Quantification of mineral matter in the Argonne Premium Coals using interactive Rietveld-based X-ray diffraction     

Colin R. Ward  John C. Taylor  C. E. Matulis  L. S. Dale 《International Journal of Coal Geology》2001,46(2-4)

The mineral matter in the eight reference North American coal samples of the Argonne Premium Coal series has been investigated on a quantitative basis using X-ray diffraction (XRD) techniques. X-ray diffraction data obtained from electronic low-temperature (oxygen–plasma) ash (LTA) residues, from ashes produced by heating the coals in air at 370°C, and also from the raw coals themselves, were evaluated using an interactive data processing system ( ™) based on Rietveld interpretation methods. The results from the three types of material (LTA, 370°C ash and raw coal) were compared for each sample. This allowed the components present in the raw coals in crystalline form to be recognised separately from mineral artifacts produced, particularly in the low-rank coals, from interaction of organically associated elements (Ca, S, etc.) during the two ashing processes.After the allowance for the production of any artifacts, the quantitative mineral assemblages identified from XRD of the raw coals were found to be consistent, even for coals having a relatively low ash percentage (around 5%), with the results obtained from the respective mineral concentrates prepared by the ashing methods. The effects of heating the coal to 370°C could also be distinguished, relative to the raw coal or the LTA, through changes in components such as pyrite and the clay minerals.Although some areas of uncertainty exist, particularly with magnesium in the low-rank coals, the calculated chemical compositions of the coal ash derived from the mineral mixtures identified for each coal were also found to be consistent with the results of direct chemical analysis of the respective coal ash materials.  相似文献   

A case example of near-surface correction for multicomponent VSPS     

Xinwu Zeng  Colin MacBeth 《Geophysical Prospecting》1996,44(5):889-910

A deterministic near-surface correction procedure is developed for multicomponent VSP data, shot using directional sources and recorded using three-component receivers. The method is capable of removing unwanted effects of acquisition such as unequal source strengths or misorientations, but may also remove near-surface multiples and anisotropy. This is of considerable benefit for obtaining accurate and consistent estimates of subsurface anisotropy from different source combinations. Application of the technique is illustrated using a dataset from the Romashkino reservoir in Russia, where three or four different directional sources are used at the same source locations. The technique corrects for the large discrepancies which exist between the estimates obtained using different source combinations. Application of the technique to three wells in the survey region reveals a nearly isotropic subsurface, except for a few isolated zones of moderate to high (2 to 8%) anisotropy which lie close to the expected depth for the reservoir. Although there is no significant correlation with the production figures for each well, the qS1 polarization azimuth within the reservoir does vary at each well location, suggesting that this may be a more sensitive indicator of reservoir Drocess.  相似文献   

Biotransformation at 10° C of Di-n-Butyl Phthalate in Subsurface Microcosms     

Christian Chauret  William E. Inniss  Colin I. Mayfield 《Ground water》1996,34(5):791-794

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Storm solute behaviour in a montane Mediterranean forested catchment     

Anna vila  Josep Piol  Ferran Rod  Colin Neal 《Journal of Hydrology》1992,140(1-4):143-161

The results of an extensive study of streamwater chemistry during stormflow events, for a montane Mediterranean area, are presented. Four groups of variables are identified as having contrasting behaviour: alkalinity and pH; nitrate and potassium; sulphate and chloride; sodium, calcium and magnesium. The results show a complex pattern of response to flow that can be broadly linked to: (1) antecedent hydrological conditions; (2) rainfall intensity; (3) supplies of water from chemically distinct areas within the catchment. However, comparisons between this study and a parallel one which examined the composition of waters within the catchment, show that it is presently impossible to quantify the relative supplies from each part of the catchment. The findings are reviewed in relation to analogous studies within a European setting and in relation to modelling initiatives.  相似文献   

Environmental management in Antarctica Instruments and institutions     

Colin M. Harris  Janice Meadows 《Marine pollution bulletin》1992,25(9-12):239-249

Instruments and institutions for environmental management in Antarctica have evolved from beginnings in the Antarctic Treaty, with subsequent introduction of the Convention for the Conservation of Antarctic Seals, the Convention on the Conservation of Antarctic Marine Living Resources, and recommendations made at Treaty meetings. The Protocol on Environmental Protection to the Antarctic Treaty will improve existing provisions for environmental management in Antarctica. When it enters into force the Protocol will apply to all activities in the Treaty area: it provides rules for environmental impact assessment, conservation of fauna and flora, disposal of wastes, prevention of marine pollution and specially protected and managed areas. The Protocol's Committee for Environmental Protection will facilitate discussion and advice on environmental management. Management of information is a vital part of ensuring measures are effective. The Protocol should be ratified quickly to improve the basis for environmental protection, but the test will be whether and how it is implemented in practice.  相似文献   

