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91.
The research evaluated the information content of spectral reflectance (laboratory and airborne data) for the estimation of needle chlorophyll (CAB) and nitrogen (CN) concentration in Norway spruce (Picea abies L. Karst.) needles. To identify reliable predictive models different types of spectral transformations were systematically compared regarding the accuracy of prediction. The results of the cross-validated analysis showed that CAB can be well estimated from laboratory and canopy reflectance data. The best predictive model to estimate CAB was achieved from laboratory spectra using continuum-removal transformed data (R2cv = 0.83 and a relative RMSEcv of 8.1%, n = 78) and from hyperspectral HyMap data using band-depth normalised spectra (R2cv = 0.90, relative RMSEcv = 2.8%, n = 13). Concerning the nitrogen concentration, we observed somewhat weaker relations, with however still acceptable accuracies (at canopy level: R2cv = 0.57, relative RMSEcv = 4.6%). The wavebands selected in the regression models to estimate CAB were typically located in the red edge region and near the green reflectance peak. For CN, additional wavebands related to a known protein absorption feature at 2350 nm were selected. The portion of selected wavebands attributable to known absorption features strongly depends on the type of spectral transformation applied. A method called “water removal” (WR) produced for canopy spectra the largest percentage of wavebands directly or indirectly related to known absorption features. The derived chlorophyll and nitrogen maps may support the detection and the monitoring of environmental stressors and are also important inputs to many bio-geochemical process models.  相似文献   
92.
Numerous paleoecological questions concern the mobility of ancient fauna in eastern Beringia. Strontium (Sr) isotope ratio (87Sr/86Sr) analysis has emerged as a powerful tracer for determining the provenance of ancient biological materials. However, it is important to characterize 87Sr/86Sr variation across a landscape. We measured the 87Sr/86Sr composition of teeth from present-day, herbivorous rodents (n = 162) sampled from across eastern Beringia to estimate bio-available 87Sr/86Sr values. We compiled these data with the very limited number of previously published 87Sr/86Sr values from the region. We then used this dataset and a machine learning, random-forest regression to predict bio-available 87Sr/86Sr variations across eastern Beringia. As a case study using our new 87Sr/86Sr map (isoscape), we measured the 87Sr/86Sr and oxygen stable isotope values (δ18O) of five radiocarbon-dated steppe bison from eastern Beringia and compared these to our 87Sr/86Sr isoscape and a δ18O isoscape to estimate the probable landscape use of these ancient fauna. Our model and isoscape provide important foundations for a wide range of additional applications, including studies of the paleo-mobility of other fauna, ancient people and present-day fauna in eastern Beringia.  相似文献   
93.
Integrating the Red Edge channel in satellite sensors is valuable for plant species discrimination. Sentinel-2 MSI and Rapid Eye are some of the new generation satellite sensors that are characterized by finer spatial and spectral resolution, including the red edge band. The aim of this study was to evaluate the potential of the red edge band of Sentinel-2 and Rapid Eye, for mapping festuca C3 grass using discriminant analysis and maximum likelihood classification algorithms. Spectral bands, vegetation indices and spectral bands plus vegetation indices were analysed. Results show that the integration of the red edge band improved the festuca C3 grass mapping accuracy by 5.95 and 4.76% for Sentinel-2 and Rapid Eye when the red edge bands were included and excluded in the analysis, respectively. The results demonstrate that the use of sensors with strategically positioned red edge bands, could offer information that is critical for the sustainable rangeland management.  相似文献   
94.
