1980s. The decrease was associated with a shift of the Arctic Oscillation (AO) to a positive phase, which persisted throughout the mid 1990s. The Arctic salinity distribution is expected to respond to these dramatic changes via modifications in the ocean circulation and in the fresh water storage and transport by sea ice. The present study investigates these different contributions in the context of idealized ice-ocean experiments forced by atmospheric surface wind-stress or temperature anomalies representative of a positive AO index.Wind stress anomalies representative of a positive AO index generate a decrease of the fresh water content of the upper Arctic Ocean, which is mainly concentrated in the eastern Arctic with almost no compensation from the western Arctic. Sea ice contributes to about two-third of this salinification, another third being provided by an increased supply of salt by the Atlantic inflow and increased fresh water export through the Canadian Archipelago and Fram Strait. The signature of a saltier Atlantic Current in the Norwegian Sea is not found further north in both the Barents Sea and the Fram Strait branches of the Atlantic inflow where instead a widespread freshening is observed. The latter is the result of import of fresh anomalies from the subpolar North Atlantic through the Iceland-Scotland Passage and enhanced advection of low salinity waters via the East Icelandic Current. The volume of ice exported through Fram Strait increases by 20% primarily due to thicker ice advected into the strait from the northern Greenland sector, the increase of ice drift velocities having comparatively less influence. The export anomaly is comparable to those observed during events of Great Salinity Anomalies and induces substantial freshening in the Greenland Sea, which in turn contributes to increasing the fresh water export to the North Atlantic via Denmark Strait. With a fresh water export anomaly of 7 mSv, the latter is the main fresh water supplier to the subpolar North Atlantic, the Canadian Archipelago contributing to 4.4 mSv.The removal of fresh water by sea ice under a positive winter AO index mainly occurs through enhanced thin ice growth in the eastern Arctic. Winter SAT anomalies have little impact on the thermodynamic sea ice response, which is rather dictated by wind driven ice deformation changes. The global sea ice mass balance of the western Arctic indicates almost no net sea ice melt due to competing seasonal thermodynamic processes. The surface freshening and likely enhanced sea ice melt observed in the western Arctic during the 1990s should therefore be attributed to extra-winter atmospheric effects, such as the noticeable recent spring-summer warming in the Canada-Alaska sector, or to other modes of atmospheric circulations than the AO, especially in relation to the North Pacific variability.  相似文献   

The Wuqbah peridotite, central Oman Ophiolite: Petrological characteristics of the mantle in a fossil overlapping ridge setting   总被引：2，自引：0，他引：2  

Jacques Girardeau  Christophe Monnier  Laurent Lemée  Frédéric Quatrevaux 《Marine Geophysical Researches》2002,23(1):43-56

The Wuqbah peridotites (Wuqbah massif, central Oman Ophiolite) constitute the mantle part of a complete ophiolitic sequence and their field deformation geometry is thought to reflect mantle dynamics in a fossil overlapping ridge settings (Girardeau et al., 2002). These peridotites comprise dominantly residual harzburgites and dunites. Nearly 70% of the harzburgites are clinopyroxene-free, and the rest contains less than 1%. The mineral chemistry of olivine, pyroxenes and spinel, and whole rock major and rare-earth element data, indicate that the Wuqbah peridotites are all strongly refractory and that they record a major percolation event, marked by strong enrichments in incompatible elements. At the massif scale, the Central Zone contains rocks with the most refractory features (20% melt extraction), as expected in an area of mantle upwelling. In the overlapping ridge senario, it corresponds to the overlap zone whose formation is discussed.  相似文献   

Coastal boulder deposits attesting to large wave impacts on the Mediterranean coast of Egypt     

Majid Shah-Hosseini  Amr Saleem  Abdel-Moneim A. Mahmoud  Christophe Morhange 《Natural Hazards》2016,83(2):849-865

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The Eldgjá eruption: timing,long-range impacts and influence on the Christianisation of Iceland     

Clive Oppenheimer  Andy Orchard  Markus Stoffel  Timothy P. Newfield  Sébastien Guillet  Christophe Corona  Michael Sigl  Nicola Di Cosmo  Ulf Büntgen 《Climatic change》2018,147(3-4):369-381

The Eldgjá lava flood is considered Iceland’s largest volcanic eruption of the Common Era. While it is well established that it occurred after the Settlement of Iceland (circa 874 CE), the date of this great event has remained uncertain. This has hampered investigation of the eruption’s impacts, if any, on climate and society. Here, we use high-temporal resolution glaciochemical records from Greenland to show that the eruption began in spring 939 CE and continued, at least episodically, until at least autumn 940 CE. Contemporary chronicles identify the spread of a remarkable haze in 939 CE, and tree ring-based reconstructions reveal pronounced northern hemisphere summer cooling in 940 CE, consistent with the eruption’s high yield of sulphur to the atmosphere. Consecutive severe winters and privations may also be associated with climatic effects of the volcanic aerosol veil. Iceland’s formal conversion to Christianity dates to 999/1000 CE, within two generations or so of the Eldgjá eruption. The end of the pagan pantheon is foretold in Iceland’s renowned medieval poem, V?luspá (‘the prophecy of the seeress’). Several lines of the poem describe dramatic eruptive activity and attendant meteorological effects in an allusion to the fiery terminus of the pagan gods. We suggest that they draw on first-hand experiences of the Eldgjá eruption and that this retrospection of harrowing volcanic events in the poem was intentional, with the purpose of stimulating Iceland’s Christianisation over the latter half of the tenth century.  相似文献