Biomass Burning in Southern Africa: Individual Particle Characterization of Atmospheric Aerosols and Savanna Fire Samples   总被引：2，自引：0，他引：2  

Xiande Liu  Piet Van Espen  Freddy Adams  Jan Cafmeyer  Willy Maenhaut 《Journal of Atmospheric Chemistry》2000,36(2):135-155

Ambient atmospheric aerosols and savanna fireparticulate emission samples from southern Africa werecharacterised in terms of particle classes and theirnumber abundance by electron probe X-ray microanalysis(EPXMA). About ten particle classes were identifiedfor each sample. The major classes werealuminosilicates and sea salts for ambient coarse(2–10 m equivalent aerodynamic diameter (EAD))samples, and K-S and S-only particles for ambient fine(<2 m EAD) samples. The K-S particles are oneof the major products of biomass burning. The EPXMAresults were found to be consistent with the resultsfrom bulk analyses on a sample by sample basis. Forsavanna fire fine samples, quantitative EPXMA revealedthat many particles had a composition of simple saltssuch as KCl. Some particles had a deviatingcomposition in the sense that more ionic species wereinvolved in sustaining the balance between cations andanions, and they were composite or mixed salts.Because of extensive processing during the atmospherictransport, the composition of the K-S particles in theambient samples was different from K₂SO₄,and such particles were enriched with S. The finepyrogenic KCl particles and the fine sea-saltparticles were much depleted in chlorine.  相似文献   

Influence of wave groups on SSC patterns over vortex ripples     

Paul V. Villard  Philip D. Osborne  Christopher E. Vincent 《Continental Shelf Research》2000,20(17):1

Estimates of spatial and temporal variations in suspended sand concentrations (SSC) made with a multi-transducer Acoustic Backscatter Sensor (ABS) under a repeated wave group over a mobile rippled bed in the wave research flume at the National Hydraulics Laboratory in Ottawa, Canada, reveal an number of complex and intriguing patterns. Ensemble averages of 8 nearly identical wave groups provided much more robust estimates of SSC and allowed a detailed examination of the wave group effects. The largest SSC near the bed (< 0.10 m) occurs in phase with the largest waves in the group. Above approximately 0.10 m elevation, SSC lags behind the near bed SSC by as much as 2–3 waves; introducing significant curvature (on a semi-log plot) to the SSC profile. The log linear segments of the SSC profile grow and decay systematically on the scale of the wave group. The range in lengths of log-linear profile segments ( 0.03–0.355 m) suggest that the boundary layer thickness also fluctuates throughout the passage of the wave group. Furthermore, there are significant variations in the patterns of SSC, which occur under the largest and smallest waves in the group. Under the largest waves vertical bands of alternating high and low SSC produce an intra-wave modulation in the upper water column ( 0.075–0.30 m). The equivalent horizontal excursion of these bands scales to the ripple length. Under the smaller waves the intra-wave modulation of the SSC disappears and is replaced by temporally homogenous suspension that expands vertically through several individual wave cycles. The former pattern of homogenous suspension appears to be associated with growth of a boundary layer due to the persistent uni-directional horizontal flow during this part of the group together with the persistence of antecedent bed generated turbulence and vorticity which maintains the suspension. The latter pattern of bands of high and low SSC indicates a strong temporal and spatial constraint on the SSC (phase coupling) induced by the presence of the bedforms which may be enhanced by strong reversals in both flow and vorticity under the large waves in the group.  相似文献   

Remineralization Ratios in the Subtropical North Pacific Gyre   总被引：2，自引：0，他引：2  

Yuan-Hui Li  David M. Karl  Christopher D. Winn  Fred T. Mackenzie  Kathleen Gans 《Aquatic Geochemistry》2000,6(1):65-85