Microbial Mn(II) oxidation kinetics in response to oxygen concentration were assessed in suboxic zone water at six sites throughout the Black Sea. Mn(II) oxidation rates increased asymptotically with increasing oxygen concentration, consistent with Michaelis-Menten enzyme kinetics. The environmental half-saturation constant, KE, of Mn(II) removal (oxidation) varied from 0.30 to 10.5 μM dissolved oxygen while the maximal environmental rate, VE−max, ranged from 4 to 50 nM h−1. These parameters varied spatially and temporally, consistent with a diverse population of enzymes catalyzing Mn oxide production in the Black Sea. Coastally-influenced sites produced lower KE and higher VE−max constants relative to the Western and Eastern Gyre sites. In the Bosporus Region, the Mn(II) residence time calculated using our KE and VE−max values with 0.1 μM oxygen was 4 days, 25-fold less than previous estimates. Our results (i) indicate that rapid Mn(II) oxidation to solid phase Mn oxides in the Black Sea’s suboxic zone is stimulated by oxygen concentrations well below the 3-5 μM concentration reliably detected by current oceanographic methods, (ii) suggest the existence of multiple, diverse Mn(II)-oxidizing enzymes, (iii) are consistent with shorter residence times than previously calculated for Mn(II) in the suboxic zone and (iv) cast further doubt on the existence of proposed reactions coupling solid phase Mn oxide production to electron acceptors other than oxygen.  相似文献   
95.
Domenico solution--is it valid?   总被引:1,自引:0,他引:1  
The Domenico solution is widely used in several analytical models for simulating ground water contaminant transport scenarios. Unfortunately, many textbook as well as journal article treatments of this approximate solution are full of empirical statements that are developed without mathematical rigor. For this reason, a rigorous analysis of this solution is warranted. In this article, we present a mathematical method to derive the Domenico solution and explore its limits. Our analysis shows that the Domenico solution is a true analytical solution when the value of longitudinal dispersivity is zero. For nonzero longitudinal dispersivity values, the Domenico solution will introduce a finite amount of error. We use an example problem to quantify the nature of this error and suggest some general guidelines for the appropriate use of this solution.  相似文献   
96.
In this note, we present a public domain analytical reactive transport modeling tool (ART3D, version 2.0). The tool is developed in FORTRAN and can be used for solving a system of a set of partial differential equations coupled with a first-order reaction network. ART3D uses a novel analytic solution technique proposed by Clement. The new software includes options for performing Monte Carlo simulations and automated parameter estimation.  相似文献   
97.
98.
The interconnection between weather and climate and the performance, well-being, and human health cannot be overemphasized. The relationship between them is of both local and global significance. Information about weather, climate, and thermal environment is very important to human health and medical practitioners. The most crucial environmental information needed by medical practitioners and for maintaining human health, performance, and well-being are thermal conditions. The study used meteorological variables: air temperature, relative humidity, wind speed, solar radiation, and RayMan model as an analytical tool to compute physiologically equivalent temperature (PET) in order to assess thermo-physiological thresholds in Ondo State. The study revealed that there are marked spatial and seasonal variations in the environmental thermal conditions in the study area. The results of physiologically equivalent temperature for different grades of thermal sensation and physiological stress on human beings indicate that about 60 % of the total study period (1998–2008) fall under physiological stress level of moderate heat stress (PET 31–36 °C). In derived savannah, 32.6 % out of the total study period was under strong heat stress. In view of this, the study concluded that Ondo State may likely be prone to heat-related ailments and that some of the death recorded in the State, in recent times, may be heat-related mortality, but this is difficult to ascertain because there is no postmortem records in Nigeria where it could be confirmed. This type of study is relevant to help government to improve health care interventions and achieve Millennium Development Goals in health sector.  相似文献   
99.
Climate change effects are expected to substantially raise the average sea level. It is widely assumed that this raise will have a severe adverse impact on saltwater intrusion processes in coastal aquifers. In this study we hypothesize that a natural mechanism, identified here as the “lifting process,” has the potential to mitigate, or in some cases completely reverse, the adverse intrusion effects induced by sea-level rise. A detailed numerical study using the MODFLOW-family computer code SEAWAT was completed to test this hypothesis and to understand the effects of this lifting process in both confined and unconfined systems. Our conceptual simulation results show that if the ambient recharge remains constant, the sea-level rise will have no long-term impact (i.e., it will not affect the steady-state salt wedge) on confined aquifers. Our transient confined-flow simulations show a self-reversal mechanism where the wedge which will initially intrude into the formation due to the sea-level rise would be naturally driven back to the original position. In unconfined systems, the lifting process would have a lesser influence due to changes in the value of effective transmissivity. A detailed sensitivity analysis was also completed to understand the sensitivity of this self-reversal effect to various aquifer parameters.  相似文献   
100.
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