Influence of the surface microlayer on the flux of nonconservative trace gases (CO,H2, CH4, N2O) across the ocean-atmosphere interface     

Ralf Conrad  Wolfgang Seiler 《Journal of Atmospheric Chemistry》1988,6(1-2):83-94

Gas exchange experiments were conducted in the tropical Atlantic Ocean during a ship expedition with FS Meteor using a small rubber raft. The temporal change of the mixing ratios of CO, H₂, CH₄ and N₂O in the headspace of a floating glass box and the concentrations of these gases in the water phase were measured to determine their transfer velocities across the ocean-atmosphere interface. The ocean acted as a sink for these gases when the water was undersaturated with respect to the mixing ratio in the headspace. The transfer velocities were different for the individual gases and showed still large differences even when normalized for diffusivity. Applying the laminar film model, film thicknesses of 20 to 70 m were calculated for the observed flux rates of the different gas species. When the water was supersaturated with respect to atmospheric CO, H₂, CH₄ and N₂O, the transfer velocities of the emission process were smaller than those determined for the deposition process. In case of H₂ and CH₄, emission was even not calculable although, based on the observed gradient, the laminar film model predicted significant fluxes at the air-sea interface. The results are interpreted by destruction processes active within the surface microlayer.  相似文献   

Mechanisms of seismic quiescences   总被引：7，自引：0，他引：7  

Christopher H. Scholz 《Pure and Applied Geophysics》1988,126(2-4):701-718

In the past decade there have been major advances in understanding the seismic cycle in terms of the recognition of characteristic patterns of seismicity over the entire tectonic loading cycle. The most distinctive types of patterns are seismic quiescences, of which three types can be recognized:post-seismic quiescence, which occurs in the region of the rupture zone of an earthquake and persists for a substantial fraction of the recurrence time following the earthquake,intermediate-term quiescences, which appear over a similar region and persist for several years prior to large plate-rupturing earthquakes, andshort-term quiescences, which are pronounced lulls in premonitory swarms that occur in the hypocentral region hours or days before an earthquake. Although the frequency with which intermediate-term and short-term quiescences precede earthquakes is not known, and the statistical significance of some of the former has been challenged, there is a need, if this phenomena is to be considered a possibly real precursor, to consider physical mechanisms that may be responsible for them.The characteristic features of these quiescences are reviewed, and possible mechanisms for their cause are discussed. Post-seismic quiescence can be readily explained by any simple model of the tectonic loading cycle as due to the regional effect of the stress-drop of the previous principal earthquake. The other types of quiescence require significant modification to any such simple model. Of the possibilities considered, only two seem viable in predicting the observed phenomena, dilatancy hardening and slip weakening. Intermediate-term quiescences typically occur over a region equal to or several times the size of the rupture zone of the later earthquake and exhibit a relationship between the quiescence duration and size of the earthquake: they thus involve regional hardening or stress relaxation and agree with the predictions of the dilatancy-diffusion theory. Short-term quiescences, on the other hand, are more likely explained by fault zone dilatancy hardening and/or slip weakening within a small nucleation zone. Because seismicity is a locally relaxing process, seismicity should follow a behaviour known in rock mechanics as the Kaiser effect, in which only a very slight increase in strength, due to dilatancy hardening or decrease in stress due to slip weakening, is required to cause quiescence. This is in contrast to other precursory phenomena predicted by dilatancy, which require large dilatant strains and complete dilatancy hardening.Lamont-Doherty Geological Observatory  相似文献   

Factors affecting trans-Tasman air services     

Christopher Kissling 《GeoJournal》1993,29(3):291-297

International civil aviation is circumscribed by a plethora of bilateral air service agreements between sovereign nations. In recent years there has been a marked trend to liberalise these agreements as well as moves to create multilateral common markets as appear to be emerging in Europe. Airline managements are being given opportunities to implement operational strategies once severely proscribed in confidential memoranda of understanding lying behind the public bilateral documents. In keeping with the philosophy of extending the Closer Economic Relations (CER) agreement, Australia and New Zealand have been exploring the ramifications of bringing trade in air services within the ambit of CER. This paper examines some of the factors affecting the trans Tasman civil aviation environment and discusses the implications of modifications to air services in and between Australia and New Zealand.  相似文献   

