The role of dissolved molecular oxygen in abiotic pyrite oxidation under acid pH conditions – Experiments with O-enriched molecular oxygen     

Claudia Heidel  Marion Tichomirowa 《Applied Geochemistry》2010

  相似文献   

Cross-scale ensemble projections of dissolved organic carbon dynamics in boreal forest streams     

Stephen K. Oni  Martyn N. Futter  Claudia Teutschbein  Hjalmar Laudon 《Climate Dynamics》2014,42(9-10):2305-2321

Climate is an important driver of dissolved organic carbon (DOC) dynamics in boreal catchments characterized by networks of streams within forest-wetland landscape mosaics. In this paper, we assess how climate change may affect stream DOC concentrations ([DOC]) and export from boreal forest streams with a multi-model ensemble approach. First, we apply an ensemble of regional climate models (RCMs) to project soil temperatures and stream-flows. These data are then used to drive two biogeochemical models of surface water DOC: (1) The Integrated Catchment model for Carbon (INCA-C), a detailed process-based model of DOC operating at the catchment scale, and (2) The Riparian Integration Model (RIM), a simple dynamic hillslope scale model of stream [DOC]. All RCMs project a consistent increase in temperature and precipitation as well as a shift in spring runoff peaks from May to April. However, they present a considerable range of possible future runoff conditions with an ensemble median increase of 31 % between current and future (2061–2090) conditions. Both biogeochemical models perform well in describing the dynamics of present-day stream [DOC] and fluxes, but disagree in their future projections. Here, we assess possible futures in three boreal catchments representative of forest, mire and mixed landscape elements. INCA-C projects a wider range of stream [DOC] due to its temperature sensitivity, whereas RIM gives consistently larger inter-annual variation and a wider range of exports due to its sensitivity to hydrological variations. The uncertainties associated with modeling complex processes that control future DOC dynamics in boreal and temperate catchments are still the main limitation to our understanding of DOC mechanisms under changing climate conditions. Novel, currently overlooked or unknown drivers may appear that will present new challenges to modelling DOC in the future.  相似文献   

Pattern scaling: Its strengths and limitations,and an update on the latest model simulations     

Claudia Tebaldi  Julie M. Arblaster 《Climatic change》2014,122(3):459-471

We review the ideas behind the pattern scaling technique, and focus on its value and limitations given its use for impact assessment and within integrated assessment models. We present estimates of patterns for temperature and precipitation change from the latest transient simulations available from the Coupled Model Inter-comparison Project Phase 5 (CMIP5), focusing on multi-model mean patterns, and characterizing the sources of variability of these patterns across models and scenarios. The patterns are compared to those obtained from the previous set of experiments, under CMIP3. We estimate the significance of the emerging differences between CMIP3 and CMIP5 results through a bootstrap exercise, while also taking into account the fundamental differences in scenario and model ensemble composition. All in all, the robustness of the geographical features in patterns of temperature and precipitation, when computed as multi-model means, is confirmed by this comparison. The intensity of the change (in both the warmer and cooler areas with respect to global temperature change, and the drier and wetter regions) is overall heightened per degree of global warming in the ensemble mean of the new simulations. The presence of stabilized scenarios in the new set of simulations allows investigation of the performance of the technique once the system has gotten close to equilibrium. Overall, the well established validity of the technique in approximating the forced signal of change under increasing concentrations of greenhouse gases is confirmed.  相似文献   

Predictive Power Evaluation of a Physically Based Model for Shallow Landslides in the Area of Oltrepò Pavese,Northern Italy   总被引：2，自引：0，他引：2  

Roberto Valentino  Claudia Meisina  Lorella Montrasio  Gian Luca Losi  Davide Zizioli 《Geotechnical and Geological Engineering》2014,32(4):783-805

The use of real-time landslide early warning systems is attracting the attention of the scientific community, since it allows to assess “where” and “when” a shallow rainfall-induced landslide might occur by coupling rainfall amounts, hydrological models and slope-stability analysis. The paper deals with the main results of a back analysis, which refers to the application of a physically based stability model [Shallow Landslides Instability Prediction (SLIP)] on regional scale. The analysis concerns the occurrence of some recent rainfall-induced shallow landslides in the municipal territory of Broni, in the area of Oltrepò Pavese (Northern Italy). The study area is a hilly region 2.4 km² wide, where more than 40 % of the territory has slopes steeper than 15° and altitudes are between 90 and 250 m a.s.l. As regards the geologic setting, clayey-silty shallow colluvial deposits, with a maximum thickness of about 3 m, overlap a bedrock made of clayey shales, calcareous flysch and marls. The SLIP model is based on the limit equilibrium method applied to an infinite slope and on the Mohr–Coulomb strength criterion for the soil. By assuming that the main hydro-geotechnical process that leads to failure is the saturation of parts of the soil, the model allows to take into account the condition of partial saturation of the soil. The safety factor (F _S ) of a slope is also function of previous rainfalls. After the implementation of the model at territory scale, the input data have been introduced through a geographic information systems platform. In the current paper we mainly intend to evaluate the performance of SLIP at catchment scale, by comparison to (1) observed landslide events and (2) another well-established physically based model (TRIGRS). Further, we want to assess the suitability of the model as early warning tool. The results produced by the model are analyzed both in terms of safety factor maps, corresponding to some particular rainfall events, and in terms of the time-varying percentage of unstable areas over a 2-year span period. The paper shows the comparison between observed landslide localizations and model predictions. A quantitative comparison between the SLIP model and TRIGRS is presented, only for the most important event that occurred during the analyzed period. Overall, the results of the stability analyses based on observed rainfalls show the capability of the SLIP model to predict, in real-time and on a wide area, the occurrence of the analyzed phenomena.  相似文献   

