Basalt generation at the Apollo 12 site,Part 1: New data,classification, and re-evaluation     

Clive R. Neal  Matthew D. Hacker  Gregory A. Snyder  Lawrence A. Taylor  Yun-Gang Liu  Roman A. Schmitt 《Meteoritics & planetary science》1994,29(3):334-348

Abstract— New data are reported from five previously unanalyzed Apollo 12 mare basalts that are incorporated into an evaluation of previous petrogenetic models and classification schemes for these basalts. This paper proposes a classification for Apollo 12 mare basalts on the basis of whole-rock Mg# [molar 100*(Mg/(Mg+Fe))] and Rb/Sr ratio (analyzed by isotope dilution), whereby the ilmenite, olivine, and pigeonite basalt groups are readily distinguished from each other. Scrutiny of the Apollo 12 feldspathic “suite” demonstrates that two of the three basalts previously assigned to this group (12031, 12038, 12072) can be reclassified: 12031 is a plagioclase-rich pigeonite basalt (Nyquist et al, 1979); and 12072 is an olivine basalt Only basalt 12038 stands out as a unique sample (Nyquist et al., 1981) to the Apollo 12 she, but whether this represents a single sample from another flow at the Apollo 12 site or is exotic to this site is equivocal. The question of whether the olivine and pigeonite basalt suites are co-magmatic is addressed by incompatible trace-element chemistry: the trends defined by these two suites when Co/Sm and Sm/Eu ratios are plotted against Rb/Sr ratio demonstrate that these two basaltic types cannot be co-magmatic. Crystal fractionation/accumulation paths have been calculated and show that neither the pigeonite, olivine, or ilmenite basalts are related by this process. Each suite requires a distinct and separate source region. This study also examines sample heterogeneity and the degree to which whole-rock analyses are representative, which is critical when petrogenetic interpretation is undertaken. Sample heterogeneity has been investigated petrographically (inhomogeneous mineral distribution) with consideration of duplicate analyses, and whether a specific sample (using average data) plots consistently upon a fractionation trend when a number of different compositional parameters are considered. Using these criteria, four basalts have been identified where reported analyses are not representative of the whole-rock composition: 12005, an ilmenite basalt; 12006 and 12036, olivine basalts; and 12031 previously classified as a feldspathic basalt, but reclassified as part of the pigeonite suite (Nyquist et al., 1979).  相似文献   

Estimating quartz fabrics from piezoelectric measurements     

J. R. Bishop 《Mathematical Geology》1981,13(4):261-289

An aggregate of piezoelectric minerals may itself be piezoelectric if the minerals are suitably aligned. Thus quartz-bearing rocks may be piezoelectric, since quartz is one such mineral. It has been shown that some rocks do possess this effect, termed a piezoelectric fabric (Bishop, 1981). The type of piezoelectric fabric may be determined by matching experimental data to theoretical models of piezoelectric fabrics. These theoretical models of pure quartz aggregates are derived by considering the symmetry of the preferred crystallographic directions of the aggregate grains. From the symmetry, the piezoelectric matrix of the model may be determined. The best-fitting model and the orientation of its fabric is obtained by equating the experimental data to each model in turn. For each model, the best fitting fabric orientation is determined by using an inversion routine. If the experimental data are due to a piezoelectric fabric and not to some random or nonpolar distribution of grains, the fabric type (c-axis point maximum or large-circle girdle) and its orientation with respect to the specimen may be determined. The positions and polarities of the quartz a-axes are also specified. A statistical examination of results from a quartz-mylonite shows that the problem of piezoelectric model fitting is well posed, in that the Eulerian angles that specify the fabric orientation are fairly independent important parameters and a sufficiently close fit of the model to the data can be obtained to determine the fabric.  相似文献   

Verifying the Integrity of Annular and Back-Filled Seals for Vadose-Zone Monitoring Wells     

Frank M. Dunnivant  Indrek Porro  Carolyn Bishop  Joel Hubbell  John R. Giles  Meredith E. Newman 《Ground water》1997,35(1):140-148

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Long-term changes in zooplankton biomass concentration and mean size over the Northwest European shelf inferred from Continuous Plankton Recorder data   总被引：3，自引：0，他引：3  

Pitois  Sophie G.; Fox  Clive J. 《ICES Journal of Marine Science》2006,63(5):785-798

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Comparison of wind-stress algorithms and their influence on wind-stress curl using buoy measurements over the shelf off Bodega Bay, California     

Adam Kochanski  Darko Kora in  Clive E. Dorman 《Deep Sea Research Part II: Topical Studies in Oceanography》2006,53(25-26):2865