Comparative compressibilities of majorite-type garnets     

R. M. Hazen  R. T. Downs  P. G. Conrad  L. W. Finger  T. Gasparik 《Physics and Chemistry of Minerals》1994,21(5):344-349

Relative compressibilities of five silicate garnets were determined by single-crystal x-ray diffraction on crystals grouped in the same high-pressure mount. The specimens include a natural pyrope [(Mg_2.84Fe_0.10Ca_0,06) Al₂Si₃O₁₂], and four synthetic specimens with octahedrally-coordinated silicon: majorite [Mg₃(MgSi)Si₃O₁₂], calcium-bearing majorite [(Ca_0.49Mg_2.51)(MgSi)Si₃0₁₂], sodium majorite [(Na_1.88Mgp_0.12)(Mg_0.06Si_1.94)Si₃O₁₂], and an intermediate composition [(Na_0.37Mg_2.48)(Mg_0.13Al_1.07 Si₀₈₀) Si₃O₁₂]. Small differences in the compressibilities of these crystals are revealed because they are subjected simultaneously to the same pressure. Bulk-moduli of the garnets range from 164.8 ± 2.3 GPa for calcium majorite to 191.5 ± 2.5 GPa for sodium majorite, assuming K′=4. Two factors, molar volume and octahedral cation valence, appear to control garnet compression.  相似文献   

Rock-magnetic proxies of climate change in the loess-palaeosol sequences of the western Loess Plateau of China   总被引：5，自引：0，他引：5  

Christopher P. Hunt  Subir K. Banerjee  Jiamao Han  Peter A. Solheid  Eric Oches  Weiwei Sun  Tungsheng Liu 《Geophysical Journal International》1995,123(1):232-244

Results of the first detailed study of the climate proxy record in the loess-palaeosol sequence at Xining-one of the few palaeoclimate sites in the currently arid western Loess Plateau of China-illustrate the importance of making many types of rock-magnetic measurements other than susceptibility. A multiparameter approach yielded confirmation that here, as elsewhere in the Loess Plateau, the susceptibility enhancement in palaeosols was caused primarily by ultrafine magnetite and maghaemite. Nevertheless, magnetic enhancement was caused not exclusively by changes in relative grain size, but also by variations in concentration and mineralogy of the magnetic fraction.
The effects of concentration variations were removed through normalization of susceptibility and anhysteretic remanence with saturation magnetization and saturation remanence, respectively. the resulting signal was ascribed more confidently to variation in magnetic grain size, which in turn was interpreted as a better proxy of pedogenesis than simple susceptibility. Variations in magnetic mineralogy were also determined to constrain interpretations further. the data were then used to discuss climate history at Xining. Finally, results from Xining were compared with other western sites and contrasted with eastern sites.
In summary: (1) data is presented from a new Loess Plateau site which also appears to yield a global climate signal; (2) a demonstration is made of a more rock-magnetically robust way to separate concentration, composition and grain-size controls on susceptibility and other magnetic parameters; and (3) models are provided for inter-regional comparisons of palaeoclimate proxy records.  相似文献   

Effects of lateral velocity heterogeneity under the Nevada Test Site on short-periodP wave amplitudes and travel times     

Christopher S. Lynnes  Thorne Lay 《Pure and Applied Geophysics》1990,132(1-2):245-267