AGB Phase Transition in Globular Clusters: A Tool for Dating Starbursts     

Claudia Maraston  Markus Kissler-Patig  Jean Brodie  Pauline Barmby  John Huchra 《Astrophysics and Space Science》2002,281(1-2):137-138

A new method to detect and study young star clusters is presented. This is based on the knowledge that the light of stellar populations with ages between ∼ 200 Myr and ∼ 1/2 Gyr is dominated by very red, bright AGB stars. Star clusters undergoing this so-called ‘AGB phase transition’ are featured by very red V-K colours, like those of Magellanic Clouds clusters, while optical colours like B-V remain blue typical for young populations. The best channel for detecting star clusters in this age range is therefore the near IR. From the theoretical side, SSP models including properly the contribution of the bright AGB are required (Maraston, 1998). Using this strategy, we succesfully detected the AGB phase transition among the clusters of the merger remnant galaxy NGC 7252 (see Maraston etal., 2001). This revised version was published online in September 2006 with corrections to the Cover Date.  相似文献   

The influence of a mature cyclonic eddy on particle export in the lee of Hawaii     

Kanchan Maiti  Claudia R. Benitez-Nelson  Yoshimi Rii  Robert Bidigare 《Deep Sea Research Part II: Topical Studies in Oceanography》2008,55(10-13):1445

Mesoscale eddies may enhance primary production (PP) in the open ocean by bringing nutrient-rich deep waters into the euphotic zone, potentially leading to increased transport of particles to depth. This hypothesis remains controversial, however, due to a paucity of direct particle export measurements. In this study, we investigated particle dynamics using ²³⁴Th–²³⁸U disequilibria within a mesoscale cold-core eddy, Cyclone Opal, which formed in the lee of the Hawaiian Islands. ²³⁴Th samples were collected along two transects across Cyclone Opal as well as during a time-series within the eddy core during a decaying diatom bloom. Particulate carbon (PC), particulate nitrogen (PN) and biogenic silica (bSiO₂) fluxes at 150 m varied spatially and temporally within the eddy and strongly depended on the ²³⁴Th model formulation used (e.g., steady state versus non-steady state, inclusion of upwelling, etc.). Particle fluxes estimated from a steady state model assuming an upwelling rate of 2 m day⁻¹ yielded the best fit to sediment-trap data. These ²³⁴Th-derived particle fluxes ranged from 332±14 to 1719±53 μmol C m⁻² day⁻¹, 27±3 to 114±12 μmol N m⁻² day⁻¹, and 33±20 to 309±73 μmol Si m⁻² day⁻¹. Although PP rates within Cyclone Opal were elevated by a factor of 2–3, PC and PN fluxes were the same, within error, inside and outside of Cyclone Opal. The ratio of PC export to PP remained surprisingly low at <0.03 and similar to those measured in surrounding waters. In contrast, bSiO₂ fluxes within the eddy core were three times higher. Detailed analyses of ²³⁴Th depth profiles consistently showed excess ²³⁴Th at 100–175 m, associated with the remineralization and possible accumulation of suspended and dissolved organic matter from the surface. We suggest that strong microzooplankton grazing facilitated particulate organic matter recycling and resulted in the export of empty diatom frustules. Thus, while eddies may increase PP, they do not necessarily increase PC and PN export to deep waters. This may be a general characteristic of wind-driven cyclonic eddies of the North Pacific Subtropical Gyre and suggests that eddies may preferentially act as a silica pump, thereby playing an important role in promoting silicic-acid limitation in the region.  相似文献   

Numerical determination of pressure-dependent effective thermal conductivity in Berea sandstone     

Mirko Siegert  Marcel Gurris  Claudia Finger  Erik H. Saenger 《Geophysical Prospecting》2022,70(1):152-172

In this paper, the methods of digital rock physics are applied to determine pressure-dependent effective thermal conductivity in rock samples. Simulations are performed with an in-house three-dimensional finite volume code. In the first step, four numerical models are derived from a given tomographic scan of Berea sandstone. Consequently, simulations of the thermal conductivity at ambient conditions are performed and validated with experimental data. In a second step, a new workflow for the determination of the pressure-dependent thermal conductivity in rock samples is elaborated, tested and calibrated. Results originating from the derived workflow show very good agreement with experimental data.  相似文献   