Based on a new mixing model of two end-members, the water column remineralization ratios of P/N/C_org - O₂ = 1/13 ± 1/135 ± 18/170 ± 9 are obtained for the Hawaii Ocean Time-series (HOT) data set at station ALOHA. The traditional Redfield ratios of P/N/C_org/–O₂ = 1/16/106/138 have standard deviations of more than 50%, when they are based on the average composition of phytoplankton. Apparently, the remineralization processes in the water column have smoothed out the observed large variability of plankton compositions. A new molar formula for the remineralized plankton may be written as ₁₃₅H₂₈₀O₁₀₅N₁₃P or C₂₅(CH₂O)₁₀₁(CH₄)₉(NH₃)₁₃(H₃PO₄). Oxidation of this formula results inC₂₅(CH₂O)₁₀₁(CH₄)₉(NH₃)₁₃(H₃PO₄) + 170O₂ 135CO₂ + 132H₂O + 13NO₃ ^- + H₂PO₄ ^- + 14H⁺.For comparison, remineralization using Redfield's formula gives:(CH₂O)₁₀₆(NH₃)₁₆(H₃PO₄) + 138O₂ 106CO₂ + 122H₂O + 16NO₃ ^-+ H₂PO₄ ^- + 17H⁺  相似文献   

Application of Six Sigma Methods for Improving the Analytical Data Management Process in the Environmental Industry     

Christopher M. French  Neno Duplancic 《Ground Water Monitoring & Remediation》2006,26(2):58-61

  相似文献   

Seismogenic destruction of the Kamenka medieval fortress, northern Issyk-Kul region, Tien Shan (Kyrgyzstan)     

Andrey M. Korjenkov  J. Ramon Arrowsmith  Christopher Crosby  Ernes Mamyrov  Lyubov A. Orlova  Irina E. Povolotskaya  Kubatbek Tabaldiev 《Journal of Seismology》2006,10(4):431-442

A paleoseismological study of the medieval Kamenka fortress in the northern part of the Issyk-Kul Lake depression, northern Tien Shan in Kyrgyzstan, revealed an oblique slip thrust fault scarp offsetting the fortification walls. This 700 m long scarp is not related to the 1911 Kebin Earthquake (Ms 8.2) fault scarps which are widespread in the region. As analysis of stratigraphy in a paleoseismic trench and archaeological evidence reveal, it can be assigned to a major twelfth century a.d. earthquake which produced up to 4 m of oblique slip thrusting antithetic to that of the nearby dominant faults. The inferred surface rupturing earthquake apparently caused the fortress destruction and was likely the primary reason for its abandonment, not the Mongolian–Tatar invasions as previously thought.  相似文献   

Maximal Overlap Wavelet Statistical Analysis With Application to Atmospheric Turbulence     

Charles R. Cornish  Christopher S. Bretherton  Donald B. Percival 《Boundary-Layer Meteorology》2006,119(2):339-374

Statistical tools based on the maximal overlap discrete wavelet transform (MODWT) are reviewed, and then applied to a dataset of aircraft observations of the atmospheric boundary layer from the tropical eastern Pacific, which includes quasi-stationary and non-stationary segments. The wavelet methods provide decompositions of variances and covariances, e.g. fluxes, between time scales that effectively describe a broadband process like atmospheric turbulence. Easily understood statistical confidence bounds are discussed and applied to these scale decompositions, and results are compared to Fourier methods for quasi-stationary turbulence. The least asymmetric LA(8) wavelet filter yields coefficients that exhibit better uncorrelatedness across scales than the Haar filter and is better suited for decomposition of broadband turbulent signals. An application to a non-stationary segment of our dataset, namely vertical profiles of the turbulent dissipation rate, highlights the flexibility of wavelet methods.  相似文献   

Analysis of I in groundwater samples: Direct and quantitative results below the drinking water standard     

Christopher F. Brown  Keith N. GeiszlerMichael J. Lindberg 《Applied Geochemistry》2007

This paper highlights an analytical method based on mass measurement that can be used to directly quantify ¹²⁹I in groundwater samples at concentrations below the maximum contaminant level (MCL) without the need for sample pre-concentration or extraction. Samples were analyzed on a Perkin Elmer ELAN DRC II ICP-MS after minimal dilution using O₂ as the reaction gas. Analysis of continuing calibration verification standards indicated that the dynamic reaction cell (DRC) mode could be used for quantitative analysis of ¹²⁹I in samples below the MCL (0.0057 ng/mL or 1 pCi/L). The low analytical detection limit of ¹²⁹I analysis in the DRC mode coupled with minimal sample dilution (1.02x) resulted in a final estimated quantification limit of 0.0051 ng/mL. Subsequent analysis of three groundwater samples containing ¹²⁹I resulted in fully quantitative results in the DRC mode, and spike recovery analyses performed on all three samples confirmed that the groundwater matrix did not adversely impact the analysis of ¹²⁹I in the DRC mode. This analytical approach has been proven to be a cost-effective, high-throughput technique for the direct, quantitative analysis of ¹²⁹I in groundwater samples at environmentally relevant concentrations that reach below the current MCL.  相似文献   

