Ageing of Dissolved Halogenated Humic Substances and the Microbiological Influence on this Process     

K. G. Heumann  G. Rdlinger  M. Erbes  I. Heiber  U. Obst  Z. Filip  H. Claus 《洁净——土壤、空气、水》2000,28(4):193-201

The distribution of halogens in various fractions of humic substances (HS), separated by their molecular weight, was found to be different for the different halogens. This was demonstrated for chlorine, bromine, and iodine in sewage and brown water samples by applying inductively coupled plasma mass spectrometry coupled with size‐exclusion chromatography. Quantification of the different fractions of iodinated humic substances was obtained by quadrupole mass spectrometry in connection with the isotope dilution technique using an ¹²⁹I‐enriched spike solution. Quantitative analysis was not possible for the corresponding chlorine and bromine species because of spectrometric interferences in the quadrupole instrument. The ageing of HS/halogen species was followed with respect to possible transformations of these species in a ground and sewage water sample up to eight weeks. Even if a distinct structural variation of the humic substance was observed with time by measuring the UV absorption, chlorine remained in the same molecular weight fraction and only a small change was found for the HS/bromine species after eight weeks. In contrast to these findings a substantial transformation of HS/iodine compounds took place, which demonstrated that the transfer probability of halogens from one to another HS fraction is increased with decreasing strength of the halogen bond to carbon. By comparing the results of an original sewage water sample with a filtered one and with another one which was enriched by microorganisms cultivated from the same original sample, a strong microbiological influence on the transformation of HS/iodine species was found. A quantitative balance of the corresponding HS/iodine fractions was calculated for an ageing period of eight weeks showing that iodine was preferably transferred to newly formed UV active HS substances of high molecular weight. In total, no iodine was released from the humic substances.  相似文献   

Coordinated Ocean-ice Reference Experiments (COREs)     

Stephen M. Griffies  Arne Biastoch  Claus Böning  Frank Bryan  Gokhan Danabasoglu  Eric P. Chassignet  Matthew H. England  Rüdiger Gerdes  Helmuth Haak  Robert W. Hallberg  Wilco Hazeleger  Johann Jungclaus  William G. Large  Gurvan Madec  Anna Pirani  Bonita L. Samuels  Markus Scheinert  Alex Sen Gupta  Camiel A. Severijns  Harper L. Simmons  Jianjun Yin 《Ocean Modelling》2009,26(1-2):1-46

Coordinated Ocean-ice Reference Experiments (COREs) are presented as a tool to explore the behaviour of global ocean-ice models under forcing from a common atmospheric dataset. We highlight issues arising when designing coupled global ocean and sea ice experiments, such as difficulties formulating a consistent forcing methodology and experimental protocol. Particular focus is given to the hydrological forcing, the details of which are key to realizing simulations with stable meridional overturning circulations.The atmospheric forcing from [Large, W., Yeager, S., 2004. Diurnal to decadal global forcing for ocean and sea-ice models: the data sets and flux climatologies. NCAR Technical Note: NCAR/TN-460+STR. CGD Division of the National Center for Atmospheric Research] was developed for coupled-ocean and sea ice models. We found it to be suitable for our purposes, even though its evaluation originally focussed more on the ocean than on the sea-ice. Simulations with this atmospheric forcing are presented from seven global ocean-ice models using the CORE-I design (repeating annual cycle of atmospheric forcing for 500 years). These simulations test the hypothesis that global ocean-ice models run under the same atmospheric state produce qualitatively similar simulations. The validity of this hypothesis is shown to depend on the chosen diagnostic. The CORE simulations provide feedback to the fidelity of the atmospheric forcing and model configuration, with identification of biases promoting avenues for forcing dataset and/or model development.  相似文献   

Assessment of susceptibility to landslides through geographic information systems and the logistic regression model     

Riegel  Roberta Plangg  Alves  Darlan Daniel  Schmidt  Bruna Caroline  de Oliveira  Guilherme Garcia  Haetinger  Claus  Osório  Daniela Montanari Migliavacca  Rodrigues  Marco Antônio Siqueira  de Quevedo  Daniela Muller 《Natural Hazards》2020,103(1):497-511

