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151.
(Marseille–Cassis–Bouches–du-Rhône). The salinity of the karstic submarine spring of Port-Miou has sometimes been attributed to the leaching of continental evaporites. Our recent chemical and isotopic analyses indicate a simple mixing between fresh karstic water and seawater. In the main gallery, the contamination by seawater, still present up to 2.2 km from the entrance at a depth of 147 m below the sea level, forces us to think about a general geometry that allows mixing of waters, at a great depth, in the karstic system. The measurements of the discharge of the spring indicate an excess of water compared with its supposed watershed, whereas a succinct evaluation of the aquifers of the Lower Provence indicates a deficit of discharge. Consequently, it seems possible that parts of the calcareous areas of the Lower Provence feed the springs of Port-Miou with a total catchment area of 1200 km2. This deep and large karstic system was probably installed during the Messinian period, when the important lowering of the level of the Mediterranean Sea provoked an important gradient between Provence and the seashore. To cite this article: B. Blavoux et al., C. R. Geoscience 336 (2004).  相似文献   
152.
This paper presents a two-stage anion-exchange procedure for tungsten extraction, an improved mass spectrometric procedure for tungsten analysis and a simplified chemical separation and TIMS procedure for the determination of Hf concentrations. The chemical separation of tungsten is based on its complexing properties with HF and H2O2. The blank level for a sample size of 300 mg is about 80 pg for tungsten. The procedure is designed for the high sensitivity of negative thermal ionisation mass spectrometry (NTIMS) provided by the use of Mg oxide as an emitter on Ir filaments. Tungsten can be readily measured with a high precision in various meteoritical material and especially in small W-poor silicate fractions. Samples containing as little as a few ng g-1 tungsten can be analysed reliably with this method.  相似文献   
153.
New noble gas data of ultramafic xenoliths from Réunion Island, Indian Ocean, further constrain the characteristics of primordial and radiogenic noble gases in Earth’s mantle plume reservoirs. The mantle source excess of nucleogenic 21Ne is significantly higher than for the Hawaiian and Icelandic plume reservoirs, similar to excess of radiogenic 4He. 40Ar/36Ar of the Réunion mantle source can be constrained to range between 8000 and 12 000, significant 129Xe and fission Xe excess are present. Regarding the relative contribution of primordial and radiogenic rare gas nuclides, the Réunion mantle source is intermediate between Loihi- and MORB-type reservoirs. This confirms the compositional diversity of plume sources recognized in other radioisotope systematics. Another major result of this study is the identification of the same basic primordial component previously found for the Hawaiian and Icelandic mantle plumes and the MORB reservoir. It is a hybrid of solar-type He and Ne, and ‘atmosphere-like’ or ‘planetary’ Ar, Kr, Xe (Science 288 (2000) 1036). 20Ne/22Ne ratios extend to maximum values close to 12.5 (Ne-B), which is the typical signature of solar neon implanted as solar corpuscular radiation. This suggests that Earth’s solar-type noble gas inventory was acquired by small (less than km-sized) precursor planetesimals that were irradiated by an active early sun in the accretion disk after nebular gas dissipation, or, alternatively, that planetesimals incorporated constituents irradiated in transparent regions of the solar nebula. Previously, such an early irradiation scenario was suggested for carbonaceous chondrites which follow common volatile depletion trends in the sequence CI–CM–CV–Earth. In turn, CV chondrites closely match Earth’s mantle composition in 20Ne/22Ne, 36Ar/22Ne and 36Ar/38Ar. This indicates that mantle Ar could well be a planetary component inherited from precursor planetesimals. However, a corresponding conclusion for mantle Kr and Xe is less convincing yet, but this may be just due to the lack of appropriate ‘meteoritic’ building blocks matching terrestrial composition. Alternatively, heavy noble gases in Earth’s mantle could be due to admixing of severely fractionated air, but this effect must have affected all mantle sources to a very similar extent, e.g. by global subduction before the last homogenization of the mantle reservoirs.  相似文献   
154.
