The importance of the diet as a source of tributyltin (TBT) in Nucella lapillus was studied using [14C]tributyltin chloride. In N. lapillus provided with prelabelled mussels, Mytilus edulis, in labelled water (mean 20·5 ng/litre TBT) the rate of accumulation of total 14C was 2–3 times that in unfed animals. Owing to its degradation in the tissues of both fed and unfed animals, concentrations of [14C]TBT tended to reach a plateau after only 28 days. However, total concentrations of 14C were still increasing after 49 days. Under experimental conditions (15°C, ample food, no disturbance) the diet accounted for about 50% of the body burden of TBT in N. lapillus after 49 days exposure: concentration factors (dry tissue/water) for [14C]TBT in both male and female N. lapillus were similar at about 60 000 in fed and 30 000 in unfed animals. It is concluded that the diet may contribute less than half of the body burden of TBT found in natural populations subjected to life-long exposure. 相似文献
This paper investigates the use of data assimilation in coastal area morphodynamic modelling using Morecambe Bay as a study site. A simple model of the bay has been enhanced with a data assimilation scheme to better predict large-scale changes in bathymetry observed in the bay over a 3-year period. The 2DH decoupled morphodynamic model developed for the work is described, as is the optimal interpolation scheme used to assimilate waterline observations into the model run. Each waterline was acquired from a SAR satellite image and is essentially a contour of the bathymetry at some level within the inter-tidal zone of the bay. For model parameters calibrated against validation observations, model performance is good, even without data assimilation. However the use of data assimilation successfully compensates for a particular failing of the model, and helps to keep the model bathymetry on track. It also improves the ability of the model to predict future bathymetry. Although the benefits of data assimilation are demonstrated using waterline observations, any observations of morphology could potentially be used. These results suggest that data assimilation should be considered for use in future coastal area morphodynamic models. 相似文献
The recent sea-ice reduction in the Arctic Ocean is not spatially uniform, but is disproportionally large around the Northwind
Ridge and Chukchi Plateau compared to elsewhere in the Canada Basin. In the Northwind Ridge region, Pacific Summer Water (PSW)
delivered from the Bering Sea occupies the subsurface layer. The spatial distribution of warm PSW shows a quite similar pattern
to the recent ice retreat, suggesting the influence of PSW on the sea-ice reduction. To understand the regionality of the
recent ice retreat, we examine the dynamics and timing of the delivery of the PSW into this region. Here, we adopt a two-layer
linearized potential vorticity equation to investigate the behavior of Rossby waves in the presence of a topographic discontinuity
in the high latitude ocean. The analytical results show a quite different structure from those of mid-latitude basins due
to the small value of β. Incident barotropic waves excited by the sea-ice motion with large annual variation can be scattered
into both barotropic and baroclinic modes at the discontinuity. Since the scattered baroclinic Rossby wave with annual frequency
cannot propagate freely, a strong baroclinic current near the topographic discontinuity is established. The seasonal variation
of current near the topographic discontinuity would cause a kind of selective switching system for shelf water transport into
the basin. In our simple analytical model, the enhanced northward transport of summer water and reduced northward transport
of winter water are well demonstrated. The present study indicates that these basic dynamics imply that a strengthening of
the surface forcing during winter in the Canada Basin could cause sea-ice reduction in the Western Arctic through the changes
of underlying Pacific Summer Water. 相似文献
Rapid shifts in past climate recorded in polar ice sheets have elicited various explanations relating to either thermohaline
circulation changes by ice-rafting or natural greenhouse gas concentrations modulated by climatic conditions in the tropics.
To compare the tropical paleoclimate record with the polar record, one must choose sediment cores from highly productive ocean
regions. Necessarily, such regions reflect the wind records in the tropics, because high productivity is associated with upwelling
driven by winds. Comparing tropical precipitation records with high-latitude records is, however, a more difficult task because
sediments recording paleoprecipitation usually have low sedimentation rates, and offer coarser resolution relative to polar
ice cores. Here, we present δ18O data of three planktonic species of Foraminifera (a proxy for precipitation) from such a sediment core, spanning the past
35 ka for the equatorial Indian Ocean, which falls under the southwest monsoon (SWM) realm. Results show that minimum SWM
precipitation occurred at the Last Glacial Maximum, with a subsequent increase at Termination IA. During the Holocene, SWM
precipitation intensified uniformly up to the core top (∼2.2 ka b.p.), as revealed by generally decreasing δ18O values. Variations in precipitation are consistent with climate changes recorded in polar ice sheets. Although the different resolutions of the two records preclude
a rigorous comparison, abrupt cooling/warming events appear to be accompanied by sudden reduction/enhancement in (SWM) rainfall.