Natural Hazards - The increase in the frequency of natural disasters in recent years and its consequent social, economic and environmental impacts make it possible to prioritize areas of risk as an...  相似文献   

Large microplastic particles in sediments of tributaries of the River Thames,UK – Abundance,sources and methods for effective quantification     

Alice A. Horton  Claus Svendsen  Richard J. Williams  David J. Spurgeon  Elma Lahive 《Marine pollution bulletin》2017,114(1):218-226

Sewage effluent input and population were chosen as predictors of microplastic presence in sediments at four sites in the River Thames basin (UK). Large microplastic particles (1 mm–4 mm) were extracted using a stepwise approach to include visual extraction, flotation and identification using Raman spectroscopy. Microplastics were found at all four sites. One site had significantly higher numbers of microplastics than other sites, average 66 particles 100 g^? 1, 91% of which were fragments. This site was downstream of a storm drain outfall receiving urban runoff; many of the fragments at this site were determined to be derived of thermoplastic road-surface marking paints. At the remaining three sites, fibres were the dominant particle type. The most common polymers identified included polypropylene, polyester and polyarylsulphone. This study describes two major new findings: presence of microplastic particles in a UK freshwater system and identification of road marking paints as a source of microplastics.

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This study is the first to quantify microplastics of any size in river sediments in the UK and links their presence to terrestrial sources including sewage and road marking paints.  相似文献   

The emergence of equatorial deep jets in an idealised primitive equation model: an interpretation in terms of basin modes     

Jan-Dirk Matthießen  Richard John Greatbatch  Martin Claus  François Ascani  Peter Brandt 《Ocean Dynamics》2017,67(12):1511-1522

Ocean circulation models do not generally exhibit equatorial deep jets (EDJs), even though EDJs are a recognised feature of the observed ocean circulation along the equator and they are thought to be important for tracer transport along the equator and even equatorial climate. EDJs are nevertheless found in nonlinear primitive equation models with idealised box geometry. Here we analyse several such model runs. We note that the variability of the zonal velocity in the model is dominated by the gravest linear equatorial basin mode for a wide range of baroclinic vertical normal modes and that the EDJs in the model are dominated by energy contained in vertical modes between 10 and 20. The emergence of the EDJs is shown to involve the linear superposition of several such neighbouring basin modes. Furthermore, the phase of these basin modes is set at the start of the model run and, in the case of the reference experiment, the same basin modes can be found in a companion experiment in which the amplitude of the forcing has been reduced by a factor of 1000. We also argue that following the spin-up, energy must be transferred between different vertical modes. This is because the model simulations are dominated by downward phase propagation following the spin-up whereas our reconstructions imply episodes of upward and downward propagation. The transfer of energy between the vertical modes is associated with a decadal modulation of the EDJs.  相似文献   

Volcanic stratigraphy of a high-altitude Mammuthus columbi (Tlacotenco,Sierra Chichinautzin), Central México     

Marie-Noelle Guilbaud  Lilia Arana-Salinas  Claus Siebe  Luis Alberto Barba-Pingarrón  Agustín Ortiz 《Bulletin of Volcanology》2015,77(3):1-16

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A high-resolution stellar library for evolutionary population synthesis     

Lucimara P. Martins  Rosa M. González Delgado  Claus Leitherer  Miguel Cerviño  Peter Hauschildt 《Monthly notices of the Royal Astronomical Society》2005,358(1):49-65