Short-period teleseismicP waves from the Nevada Test Site (NTS) show systematic variations in amplitudes and travel times, with low amplitudes corresponding to fast travel times, suggesting elastic focussing-defocussing effects. Also, the azimuthal amplitude and travel time patterns for events at the Pahute Mesa subsite are systematically different from those at the Yucca Flat subsite, indicating the presence of a near-source component in both the amplitude and travel-time variations. This component is isolated by removing the mean station pattern for all of NTS from the observations. A very-near-source component in the Pahute Mesa observations is also isolated by removing subsite station means from the measurements, whereas the Yucca Flat observations exhibited no coherent very-near-source component. These anomalies are back-projected through laterally homogeneous structure to form thin lens models at various depths. Travel-time delays are predicted from the amplitude variations using the equation for wavefront curvature. The long-wavelength components of the predicted and observed time delays correlate well, at depths of 25 km for the very-near-source component under Pahute Mesa and 160 km for the regional component under NTS. The time delay surfaces predicted by the amplitudes at these depths are mapped into warped velocity discontinuities suitable for the calculation of synthetic seismograms using the Kirchhoff-Helmholtz integral formulation. Both the intersite (near-source) and intrasite (very-near-source) differences in amplitudes are qualitatively predicted very well, although the range of variation is somewhat underpredicted. This deficiency is likely due to the destructive interference of anomalies inherent in back-projection to a single layer.  相似文献   

Responses of fish and macrobenthic assemblages to hydrologic disturbances in Tijuana Estuary and Los Peñasquitos Lagoon,California     

Christopher S. Nordby  Joy B. Zedler 《Estuaries and Coasts》1991,14(1):80-93

Changes in the assemblages of fishes and benthic macro-invertebrates were evaluated in relation to wastewater inflows at Tijuana Estuary and impounded streamflows and mouth closure at Los Peñasquitos Lagoon. Freshwater from sewage spills or winter rains lowered water salinities and had major impacts on the channel organisms of both southern California coastal wetlands. Benthic infaunal assemblages responded more rapidly to reduced salinity than did fishes, with continued salinity reduction leading to the extirpation of most species. Both the fish and benthic invertebrate assemblages became dominated by species with early ages of maturity and protracted spawning seasons. Between-system comparisons showed that good tidal flushing reduced negative impacts on both the fish and benthic assemblages.  相似文献   

Airborne vector gravimetry using precise,position-aided inertial measurement units     

Christopher Jekeli 《Journal of Geodesy》1994,69(1):1-11

Vector gravimetry using a precise inertial navigation system continually updated with external position data, for example using GPS, is studied with respect to two problems. The first concerns the attitude accuracy requirement for horizontal gravity component estimation. With covariance analyses in the space and frequency domains it is argued that with relatively stable uncompensated gyro drift, the short-wavelength gravity vector can be estimated without the aid of external attitude updates. The second problem concerns the state-space estimation of the gravity signal where considerable approximations must be assumed in the gravity model in order to take advantage of the ensemble error estimation afforded by the Kalman filter technique. Gauss-Markov models for the gravity field are specially designed to reflect the attenuation of the signal at a specific altitude and the omission of the long-wavelength components from the estimation. With medium accuracy INS/GPS systems, the horizontal components of gravity with wavelengths shorter than 250 km should be estimable to an accuracy of 4–6 mgal (µg); while high accuracy systems should yield an improvement to 1–2 mgal.  相似文献   

Eccentric geomagnetic dipole drift     

Joseph C. Cain  Dave R. Schmitz  Christopher Kluth 《Physics of the Earth and Planetary Interiors》1985,39(4):237-242

A recalculation of the rate of westward drift of the eccentric geomagnetic dipole since 1900 has confirmed its correlation with irregularities in the excess length-of-day (LOD) as originally reported by Vestine. The major changes in the LOD curve since 1900 are shown to be well correlated with the westward drift rate from a number of magnetic models covering the interval. A new Magsat model of secular variation for 1980.0 shows no increase in the drift rate which dropped by a factor of three in the interval 1965–1970.  相似文献   

Acid mine drainage contaminates groundwater of a Tennessee watershed     

Christopher J. O’Bara  R. Don Estes 《Environmental Geology》1985,7(3):159-161

Water samples were collected from 18 natural springs within the West Fork of the Obey River watershed. Overton County, Tennessee, to determine if groundwater was adversely affected by runoff from abandoned surface coal mines Six springs were found to be affected severely and deemed unfit as a source of potable water Water quality of the remaining springs was essentially unaffected it appeared that proximity to surface mines, elevation at the outflow, and geology of the surrounding strata determined the quality of the groundwater The unit is jointly supported by Tennessee Technological University, the Tennessee Wildlife Resource Agency, and the US. Fish and Wildlife Service  相似文献