The main objectives of this study were to compare three wind-stress algorithms of varying intricacy and estimate the extent to which each method altered computed wind-stress curl. The algorithms included (1) a simple bulk formula for neutral conditions that is dependent only on wind velocity components; (2) a formula that in addition to dependence on wind components includes a simplified effect of thermal stability through differences in air and sea temperatures; and (3) an algorithm that includes full treatment of dynamics and atmospheric stability. Data for the analysis were from a field program that used a special buoy network off Bodega Bay during 28 June–4 August 2001.A diamond-shaped setup of five closely separated buoys in Bodega Bay allowed for one of the first attempts to compute wind-stress curl over the ocean using buoy measurements. Based on an analysis of the available dataset, the marine layer over Bodega Bay is characterized by positive wind-stress curl with a median value around 0.2 Pa (100 km)⁻¹ and maximum values reaching 2.5 Pa (100 km)⁻¹. Positive wind-stress curl was observed for all wind speed conditions, whereas negative wind-stress curl episodes were associated mostly with low-wind conditions.Comparison of wind-stress curl computed using the three algorithms showed that differences among them can be significant. The first and third algorithms indicated similar stress curl (difference around 10%), but the differences between these two and the second algorithm were much higher (approximately 40%). The reason for the difference is the stability correction, which in the third algorithm strongly decreases with an increase in wind speeds, but stays at a similar level for all wind speeds in the second algorithm. Consequently, for higher wind speeds the variability of wind stress calculated using the second algorithm is greater than for the other two algorithms, causing significant differences in computed wind-stress curl (root mean-square error equal to 0.19 Pa (100 km)⁻¹).Despite the apparent biases in computed wind stress and wind-stress curl among the algorithms, all of them show a significant trend of decreasing sea-surface temperature (SST) with increasing wind-stress curl. The bootstrapping analysis has revealed that both the along-shore wind stress and wind-stress curl have noticeable correlation with the changes in the sea-surface temperature as an indirect indication of the upwelling. An additional analysis, based on the low-pass filtered data, showed also significant agreement between the measured divergence in the cross-shore surface transport and the wind-stress curl computed for all three algorithms.  相似文献   

Managerial decisions as experiments: an opportunity to determine the ecological impact of boat-generated waves on macrobenthic infauna     

M.J. Bishop  M.G. Chapman 《Estuarine, Coastal and Shelf Science》2004,61(4):613-622

A previous correlative study showed that assemblages of macrobenthic infauna and abundances of common taxa on intertidal mudflats differed between a no-wash zone, where ferries had to minimize production of wash, and places where the production of wash was unrestricted (wash zone). This suggested that boat-generated waves (wash) are important in determining the structure of these assemblages. Causality between wash and the observed patterns could not, however, be unambiguously established, due to the absence of ‘before’ data. Here, a managerial decision to stop ferry services on the upper Parramatta River, Sydney, Australia during the 2000 Olympics was used as the basis for a manipulative experiment to examine the effects of changes in the amount of wash on these fauna. It was hypothesized that if wash is important in structuring infaunal assemblages, assemblages in the wash zone would become more similar to those of the no-wash zone following removal of the disturbing force, i.e. the ferry service. Similarly, if the smaller abundances of capitellids, nereids and spionids in the wash zone are caused by this disturbance, abundances should increase in the wash zone during the stoppage and decrease following the return of services. As hypothesized, assemblages within the wash zone became more similar to those of the no-wash zone following the temporary removal of the ferry services. Following the return of ferries, assemblages changed back towards (although not reaching) their previous state. Abundances of the polychaete families Nereididae, Capitellidae and Spionidae also increased at some sites during the cessation, although this pattern was not found in all sites and there was no general response to the cessation of wash as had been predicted. These results indicate that wash is important in structuring assemblages of macrobenthic infauna, although responses of individual taxa are more idiosyncratic. More importantly, they show that manipulations, resulting from managerial decisions, can be treated as testable hypotheses and utilized by scientists as experiments to test for causal relationships.  相似文献   

Elusive security: The military and political geography of South Lebanon     

Clive H. Schofield 《GeoJournal》1993,31(2):149-161

Israel's quest for security on its northern border with Lebanon has a history dating back to the foundation of the Palestine mandate. In the early period from the First World War to the end of the 1960s the quest was dominated with attaining economic and environmental security by seeking to acquire rights to the waters of South Lebanon. Recent decades in contrast have witnessed the rise in importance of border security and strategic security requirements in the face of military threats to northern Israel. Israel's interventionist policy in South Lebanon has been formalised to include a permanent presence on Lebanese territory in the form of the security zone. It is argued that despite the positive events that have occurred in the region in the early 1990s, it remains unlikely that Israel will easily relinquish its security shield in South Lebanon thus ultimately undermining the possibility of moving away from elusive to permanent security.  相似文献   

Reflectance spectroscopy and geochemical analyses of Lake Hoare sediments, Antarctica: implications for remote sensing of the Earth and Mars     