We present a library of 1654 high-resolution stellar spectra, with a sampling of 0.3 Å and covering the wavelength range from 3000 to 7000 Å. The library was computed with the latest improvements in stellar atmospheres, incorporating non-local thermodynamic equilibrium (non-LTE) line-blanketed models for hot, massive  ( T _eff≥ 27 500 K)  and line-blanketed models for cool  (3000 ≤ T _eff≤ 4500 K)  stars. The total coverage of the grid is  3000 K ≤ T _eff≤ 55 000 K  and  −0.5 ≤ log g ≤ 5.5  , for four chemical abundance values: twice solar, solar, half solar and 1/10 solar. Evolutionary synthesis models using this library are presented in a companion paper. We tested the general behaviour of the library by calculating and comparing equivalent widths of numerous H and He  i lines, and some of the commonly used metallic indices. We also compared the library with the empirical libraries STELIB and Indo-US. The full set of the synthetic stellar spectra is available from our websites ( http://www.iaa.csic.es/~rosa and http://www.astro.iag.usp.br/~lucimara/library.htm ).  相似文献   

南极中山站至Dome A剖面表面雪样氧同位素组成          下载免费PDF全文

阎明  李院生  谭德军  温家洪  汪大立  Claus U.Hammer  孙波  康建成  刘雷保 《极地研究》2001,13(3):159-164

运用质谱技术 ,测定了南极中山站至 Dome A剖面 1 998/1 999年度表面雪样氧同位素组成。结果表明 ,表面雪样氧同位素组成变化范围相当大 (- 2 2 .5 1‰ - - 5 0 .6 7‰ ) ,且具有随距中山站距离逐渐增大、海拔高度逐渐增加而逐渐减小的趋势。线性回归分析显示表面雪样氧同位素组成与距中山站距离、海拔高度和纬度存在着很好的相关性 ,这实际上反映出稳定同位素组成和温度之间的密切联系  相似文献   

“Galileo Galilei” (GG) a small satellite to test the equivalence principle of Galileo, Newton and Einstein     

Anna M. Nobili  Gian Luca Comandi  Suresh Doravari  Donato Bramanti  Rajeev Kumar  Francesco Maccarrone  Erseo Polacco  Slava G. Turyshev  Michael Shao  John Lipa  Hansjoerg Dittus  Claus Laemmerzhal  Achim Peters  Jurgen Mueller  C. S. Unnikrishnan  Ian W. Roxburgh  Alain Brillet  Christian Marchal  Jun Luo  Jozef van der Ha  Vadim Milyukov  Valerio Iafolla  David Lucchesi  Paolo Tortora  Paolo De Bernardis  Federico Palmonari  Sergio Focardi  Dino Zanello  Salvatore Monaco  Giovanni Mengali  Luciano Anselmo  Lorenzo Iorio  Zoran Knezevic 《Experimental Astronomy》2009,23(2):689-710

“Galileo Galilei” (GG) is a small satellite designed to fly in low Earth orbit with the goal of testing the Equivalence Principle—which is at the basis of the General Theory of Relativity—to 1 part in 10¹⁷. If successful, it would improve current laboratory results by 4 orders of magnitude. A confirmation would strongly constrain theories; proof of violation is believed to lead to a scientific revolution. The experiment design allows it to be carried out at ambient temperature inside a small 1-axis stabilized satellite (250 kg total mass). GG is under investigation at Phase A-2 level by ASI (Agenzia Spaziale Italiana) at Thales Alenia Space in Torino, while a laboratory prototype (known as GGG) is operational at INFN laboratories in Pisa, supported by INFN (Istituto Nazionale di fisica Nucleare) and ASI. A final study report will be published in 2009.  相似文献   

P_n anisotropy studies in northern Britain and the eastern and western United States     

David Bamford  Martin Jentsch  Claus Prodehl 《Geophysical Journal International》1979,57(2):397-429

Summary. Available seismic refraction data from three different continental areas, northern Britain and the eastern and western United States, has been studied for possible P_n , velocity anisotropy using the methods described by Bamford. There are various deficiencies in the time—distance data used in each case but, while the uppermost mantle beneath northern Britain and the eastern United States seems to be isotropic within the limits of measurement error, there is a small but significant anisotropy beneath the western United States.
Both the amount (up to 3 per cent) and the direction (70–80° east of north) of this anisotropy are very similar to the results obtained in the Pacific Ocean off California. We tentatively conclude that this anisotropy is present as a consequence of the subduction of oceanic lithosphere beneath the western United States.  相似文献