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Stiffness variations in carbonates may be described as resulting from different concentrations of flat compliant pores or cracks, which can have a significant effect on the effective stiffness and acoustic properties (e.g., velocities and attenuations) of dry as well as saturated carbonates, although they carry extremely little porosity. As shown in this paper, the effects of dual porosity and wave-induced fluid flow or pore pressure communication may also play a significant role. On the basis of a previously published T-matrix approach to model the effective viscoelastic properties of cracked porous media, we illustrate the (frequency-dependent) effects of wave-induced fluid flow (mainly squirt flow) or pore pressure communication for a model structure consisting of a mixture of fluid-saturated porous grains and fluid-saturated cavities (vugs, etc.) that are embedded in a solid matrix associated with carbonates. We assume that the pores within the porous grains are decoupled from the pores in the solid matrix (and possibly saturated with different fluids) but that each pore system at the micro and/or mesoscale may or may not be connected. For each of four different connectivity models, we present numerical results for four different cases of microstructure (that emphasize the importance of cracks and flat compliant pores). Our numerical results indicate that the velocity and attenuation spectra of carbonates vary significantly, even when the crack density and all other volume concentrations are constant.  相似文献   
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In the framework of the Sismovalp European project, an equivalent linear 2D code was developed to compute the response of a valley to SH waves, using the discrete wave-number method proposed by Aki and Larner (Aki K, Larner KL (1970) J Geophys Res 75:5). To overcome the frequency upper bound limitation, the Aki and Larner’s method is combined with a one-dimensional computation using a classical multi-layer method (Aki K, Richards PG (1980) Quantitative Seismology: Theory and Methods, vols. 1 & 2. W.H. Freeman & Co, San Francisco). The so-called “Aki–Larner extended method” is associated to an iterative algorithm, as proposed by Seed and Idriss (Seed HB, Idriss IM (1969) Report No. EERC 70–10, Earthquake Research Center, University of California, Berkeley, California) which accounts for the modulus and damping degradation using a linear visco-elastic model. A comparison of the results in the linear and the equivalent linear cases, for a magnitude 6.0 earthquake, shows that the account for the equivalent linear behaviour of the soil significantly reduces the amplification level, especially at frequencies higher than the fundamental resonance frequency of the site. In the case of site effects or microzonation studies devoted to produce design spectra for engineering structures, this can have a major impact on the associated results and costs, depending on the frequency of interest for the considered structure. As a first application of the developed technique, 2D equivalent linear Aki–Larner computations are used to perform the seismic microzonation study of the upper Rhone valley, in the Visp area (Switzerland), a typical 2D alpine valley. These investigations made it possible to determine site specific spectra, associated with different zones, to be used instead of the code spectra that do not take into account the local 2D amplification.  相似文献   
24.
F. Remy  F. Mignard 《Icarus》1985,63(1):1-19
We have studied the long-time dynamical evolution of a population of comets surrounding the Solar System at a large distance. Orbital changes are caused by random passing stars. We first emphasize the need for a new simulation because of the lack of completeness of previous analytical and numerical studies. Then the solar neighborhood is modeled by a sphere of 1 pc in radius, which stars cross at random in direction and distance. The geometry of the encounters allows us to compute the impulse gained by the star and the Sun, in the context of an impact approximation. Then we determine the change of orbital elements for a population of comets and follow the evolution of the frequency distribution for the five Keplerian elements. Clouds are selected in such a way that we test the two main hypotheses for the origin of the Oort cloud, and also the regions of stability in an aphelion-eccentricity diagram. We show that stellar perturbations randomize the cloud and prevent one from inferring the initial cloud configuration from the current distribution. Clouds are depleted by the diffusion of comets into the planetary regions, where they become planet-influenced comets or are ejected from the Solar System. The diffusion of aphelion toward interstellar regions proves to be the major source of cometary loss. Direct ejection to hyperbolic orbits amounts to 9% of the originally population over the age of the Solar System. Finally the current and original cloud populations are estimated at 1.8 × 1012 and 2 × 1013 comets and we discuss these results.  相似文献   
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The monsoon is a large‐scale feature of the tropical atmospheric circulation, affecting people and economies in the world's most densely populated regions. Future trends due to natural variability and human‐induced climate changes are uncertain. Palaeoclimate records can improve our understanding of monsoon dynamics and thereby reduce this uncertainty. Palaeoclimate records have revealed a dramatic decrease in the Asian summer monsoon since the early Holocene maximum 9 ka BP. Here we focus on the last 2 ka, where some records indicate an increasing trend in the summer monsoon. Analysing Globigerina bulloides upwelling records from the Arabian Sea, we find the weakest monsoon occurred 1500 a BP, with an increasing trend towards the present. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   
27.