High Resolution Radio Observations of Luminous IR Galaxies     

Colin J. Lonsdale 《Astrophysics and Space Science》1999,266(1-2):119-124

High resolution radio observations provide a unique tool for investigation ofultraluminous infrared galaxies, due to the combination of high angularresolution and source transparency available at centimeter wavelengths. Thetypical angular size of the IR emitting region in the most luminous systems isof order 0.1 arcsec, while dust absorption appears to obscure this region fromdirect view at wavelengths shorter than 100 microns. Radio observationswith VLBI and MERLIN are revealing compact radio structures indicative of bothstarburst and AGN activity in these systems. Additional observations arerequired to clarify relationships between radio structures and the energygeneration mechanisms, and to realize the full potential of radio interferometryfor ULIRG studies.  相似文献   

Survivorship and growth of Fucus gardneri after transplant to an acid mine drainage-polluted area     

Marsden AD  DeWreede RE  Levings CD 《Marine pollution bulletin》2003,46(1):65-73

Acid mine drainage (AMD) from an abandoned copper mine at Britannia Beach, British Columbia, Canada, enters the marine environment through Britannia Creek. The surrounding intertidal zone is devoid of rockweed, Fucus gardneri Silva, a seaweed that dominates nearby shores. Rockweed plants were transplanted to the intertidal zone near Britannia Creek and monitored for changes in percent cover, survivorship, growth rate and Cu content. Autumn and winter transplants to within 100 m of Britannia Creek resulted in negative growth rates and high mortality within 57 days of exposure to AMD, with Cu levels in rockweed surpassing 2,300 ppm in dry tissue. Summer transplants to sites 300-700 m from Britannia Creek showed no consistent differences between AMD-exposed rockweed and control plants, possibly because the plants were stressed by desiccation. The results are consistent with ecological effects observed in other studies, and provide strong evidence for the role of AMD in excluding rockweed from the shores near Britannia Creek.  相似文献   

Tar ball frequency data and analytical results from a long-term beach monitoring program     

Owens EH  Mauseth GS  Martin CA  Lamarche A  Brown J 《Marine pollution bulletin》2002,44(8):770-780

Following the spill of fuel oils from the New Carissa in February 1999, approximately 300 km of beaches on the Pacific coast of North America were surveyed. A long-term observation program focused on the documentation of stranded tar balls in the vicinity of the spill site. Systematic beach surveys which were conducted over the period March 1999 to April 2001 and semi-logarithmic scale, time-series plots proved the most useful format for identifying trends. Beach monitoring continued through to August 2001. by which time 212 tar balls had been analyzed by GC/MS for their chemical characteristics. The samples of tar balls collected between February 1999 and August 2001 were qualitatively compared with New Carissa source oils (NCSO) and 101 (48%) were not consistent with NSCO. The presence of tar balls that are not related to an incident can confound attempts to define cleanup or endpoint criteria and to assess possible injury to natural resources.  相似文献   

Incipient weathering rind development on introduced machine‐polished granite discs in an Arctic alpine environment,northern Scandinavia     

John C. Dixon  Sean W. Campbell  Colin E. Thorn  Robert G. Darmody 《地球表面变化过程与地形》2006,31(1):111-121

Weathering rinds, zones of alteration on the exterior surfaces of rock outcrops and coarse unconsolidated surficial debris are widely used by geomorphologists and Quaternary geologists as indicators of the relative age of landforms and landscapes. Additionally they provide unique insights into the earliest stages of rock and mineral weathering, yet the origin of these alteration zones is relatively poorly understood. This lack of understanding applies especially to the initial stages of rind formation. The study reported in this paper has two principal objectives. The first is to use lightly polished granite discs inserted in soil profiles under several different plant communities in an Arctic alpine environment for a period of four or five years to investigate the nature of incipient weathering rind development. The second is to investigate the factors responsible for spatial variability in the nature and rates of rind formation. Incipient weathering rind development on the outer edges of the granite discs is observable and measurable over a period of time as short as four years in the mild Arctic alpine environment of Swedish Lapland. The earliest stages of rind development involve the development of a porous structure consisting of a combination of pits and fractures which have been solutionally enlarged and modified. Solution appears to be preferentially concentrated on the surfaces of feldspars and, to a lesser extent, quartz. In addition, iron oxides are present along grain boundaries and in grain interiors and are interpreted to have been derived from the oxidation of ferromagnesian minerals. Spatial variability in weathering rind development appears to be particularly driven by differences in moisture but is not related to soil pH. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

Ten Years (1994–2004) of ‘potential’ weathering in Kärkevagge,Swedish Lapland     

Colin E. Thorn  John C. Dixon  Robert G. Darmody  Charles E. Allen 《地球表面变化过程与地形》2006,31(8):992-1002

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