Thus, mechanisms with time scales much shorter than a millennium, such as natural greenhouse warming (e.g., CH4 concentration), controlled by emissions from the tropics, could have played a major role in high-latitude climate change. 相似文献
Based on a multiparameter approach a combined litho- and organofacies concept was developed for glacial and interglacial sediment sections along an E-W transect through the central part of the Norwegian-Greenland Sea (NGS).
Modern and past surface water regimes are clearly displayed by specific litho- and organofacies patterns. Interglacial conditions reveal specific Atlantic water associated lithofacies (A and B3) in the eastern and central sector of the Norwegian-Greenland Sea (NGS). Corresponding interglacial organofacies in general are not well correlated to lithofacies due to strong diagenetic degradation of labile, e.g. autochthonous organic matter (OM). While in near-surface sediments a marine-dominated organofacies (I-1) is preserved under Atlantic water masses, this correlation is not evident for lower Holocene and Isotope Stage 5 deposits. However, during Isotopic Event 5.5.1 increased proportions of marine OM are recorded in a high accumulating core on the Vøring Plateau. Glaciomarine background lithofacies (B and C) indicate minor input of ice rafted debris (IRD) and seasonal variable sea-ice cover. Corresponding organofacies (II-1, non-oxidized and II-2, oxidized) are dominated by allochthonous OM. Most spectacular are glacial diamictons (Lithofacies E and F) evidencing short-term sediment pulses due to a sudden disintegration of far advanced tide water ice margins on the outer shelves. These diamictons bear specific organofacies (III-1 and III-2) with a clear predominance of terrigenous and reworked OM.
Some of the diamictons seem to occur contemporaneous with the so called “Heinrich-layers” H1 and H2, suggesting a common trigger-mechanism for the almost simultaneous disintegration of huge continental ice masses along the shelves of North America and the eastern margin of the NGS.
Application of a combined organo- and lithofacies concept provides essential information on spatial and temporal variations of water mass characteristics, the oceanic effects of ice sheet dynamics and circulation models. 相似文献
The construction of reservoir models is frustrated by the fact that core and well cover only a fraction of the reservoir volume and it is therefore difficult to determine features like facies shape, -size, and -distribution, inter- and intra-facies boundaries and lateral trends from them. These features are, however, critical to fluid flow and they should necessarily be incorporated in the reservoir model and we therefore propose to systematically describe geometry and distribution of facies. To this end we make use of “standard facies models” that a priori contain all elements and boundaries of facies for a number of typical depositional environments. 相似文献
The exothermic reaction which proceeds when small sachets containing particulate mixtures of iron and magnesium are flooded with sea water, has been used for thermal support of free divers. Initial application of such generators to heating of the hands (Burton and Chan, 1981), and later extension to heating of the torso, have been described previously (Chan and Burton, 1981, 1982). Of considerable interest during field trials of the torso heating system was a strong subjective impression among those taking part, that significant increases of dive duration and decreases of perceived discomfort could be obtained with relatively low levels of power generation, for example less than 50% of that required for thermal balance. In this paper, a simple mathematical model of human stored heat loss is used to rationalize this observation. Also it successfully predicts voluntary exposure times of unheated divers who become cold. When used to estimate body heat debt, the model enables documented dives by this laboratory and by others, including recent exposures in Antarctica using low level supplementary heating, to be analysed. 相似文献
Dissolved and particulate concentrations of the biogenic thiols cysteine (Cys), arginine–cysteine (Arg–Cys), glutamine–cysteine (Gln–Cys), γ-glutamate–cysteine (γ-Glu–Cys) and glutathione (GSH) were measured in the subartic Pacific Ocean in the summer of 2003 using high performance liquid chromatography (HPLC) with precolumn derivatization as reported in previous work. In this study, a preconcentration protocol for the derivatized thiols was utilized to extend detection limits of dissolved thiols to picomolar levels. The measured concentrations of particulate and dissolved thiols were uncoupled, with distinctive depth profiles and large differences in the particulate to dissolved ratios between individual compounds. Glutathione was the most abundant particulate thiol whereas the most abundant dissolved thiol was γ-Glu–Cys, with concentrations as high as 15 nM. Given the relatively small pool of intracellular γ-Glu–Cys and the very low dissolved concentrations of GSH, we hypothesize that glutathione released from cells is rapidly converted to the potentially degradation resistant γ-Glu–Cys outside the cell. The relatively high concentrations of other dissolved thiols compared to particulate concentrations implies both biological exudation and slow degradation rates. Some thiols appear to vary with changes in nutrient availability but this effect is difficult to decouple from changes in community structure inferred from pigment analyses. Dissolved thiol concentrations also exceed typical metal concentrations in the subartic Pacific, supporting previous arguments that they may be important in metal speciation. 相似文献