Can agriculture support climate change adaptation, greenhouse gas mitigation and rural livelihoods? insights from Kenya     

Elizabeth Bryan  Claudia Ringler  Barrack Okoba  Jawoo Koo  Mario Herrero  Silvia Silvestri 《Climatic change》2013,118(2):151-165

Changes in the agriculture sector are essential to mitigate and adapt to climate change, meet growing food demands, and improve the livelihoods of poor smallholder producers. What agricultural strategies are needed to meet these challenges? To what extent are there synergies among these strategies? This paper examines these issues for smallholder producers in Kenya across several agroecological zones. Several practices emerge as triple wins, supporting climate adaptation, greenhouse gas mitigation, and profitability goals. In particular, integrated soil fertility management and improved livestock feeding are shown to provide multiple benefits across all agroecological zones examined. Triple wins of other agricultural practices are limited to specific agroecological zones. Irrigation and soil and water conservation, for example, are essential for adaptation, mitigation, and profitability in arid areas. The results suggest that agricultural investments targeted toward these triple-win strategies will have the greatest payoff in terms of increased resilience of farm and pastoralist households and global climate change mitigation. To reap the benefits of triple-win strategies will require that policymakers, researchers, and practitioners move away from isolated approaches focused on either adaptation or mitigation or rural income generation toward a more holistic assessment of joint strategies as well as their tradeoffs and synergies.  相似文献   

The climatic characteristics of extreme precipitations for short-term intervals in the watershed of Lake Maggiore     

Helmi Saidi  Marzia Ciampittiello  Claudia Dresti  Giorgio Ghiglieri 《Theoretical and Applied Climatology》2013,113(1-2):1-15

Alpine and Mediterranean areas are undergoing a profound change in the typology and distribution of rainfall. In particular, there has been an increase in consecutive non-rainy days, and an escalation of extreme rainy events. The climatic characteristic of extreme precipitations over short-term intervals is an object of study in the watershed of Lake Maggiore, the second largest freshwater basin in Italy (located in the north-west of the country) and an important resource for tourism, fishing and commercial flower growing. The historical extreme rainfall series with high-resolution from 5 to 45 min and above: 1, 2, 3, 6, 12 and 24 h collected at different gauges located at representative sites in the watershed of Lake Maggiore, have been computed to perform regional frequency analysis of annual maxima precipitation based on the L-moments approach, and to produce growth curves for different return-period rainfall events. Because of different rainfall-generating mechanisms in the watershed of Lake Maggiore such as elevation, no single parent distribution could be found for the entire study area. This paper concerns an investigation designed to give a first view of the temporal change and evolution of annual maxima precipitation, focusing particularly on both heavy and extreme events recorded at time intervals ranging from few minutes to 24 h and also to create and develop an extreme storm precipitation database, starting from historical sub-daily precipitation series distributed over the territory. There have been two-part changes in extreme rainfall events occurrence in the last 23 years from 1987 to 2009. Little change is observed in 720 min and 24-h precipitations, but the change seen in 5, 10, 15, 20, 30, 45, 60, 120, 180 and 360 min events is significant. In fact, during the 2000s, growth curves have flattened and annual maxima have decreased.  相似文献   

Moisture source for the Amazon Basin: a study of contrasting years     

Prakki Satyamurty  Claudia Priscila Wanzeler da Costa  Antonio Ocimar Manzi 《Theoretical and Applied Climatology》2013,111(1-2):195-209

The regions where the divergence of vertically integrated water vapor flux, averaged over a season or a year, is positive (negative) are sources (sinks) of moisture for the atmosphere. An aerial river is defined as a stream of strong water vapor flux connecting a source and a sink. Moisture flux, its divergence, and sources and sinks over the tropics of South and Central America and the adjoining Atlantic Ocean are obtained for dry years and for wet years in the Amazon Basin. Results show that the Amazon Basin is a sink region for atmospheric moisture in all seasons and that there are two source regions for the moisture in the basin, one situated in the South Atlantic and the other in the North Atlantic, both located equator-ward of the respective subtropical high-pressure centers. The convergence of moisture increases over the Amazon Basin in austral summer, and at the same time it decreases in the Pacific and Atlantic ITCZs. Box model calculations reveal that the wet years, on the average, present about 55 % more moisture convergence than the dry years in the Amazon Basin. A reduction in the moisture inflow across the eastern and northern boundaries of the basin (at 45°W and at the Equator, respectively) and an increase in the outflow across the southern boundary (at 15°S) lead to dry conditions. The annual mean contribution of moisture convergence to the precipitation over the Amazon Basin is estimated to be 70 %. In the dry years, it lowers to around 50 %. The net convergence of water vapor flux over the basin is a good indicator of the wet or dry condition.  相似文献