The phase relationship between climate parameters during terminations gives insight into deglaciation mechanisms. By combining foraminiferal Mg/Ca and alkenone thermometers with planktonic and benthic foraminiferal δ18O, we determined the phase relationship between local sea surface temperature (SST) and global seawater δ18O changes in the Coral Sea in the Southwestern Pacific over the last 360 ka. The onset of the SST warming preceded the seawater δ18O change by several ka for Termination I, II and III. During Termination I, the SST warming started at 20 ka BP, earlier than atmospheric CO2 rise suggesting that the greenhouse effect was not the main trigger of this early warming. Compilation of 14C-dated SST records from the whole Pacific during Termination I reveals that the onset of the warming is generally earlier in the Southern and the tropical Pacific than in the North Pacific. This spatio-temporal warming pattern suggests linkage between the southern ocean and tropical Pacific. The early tropical warming could provide heat and moisture to the northern high latitudes, modifying radiative balance and precipitation over ice sheets at the onset of deglaciation.  相似文献   
28.
In assessing the feasibility of widespread deployment of CO2 geological storage, it is prudent to first assess potential consequences of an error or accident that could lead to CO2 leakage into groundwater resources above a sequestration interval. Information about the sensitivity of the groundwater system to introduction of CO2 is needed in order to design groundwater monitoring program. A laboratory-batch experiment was conducted to explore the range of CO2 impact on groundwater quality of a spectrum of representative aquifers, in the Gulf Coast region, USA. Results show that CO2 elevated concentrations of many cations within hours or days. Two types of cations were recognized according to their concentration trends. Type I cations—Ca, Mg, Si, K, Sr, Mn, Ba, Co, B, Zn—rapidly increased following initial CO2 flux and reached stable concentrations before the end of the experiment. Type II cations—Fe, Al, Mo, U, V, As, Cr, Cs, Rb, Ni and Cu—increased at the start of CO2 flux, but declined, in most cases, to levels lower than pre-CO2 concentrations. Dissolution of dolomite and calcite caused the largest increase in concentrations for Ca, Mg, Mn, Ba and Sr. Cation release rates decreased linearly as pH increased during mineral buffering. Experiment results suggest that carbonate minerals are the dominant contributor of changes in groundwater quality. Risk assessments of potential degradation of groundwater and monitoring strategies should focus on these fast-reacting minerals. Mobilization risk of Type II cations, however, may be self-mitigated because adsorption occurs when pH rebounds.  相似文献   
29.
Understanding catchment-scale patterns of groundwater and stream salinity are important in land- and water-salinity management. A large-scale assessment of groundwater and stream data was undertaken in the eastern Mt Lofty Ranges of South Australia using geographical information systems (GIS), regional scale hydrologic data, hydrograph separation and hydrochemical techniques. Results of the study show: (1) salts were mostly of marine origin (75%), while sulfate and bicarbonate from mineral weathering comprised most of the remainder, (2) elevated groundwater salinities and stable water isotopic compositions similar to mean rainfall indicated that plant transpiration was the primary salt accumulation mechanism, (3) key factors explaining groundwater salinity were geology and rainfall, with overall catchment salinity inversely proportional to average annual rainfall, and groundwater salinity ‘hotspots’ (EC >8 mS/cm) associated with geological formations comprising sulfidic marine siltstones and shales, (4) shallow groundwater correlated with elevated stream salinity, implying that baseflow contributed to stream salt loads, with most of the annual salt load (estimated to be 24,500 tonnes) occurring in winter when baseflow volume was highest. Salt-load analysis using stream data could be a practical, low-cost technique to rapidly target the investigation of problem areas within a catchment.  相似文献   
30.
Boriskino is a poorly studied CM chondrite with numerous millimeter‐ to centimeter‐scale clasts exhibiting sharp boundaries. Clast textures and mineralogies attest to diverse geological histories with various degrees of aqueous alteration. We conducted a petrographic, chemical, and isotopic study on each clast type of the breccia to investigate if there exists a genetic link between brecciation and aqueous alteration, and to determine the controlling parameter of the extent of alteration. Boriskino is dominated by CM2 clasts for which no specific petrographic type could be assigned based on the chemical compositions and modal abundances of constituents. One clast stands out and is identified as a CM1 lithology, owing to its lack of anhydrous silicates and its overall abundance of dolomite‐like carbonates and acicular iron sulfides. We observe that alteration phases near clast boundaries exhibit foliation features, suggesting that brecciation postdated aqueous alteration. We measured the O‐isotopic composition of Ca‐carbonates and dolomite‐like carbonates to determine their precipitation temperatures following the methodology of Verdier‐Paoletti et al. (2017). Both types of carbonates yield similar ranges of precipitation temperatures independent of clast lithology, ranging from ?13.9 ± 22.4 (2σ) to 166.5 ± 47.3 °C, precluding that temperature alone accounts for the differences between the CM1 and CM2 lithologies. Instead, we suggest that initial water/rock ratios of 0.75 and 0.61 for the CM1 and CM2 clasts, respectively, might control the extent of aqueous alteration. Based on these estimates, we suggest that Boriskino clasts originated from a single parent body with heterogeneous distribution of water either due to local differences in the material permeability or in the initial content of ice available. These conditions would have produced microenvironments with differing geochemical conditions thus leading to a range of degrees of aqueous alteration.  相似文献   
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