Another description of the Mediterranean Sea outflow   总被引:1,自引:0,他引:1  
Papers about the outflow in the Strait of Gibraltar assume that (i) it is composed of only two Mediterranean Waters (MWs), the Levantine Intermediate Water (LIW) and the Western Mediterranean Deep Water (WMDW) from the eastern and western basins, respectively, (ii) both MWs are mixed near 6°W, hence producing a homogeneous outflow that is then split into veins, due to its cascading along different paths and to different mixing conditions with the Atlantic Water (AW).A re-analysis of 1985–1986 CTD profiles (Gibraltar Experiment) indicates two other MWs, the Winter Intermediate Water (WIW) from the western basin and the Tyrrhenian Dense Water (TDW) basically originated from the eastern basin. In the central Alboran subbasin, these four MWs are clearly differentiated, roughly lying one above the other in proportions varying from north to south. Proportions also vary with time, so that the outflow can be mostly of either eastern or western origin. While progressing westward, the MWs can still be differentiated and associated isopycnals tilt up southward as much as being, in the sill surroundings, roughly parallel to the Moroccan continental slope where the densest MWs are. The MWs at the sill are thus juxtaposed and they all mix with AW, leading to an outflow that is horizontally heterogeneous just after the sill (5°45′W) before progressively becoming vertically heterogeneous as soon as 6°15′W. There can be little LIW and/or no WMDW outflowing for a while.An analysis of new 2003–2008 time series from two CTDs moored (CIESM Hydro-Changes Programme) at the sill (270 m) and on the Moroccan shelf (80 m) confirms the juxtaposition of the MWs, their individual and generally intense mixing with AW, as well as the large temporal variability of the outflow composition. Only LIW and TDW were indicated at the sill while, on the shelf, only LIW, TDW sometimes denser there than 200 m below, and WMDW were indicated; but none of the MWs has been permanently outflowing at one or the other place.The available data can be analyzed coherently. Intermediate and deep MWs are formed in both basins in amounts that, although variable from year to year, allow their tracing up to the strait. Four major MWs circulate alongslope counterclockwise as density currents and as long as they are not trapped within a basin, which is necessarily the case for the deep MWs. In the Alboran, the intermediate MWs (WIW, LIW and upper-TDW) circulate in the north while the deep MWs (lower-TDW and WMDW) are uplifted, hence relatively motionless and mainly pushed away in the south. Since both the intermediate and deep MWs outflow at the sill, they are considered as light and dense MWs, the light–dense MWs interface possibly intersecting the AW–MWs interface in the sill surroundings. Considering an outflow east of the sill composed of only two (light–dense) homogeneous layers gives significant results. Across the whole strait, the outflow has spatial and temporal variabilities much larger than previously assumed. The MWs are superposed in the sea and lead at the sill to juxtaposed and vertically stratified suboutflows that will cascade independently before forming superposed veins in the ocean. These veins can have similar densities and hydrographic characteristics even if associated with different MWs, which accounts for the features permanency assumed up to now. The outflow structure downstream of the sill depends on its composition upstream and, more importantly, on that of AW in the sill surroundings where fortnightly and seasonal signals are imposed on the whole outflow.  相似文献   
155.
Ammonoid diversity patterns show that the spreading of oceanic anoxia is not the initial and major kill mechanism for the Cenomanian/Turonian mass extinction as usually suggested. In the Anglo-Paris Basin and the Vocontian Basin, the drop of ammonoid species richness starts around the middle/late Cenomanian boundary, i.e. 0.75 myr before the occurrence of anoxic deepwater sediments. The stepwise extinction of first heteromorphs and then acanthoceratids is incompatible with the rise of the oxygen minimum zone. Moreover, shelf environments of these basins remained well oxygenated during the Cenomanian/Turonian boundary interval. Thus, we stress that other causative mechanisms initiated the ammonoid extinction even if anoxia subsequently participated in the demise of marine ecosystems. Editorial handling: M.J. Benton & J.-P. Billon-Bruyat  相似文献   
156.
This paper is a comparative study between the two most common hailpad calibration systems: one annual calibration of a whole consignment of material, and the individual calibration of each plate after a hailfall. Individual calibration attempts to minimize errors due to differences in sensitivity to the impact of hailstones between plates from the same consignment, or due to differences in the inking process before the actual measurement.The comparison was carried out using calibration data from the past few years in the hailpad network in south-western France, and data from an individual calibration process on material provided by the hailpad network in Lleida (Spain). The same type of material was used in the two cases.The results confirm that the error in measuring hailstone sizes is smaller in the case of an individual calibration of hailpads than when one single calibration process was carried out for a whole consignment. The former is approximately 80% of the latter. However, this error could have been higher if it had not been the same person carrying out the single calibration process and the measuring of the dents: it has been found that differences in the inking process may account for up to 20% of the error in the case of small hailstones. Calibration errors affecting other variables, e.g. energy or parameter λ of the exponential size distribution are generally higher (5% and 18%, respectively) than errors due to the spatial variability of the hailstones. However, the calibration method does not influence the maximum size, since the relative error attributed to the spatial variability is about 8 times the calibration error.In conclusion, if errors in determining energy or parameter λ are to be reduced to a minimum, it is highly advisable to be consistent in applying the measuring procedure (if possible with the same person carrying out the measurements all the time), and even to use individual calibration on each plate, always bearing in mind that technicians have to be trained appropriately in order to achieve the highest possible degree of uniformity.  相似文献   
157.
