A new laboratory technique for determining the compressional wave properties of marine sediments at sonic frequencies and in situ pressures     

Clive McCann  Jeremy Sothcott  Angus I. Best 《Geophysical Prospecting》2014,62(1):97-116

We describe a new laboratory technique for measuring the compressional wave velocity and attenuation of jacketed samples of unconsolidated marine sediments within the acoustic (sonic) frequency range 1–10 kHz and at elevated differential (confining – pore) pressures up to 2.413 MPa (350 psi). The method is particularly well suited to attenuation studies because the large sample length (up to 0.6 m long, diameter 0.069 m) is equivalent to about one wavelength, thus giving representative bulk values for heterogeneous samples. Placing a sediment sample in a water‐filled, thick‐walled, stainless steel Pulse Tube causes the spectrum of a broadband acoustic pulse to be modified into a decaying series of maxima and minima, from which the Stoneley and compressional wave, velocity and attenuation of the sample can be determined. Experiments show that PVC and copper jackets have a negligible effect on the measured values of sediment velocity and attenuation, which are accurate to better than ± 1.5% for velocity and up to ± 5% for attenuation. Pulse Tube velocity and attenuation values for sand and silty‐clay samples agree well with published data for similar sediments, adjusted for pressure, temperature, salinity and frequency using standard equations. Attenuation in sand decreases with pressure to small values below Q^?1 = 0.01 (Q greater than 100) for differential pressures over 1.5 MPa, equivalent to sub‐seafloor depths of about 150 m. By contrast, attenuation in silty clay shows little pressure dependence and intermediate Q^?1 values between 0.0206–0.0235 (Q = 49–43). The attenuation results fill a notable gap in the grain size range of published data sets. Overall, we show that the Pulse Tube method gives reliable acoustic velocity and attenuation results for typical marine sediments.  相似文献   

Secondary Ion Mass Spectrometry Methodology for Isotopic Ratio Measurement of Micro‐Grains in Thin Sections: True Grain Size Estimation and Deconvolution of Inter‐Grain Size Gradients and Intra‐Grain Radial Gradients     

Clive Jones  David A. Fike  Katja M. Meyer 《Geostandards and Geoanalytical Research》2019,43(1):61-76

In a thin section, grains that were approximately spherical in situ appear circular in cross section, and the distribution of apparent diameters frequently assumed to be their size distribution. Scanning ion imaging by secondary ion mass spectrometry (SIMS) is capable of providing precise (< 1‰) stable isotope ratio measurements of such grains, but, importantly, also registers their rate of evolution in apparent size as they are ablated by the primary beam. By assessing rates of radius change with depth, the described methodology enables the ‘true’ size of grains to be estimated, as well as the distance of the sectioned surface from the original grain centre. Transects in three dimensions are made possible, and this capability enables better identification (and thus separation) of both inter‐grain chemical signatures as a function of grain size, and intra‐grain radial trends. In this example, we highlight the specific application to pyrite (FeS₂) minerals, which are frequently analysed by SIMS to determine their inter‐grain and intra‐grain geochemical variations, particularly in their sulfur stable isotopic ratios (δ³⁴S). Benefits of the new methodology over the Faraday cup ‘spot mode’ are described. Data correction algorithms and precision considerations are discussed.  相似文献   

Probing the magma plumbing of Erebus volcano,Antarctica, by open-path FTIR spectroscopy of gas emissions     

Clive Oppenheimer  Philip R. Kyle 《Journal of Volcanology and Geothermal Research》2008

Gas emissions from Erebus volcano, Antarctica, were measured by open-path Fourier transform infrared spectroscopy to understand degassing of its magmatic system. Two degassing phonolite lava lakes were present in the summit crater during observation in December 2004. We report analyses of H₂O, CO₂, CO, SO₂, HF, HCl and OCS, (in order of molar abundance) in the plumes. Variations in the proportions of these species strongly reflect the dynamics of degassing, and sourcing of gas from different depths in the magmatic network. The highest observed ratios of CO₂ and H₂O are consistent with gas extracted from the melt at a depth of up to ∼ 2 km below the lava lakes. Magma degassing above this depth contributes to a higher H₂O/CO₂ proportion in the airborne plume. The ratio therefore reflects the balance of deeper vs. shallower contributions of volatiles and, possibly, a combination of closed- and open-system degassing. We observe a strong contrast in HF content in emissions from the two lava lakes, which we attribute to differing levels of magma ascent and/or cooling and crystallization of the magma supply. Fluxes of all gas species were determined using independent SO₂ flux determinations and measured gas ratios. In the case of CO₂ and water, ∼ 1 and ∼ 0.4 m³ s^− 1, respectively, of parental basanite magma are required to sustain the calculated output. The discrepancy between the two figures is readily explained by sequestration of part of the magma supply at depth such that it only partially degasses its complement of water.  相似文献   

Attenuation of P- and S-waves in limestones   总被引：2，自引：1，他引：1  

Solomon Assefa  Clive McCann  & Jeremy Sothcott 《Geophysical Prospecting》1999,47(3):359-392