Bishop JL  Koeberl C  Kralik C  Fröschl H  Englert PA  Andersen DW  Pieters CM  Wharton RA 《Geochimica et cosmochimica acta》1996,60(5):765-785

Visible to infrared reflectance spectroscopic analyses (0.3-25 micromoles) have been performed on sediments from the Dry Valleys region of Antarctica. Sample characterization for these sediments includes extensive geochemical analyses and X-ray diffraction (XRD). The reflectance spectra and XRD indicate major amounts of quartz, feldspar, and pyroxene in these samples and lesser amounts of carbonate, mica, chlorite, amphibole, illite, smectite, and organic matter. Calcite is the primary form of carbonate present in these Lake Hoare sediments based on the elemental abundances and spectroscopic features. The particle size distribution of the major and secondary components influences their detection in mixtures and this sensitivity to particle size is manifested differently in the "volume scattering" and "surface scattering" infrared regions. The Christiansen feature lies between these two spectral regimes and is influenced by the spectral properties of both regions. For these mixtures the Christiansen feature was found to be dependent on physical parameters, such as particle size and sample texture, as well as the mineralogy. Semiquantitative spectroscopic detection of calcite and organic material has been tested in these quartz- and feldspar-rich sediments. The relative spectral band depths due to organics and calcite correlate in general with the wt% C from organic matter and carbonate. The amounts of organic matter and carbonate present correlate with high Br and U abundances and high Ca and Sr abundances, respectively. Variation in the elemental abundances was overall minimal, which is consistent with a common sedimentary origin for the forty-two samples studied here from Lake Hoare.  相似文献   

Comparison of COSPEC and two miniature ultraviolet spectrometer systems for SO2 measurements using scattered sunlight     

Tamar Elias  A. Jeff Sutton  Clive Oppenheimer  Keith A. Horton  Harold Garbeil  Vitchko Tsanev  Andrew J. S. McGonigle  Glyn Williams-Jones 《Bulletin of Volcanology》2006,68(4):313-322

The correlation spectrometer (COSPEC), the principal tool for remote measurements of volcanic SO₂, is rapidly being replaced by low-cost, miniature, ultraviolet (UV) spectrometers. We compared two of these new systems with a COSPEC by measuring SO₂ column amounts at Kīlauea Volcano, Hawaii. The two systems, one calibrated using in-situ SO₂ cells, and the other using a calibrated laboratory reference spectrum, employ similar spectrometer hardware, but different foreoptics and spectral retrieval algorithms. Accuracy, signal-to-noise, retrieval parameters, and precision were investigated for the two configurations of new miniature spectrometer. Measurements included traverses beneath the plumes from the summit and east rift zone of Kīlauea, and testing with calibration cells of known SO₂ concentration. The results obtained from the different methods were consistent with each other, with <8% difference in estimated SO₂ column amounts up to 800 ppm m. A further comparison between the COSPEC and one of the miniature spectrometer configurations, the ‘FLYSPEC’, spans an eight month period and showed agreement of measured emission rates to within 10% for SO₂ column amounts up to 1,600 ppm m. The topic of measuring high SO₂ burdens accurately is addressed for the Kīlauea measurements. In comparing the foreoptics, retrieval methods, and resultant implications for data quality, we aim to consolidate the various experiences to date, and improve the application and development of miniature spectrometer systems.  相似文献   

Evidence for the rapid incorporation of hopanoids into kerogen     

Paul Farrimond  Andrew N Bishop  Helen E Innes  Colin E Snape 《Geochimica et cosmochimica acta》2003,67(7):1383-1394

Hopanoids bound into the insoluble organic matter (kerogen) of Recent sediments from a freshwater lake (Priest Pot) and an anoxic sulphidic fjord (Framvaren) were released by hydropyrolysis and examined by gas chromatography-mass spectrometry. Bound hopanoids are present in high concentration (190-1400 μg/g TOC) and represent 22 to 86% of the total analysable hopanoids (i.e., bound and solvent-soluble), this proportion increasing with depth in Framvaren Fjord. The hopanes generated by hydropyrolysis contain higher amounts of the C₃₅, C₃₂, and C₃₀ homologues, reflecting the carbon number distribution of the bound hopanoids and indicating that both biohopanoids (C₃₀ and C₃₅) and their diagenetic products (dominated by C₃₂) are incorporated into the kerogen on a timescale of only 0 to 350 years. Sequential (multiple temperature) hydropyrolysis experiments gave an indication of the relative strengths of bonds being cleaved in association with hopane generation: The hopanoids of a sediment from Priest Pot are almost entirely bound by strong covalent bonds, interpreted to be mainly ether linkages, whilst a Framvaren sediment contains hopanoids that are bound by a mixture of weak di-/polysulphide linkages and stronger ether bonds. Labelling with deuterium indicated that the strong covalent linkages dominate, even for the Framvaren sediment.  相似文献