The spectral irradiance at the center of the solar H I Lyman α (, referred to as Lyα in this paper) line profile is the main excitation source responsible for the atomic hydrogen resonant scattering of cool material in our Solar System. It has therefore to be known with the best possible accuracy in order to model the various Lyα emissions taking place in planetary, cometary, and interplanetary environments. Since the only permanently monitored solar irradiance is the total one (i.e. integrated over the whole Lyα line profile), Vidal-Madjar [1975. Evolution of the solar Lyman alpha flux during four consecutive years. Solar Phys. 40, 69-86] using Orbiting Solar Observatory 5 (OSO-5) satellite Lyα data, established a semi-empirical formula allowing him to deduce the central spectral Lyα irradiance from the total one. This relation has been extensively used for three decades. But, at the low altitude of the OSO-5 orbit, the central part of the solar line profile was deeply absorbed by a large column of exospheric atomic hydrogen. Consequently, the spectral irradiance at the center of the line was obtained by a complex procedure confronting the observations with simulations of both the geocoronal absorption and the self-reversed shape of the solar Lyα profile. The SUMER spectrometer onboard SOHO positioned well outside the hydrogen geocorona, provided full-Sun Lyα profiles, not affected by such an absorption [Lemaire et al., 1998. Solar H I Lyman α full disk profile obtained with the SUMER/SOHO spectrometer. Astron. Astrophys. 334, 1095-1098; 2002. Variation of the full Sun Hydrogen Lyman α and β profiles with the activity cycle. Proc. SOHO 11 Symposium, ESA SP-508, 219-222; 2004. Variation of the full Sun Hydrogen Lyman profiles through solar cycle 23. COSPAR 2004 Meeting], making it—for the first time—possible to measure the spectral and total Lyα solar irradiances directly and simultaneously. A new relation between these two quantities is derived in an expression that is formally similar to the previous one, but with significantly different parameters. After having discussed the potential causes for such differences, it is suggested that the new relation should replace the old one for any future modeling of the numerous Lyα absorptions and emissions observed in the Solar System.  相似文献   
158.
Dynamical systems with three degrees of freedom can be reduced to the study of a fourdimensional mapping. We consider here, as a model problem, the mapping given by the following equations: $$\left\{ \begin{gathered} x_1 = x_0 + a_1 {\text{ sin (}}x_0 {\text{ + }}y_0 {\text{)}} + b{\text{ sin (}}x_0 {\text{ + }}y_0 {\text{ + }}z_{\text{0}} {\text{ + }}t_{\text{0}} {\text{)}} \hfill \\ y_1 = x_0 {\text{ + }}y_0 \hfill \\ z_1 = z_0 + a_2 {\text{ sin (}}z_0 {\text{ + }}t_0 {\text{)}} + b{\text{ sin (}}x_0 {\text{ + }}y_0 {\text{ + }}z_{\text{0}} {\text{ + }}t_{\text{0}} {\text{) (mod 2}}\pi {\text{)}} \hfill \\ t_1 = z_0 {\text{ + }}t_0 \hfill \\ \end{gathered} \right.$$ We have found that as soon asb≠0, i.e. even for a very weak coupling, a dynamical system with three degrees of freedom has in general either two or zero isolating integrals (besides the usual energy integral).  相似文献   
159.
Summary. The motion of a phase boundary in the Earth caused by temperature and pressure excitations at the Earth's surface is determined under a linear approximation. The solution is found as a sum of convolutions of pressure and temperature Green's functions with the corresponding excitations. The Green's functions are given under the form of Laplace transforms that can be inverted either by numerical evaluation of a branch cut integral or by inversion of a series expansion. This solution is a generalization of a solution previously derived by Gjevik. This latter solution is the first term in the series expansion. The relaxation times associated with the phase boundary motion are of the order of 105–107yr for the olivine—spinel phase transition and of 106–107yr for the basalt—eclogite transition. The linear approximation remains valid for long times only if the phase boundary moves slowly.  相似文献   
160.
Eleven vertical profiles of stratospheric NO3 have been obtained since 1992 using the AMON and SALOMON balloon-borne UV-visible spectrometers. The measurements are compared to the SLIMCAT 3D model and calculations based on the steady-state hypothesis for NO3. The calculations cannot reproduce some parts of the profiles which exhibit strong concentration fluctuations over few kilometres, as a consequence of the dependence of NO3 on local temperature variations. A statistical use of the data allows us to estimate the influence of the temperature dependence of the absorption cross-section on the data analysis, and the validity of the recommended reaction rates available in the literature. Discrepancies exist between the model based on recommended kinetics and observations at warmer temperatures. Nevertheless, the analysis is biased by local temperature inhomogeneities, and only a low-resolution vertical shape of the NO3 profiles can be retrieved.  相似文献   
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