Ultrasonic compressional- and shear-wave attenuation measurements have been made on 40, centimetre-sized samples of water- and oil-saturated oolitic limestones at 50 MPa effective hydrostatic pressure (confining pressure minus pore-fluid pressure) at frequencies of about 0.85 MHz and 0.7 MHz respectively, using the pulse-echo method. The mineralogy, porosity, permeability and the distribution of the pore types of each sample were determined using a combination of optical and scanning electron microscopy, a helium porosimeter and a nitrogen permeameter. The limestones contain a complex porosity system consisting of interparticle macropores (dimensions up to 300 microns) and micropores (dimensions 5–10 microns) within the ooids, the calcite cement and the mud matrix. Ultrasonic attenuation reaches a maximum value in those limestones in which the dual porosity system is most fully developed, indicating that the squirt-flow mechanism, which has previously been shown to occur in shaley sandstones, also operates in the limestones. It is argued that the larger-scale dual porosity systems present in limestones in situ could similarly cause seismic attenuation at the frequencies of field seismic surveys through the operation of the squirt-flow mechanism.  相似文献   

Hollowing out the state? Some observations on the restructuring of hospital services in New Zealand   总被引：1，自引：0，他引：1  

J Ross Barnett 《Area》1999,31(3):259-270

Summary This study applies Jessop's idea of the 'hollowed-out' state to an analysis of the restructuring of hospital services in New Zealand. Decentralization of responsibility for the funding and provision of hospital services to regional and local levels has had distinct fiscal and political advantages for the state and is rapidly changing the geography of hospital provision.  相似文献   

Russia and the Modern World: A New Geography     

Ross Barnett 《New Zealand geographer》1999,55(2):78-79

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Two North Sea policies : Danish and Norwegian attitudes compared     

Clive Archer 《Marine Policy》1977,1(4):289-300

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Environmental Stewardship in UK agriculture: A comparison of the environmentally sensitive area programme and the Countryside Stewardship Scheme in South East England   总被引：1，自引：0，他引：1  

Matt Lobley  Clive Potter 《Geoforum》1998,29(4):413-432

Research into the adoption of Environmental Land Management Schemes (ELMS) has typically sought to identify the defining characteristics of participants and the ‘barriers to entry’ that dissuade others from joining. More recently, attention has focused on the motivation of participants and non-participants in helping to understand patterns of participation. This paper compares the pattern of participation in two distinct schemes operating in South East England. Indirect evidence suggests that scheme design and implementation is influencing the type of farmer joining and their motivation for doing so. Results from a survey of farmers also support the idea that the schemes are recruiting from different sections of the farming community. ESA farmers are largely motivated by financial gain, whereas those enrolling land in the Countryside Stewardship Scheme have more clearly defined conservation motives. Although there is also a ‘core’ of resistant non-participants, further changes to the design and delivery of policy could encourage a large number of ‘potential enrolers’ to join.  相似文献   

High-resolution observations of interstellar NaI andKi absorptions towards giants within 200 PC from the sun     

R. Génova  J. E. Beckman  C. D. McKeith  E. Barnett 《Astrophysics and Space Science》1990,171(1-2):235-238

We show here the first results of a programme of observations designed to probe the structure and kinematics of the Local Insterstellar Medium (LISM) using the Queen's University of Belfast Echelle Spectrograph (QUBES) on the 4.2 m William Herschel Telescope.The observations show the potential of the instrument for measuring small column densities, and for precise velocity structure analysis.Paper presented at the 11th European Regional Astronomical Meetings of the IAU on New Windows to the Universe, held 3–8 July, 1989, Tenerife, Canary Islands, Spain.  相似文献   

Infrared and Raman spectra of lunar samples from Apollo 11, 12 and 14     

Clive H. Perry  D. K. Agrawal  E. Anastassakis  R. P. Lowndes  A. Rastogi  N. E. Tornberg 《Earth, Moon, and Planets》1972,4(3-4):315-336

We report the room temperature infrared reflectance spectra of several lunar surface rocks in the form of polished slices or butt ends. The spectra were obtained over the frequency range 20-2000 cm^–1 throughout the mid and far infrared (5-500µ) region of the electromagnetic spectrum where the fundamental internal and lattice vibrational modes of all minerals and rocks occur.Some fines samples were examined as pressed pellets and their reflectivities compared with the bulk samples. Several terrestrial minerals and rocks were also investigated. Kramers-Kronig analyses of these reflectance spectra were undertaken and the dispersion of the dielectric response ( and ) and the optical constants (n andk) have been determined over this frequency range. The low frequency and high frequency (infrared) dielectric constants were also calculated from the reflectance data.Raman light scattering measurements were made on all the samples supplied from the first three Apollo missions. Large background scattering proved to be the greatest experimental problem. Successful spectra in nearly all cases were obtained from small crystalline inclusions imbedded in the main ground mass. Some crystalline bulk rocks containing many very fine inclusions gave identifiable spectra and at least three different types were obtained.Supported by NASA Grant NGR 22-011-069 and by a Northeastern University Grant for Basic Research.  相似文献