Hypoxic events in Narragansett Bay, Rhode Island, during the summer of 2001   总被引：1，自引：0，他引：1  

D. Christopher Melrose  Candace A. Oviatt  Mark S. Berman 《Estuaries and Coasts》2007,30(1):47-53

Bottom water hypoxic events were observed in Narragansett Bay, Rhode Island during the summer of 2001 using a towed sensor, vertical casts at fixed stations, and continuous monitoring buoys. This combination of approaches allowed for both extensive spatial and temporal sampling. Oxygen concentrations below the U.S. Environmental Protection Agency (EPA) acute hypoxia criterion of 2.3 mg l^?1 were observed in the northern parts of Narragansett Bay, including the Providence River. We estimate 39% of the area of the Providence River was affected by acute hypoxia between July and September 2001. All other regions experienced only small areas of acute hypoxia (<5%), and no acute hypoxia was observed from Quonset Point south. The area encompassing oxygen concentrations below the EPA chronic hypoxia criterion of 4.8 mg l^?1 was much more extensive in the upper half of Narragansett Bay, sometimes covering the majority of the region, though it is unclear whether exposure to concentrations below this criterion persisted long enough to significantly affect marine species in these areas. Vertical profiles of dissolved oxygen typically exhibited a mid water oxygen minimum near the pycnocline, followed by a slight increase in oxygen with depth. The surface waters above the pycnocline were typically supersaturated with oxygen. The northern portions of the Bay where the most extensive hypoxia was observed corresponded to the regions with both the greatest thermohaline stratification, the highest nutrient inputs, and the highest primary productivity.  相似文献   

Modeling errors in upward continuation for INS gravity compensation     

Christopher Jekeli  Jong-Ki Lee  Jay H. Kwon 《Journal of Geodesy》2007,81(5):297-309

Accurate upward continuation of gravity anomalies supports future precision, free-inertial navigation systems, since the latter cannot by themselves sense the gravitational field and thus require appropriate gravity compensation. This compensation is in the form of horizontal gravity components. An analysis of the model errors in upward continuation using derivatives of the standard Pizzetti integral solution (spherical approximation) shows that discretization of the data and truncation of the integral are the major sources of error in the predicted horizontal components of the gravity disturbance. The irregular shape of the data boundary, even the relatively rough topography of a simulated mountainous region, has only secondary effect, except when the data resolution is very high (small discretization error). Other errors due to spherical approximation are even less important. The analysis excluded all measurement errors in the gravity anomaly data in order to quantify just the model errors. Based on a consistent gravity field/topographic surface simulation, upward continuation errors in the derivatives of the Pizzetti integral to mean altitudes of about 3,000 and 1,500 m above the mean surface ranged from less than 1 mGal (standard deviation) to less than 2 mGal (standard deviation), respectively, in the case of 2 arcmin data resolution. Least-squares collocation performs better than this, but may require significantly greater computational resources.  相似文献   

Historical effects of temperature and precipitation on California crop yields   总被引：3，自引：1，他引：3  

David B. Lobell  Kimberly Nicholas Cahill  Christopher B. Field 《Climatic change》2007,81(2):187-203

For the 1980–2003 period, we analyzed the relationship between crop yield and three climatic variables (minimum temperature, maximum temperature, and precipitation) for 12 major Californian crops: wine grapes, lettuce, almonds, strawberries, table grapes, hay, oranges, cotton, tomatoes, walnuts, avocados, and pistachios. The months and climatic variables of greatest importance to each crop were used to develop regressions relating yield to climatic conditions. For most crops, fairly simple equations using only 2–3 variables explained more than two-thirds of observed yield variance. The types of variables and months identified suggest that relatively poorly understood processes such as crop infection, pollination, and dormancy may be important mechanisms by which climate influences crop yield. Recent climatic trends have had mixed effects on crop yields, with orange and walnut yields aided, avocado yields hurt, and most crops little affected by recent climatic trends. Yield-climate relationships can provide a foundation for forecasting crop production within a year and for projecting the impact of future climate changes.  相似文献