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21.
Kazuyo Tachikawa Laurence Vidal Corinne Sonzogni Edouard Bard 《Quaternary Science Reviews》2009,28(13-14):1160-1170
The phase relationship between climate parameters during terminations gives insight into deglaciation mechanisms. By combining foraminiferal Mg/Ca and alkenone thermometers with planktonic and benthic foraminiferal δ18O, we determined the phase relationship between local sea surface temperature (SST) and global seawater δ18O changes in the Coral Sea in the Southwestern Pacific over the last 360 ka. The onset of the SST warming preceded the seawater δ18O change by several ka for Termination I, II and III. During Termination I, the SST warming started at 20 ka BP, earlier than atmospheric CO2 rise suggesting that the greenhouse effect was not the main trigger of this early warming. Compilation of 14C-dated SST records from the whole Pacific during Termination I reveals that the onset of the warming is generally earlier in the Southern and the tropical Pacific than in the North Pacific. This spatio-temporal warming pattern suggests linkage between the southern ocean and tropical Pacific. The early tropical warming could provide heat and moisture to the northern high latitudes, modifying radiative balance and precipitation over ice sheets at the onset of deglaciation. 相似文献
22.
Jiemin Lu Judson W. Partin Susan D. Hovorka Corinne Wong 《Environmental Earth Sciences》2010,60(2):335-348
In assessing the feasibility of widespread deployment of CO2 geological storage, it is prudent to first assess potential consequences of an error or accident that could lead to CO2 leakage into groundwater resources above a sequestration interval. Information about the sensitivity of the groundwater system
to introduction of CO2 is needed in order to design groundwater monitoring program. A laboratory-batch experiment was conducted to explore the range
of CO2 impact on groundwater quality of a spectrum of representative aquifers, in the Gulf Coast region, USA. Results show that
CO2 elevated concentrations of many cations within hours or days. Two types of cations were recognized according to their concentration
trends. Type I cations—Ca, Mg, Si, K, Sr, Mn, Ba, Co, B, Zn—rapidly increased following initial CO2 flux and reached stable concentrations before the end of the experiment. Type II cations—Fe, Al, Mo, U, V, As, Cr, Cs, Rb,
Ni and Cu—increased at the start of CO2 flux, but declined, in most cases, to levels lower than pre-CO2 concentrations. Dissolution of dolomite and calcite caused the largest increase in concentrations for Ca, Mg, Mn, Ba and
Sr. Cation release rates decreased linearly as pH increased during mineral buffering. Experiment results suggest that carbonate
minerals are the dominant contributor of changes in groundwater quality. Risk assessments of potential degradation of groundwater
and monitoring strategies should focus on these fast-reacting minerals. Mobilization risk of Type II cations, however, may
be self-mitigated because adsorption occurs when pH rebounds. 相似文献
23.
David L. Poulsen Craig T. Simmons Corinne Le Galle La Salle Jim W. Cox 《Hydrogeology Journal》2006,14(7):1339-1359
Understanding catchment-scale patterns of groundwater and stream salinity are important in land- and water-salinity management. A large-scale assessment of groundwater and stream data was undertaken in the eastern Mt Lofty Ranges of South Australia using geographical information systems (GIS), regional scale hydrologic data, hydrograph separation and hydrochemical techniques. Results of the study show: (1) salts were mostly of marine origin (75%), while sulfate and bicarbonate from mineral weathering comprised most of the remainder, (2) elevated groundwater salinities and stable water isotopic compositions similar to mean rainfall indicated that plant transpiration was the primary salt accumulation mechanism, (3) key factors explaining groundwater salinity were geology and rainfall, with overall catchment salinity inversely proportional to average annual rainfall, and groundwater salinity ‘hotspots’ (EC >8 mS/cm) associated with geological formations comprising sulfidic marine siltstones and shales, (4) shallow groundwater correlated with elevated stream salinity, implying that baseflow contributed to stream salt loads, with most of the annual salt load (estimated to be 24,500 tonnes) occurring in winter when baseflow volume was highest. Salt-load analysis using stream data could be a practical, low-cost technique to rapidly target the investigation of problem areas within a catchment. 相似文献
24.
A reinforced concrete frame-wall structure of a building designed in accordance to standard practice in Argentina was analysed by the procedures prescribed by current Argentine Codes. In addition, the inelastic step-by-step response of the structure to design spectrum-compatible accelerograms was studied by means of a special element for inelastic dynamic analysis of reinforced concrete frames. Results obtained by the different methods of analysis are presented. 相似文献
25.
Maximilien J. Verdier‐Paoletti Yves Marrocchi Lionel G. Vacher Jrme Gattacceca Andrey Gurenko Corinne Sonzogni Matthieu Gounelle 《Meteoritics & planetary science》2019,54(8):1692-1709
Boriskino is a poorly studied CM chondrite with numerous millimeter‐ to centimeter‐scale clasts exhibiting sharp boundaries. Clast textures and mineralogies attest to diverse geological histories with various degrees of aqueous alteration. We conducted a petrographic, chemical, and isotopic study on each clast type of the breccia to investigate if there exists a genetic link between brecciation and aqueous alteration, and to determine the controlling parameter of the extent of alteration. Boriskino is dominated by CM2 clasts for which no specific petrographic type could be assigned based on the chemical compositions and modal abundances of constituents. One clast stands out and is identified as a CM1 lithology, owing to its lack of anhydrous silicates and its overall abundance of dolomite‐like carbonates and acicular iron sulfides. We observe that alteration phases near clast boundaries exhibit foliation features, suggesting that brecciation postdated aqueous alteration. We measured the O‐isotopic composition of Ca‐carbonates and dolomite‐like carbonates to determine their precipitation temperatures following the methodology of Verdier‐Paoletti et al. (2017). Both types of carbonates yield similar ranges of precipitation temperatures independent of clast lithology, ranging from ?13.9 ± 22.4 (2σ) to 166.5 ± 47.3 °C, precluding that temperature alone accounts for the differences between the CM1 and CM2 lithologies. Instead, we suggest that initial water/rock ratios of 0.75 and 0.61 for the CM1 and CM2 clasts, respectively, might control the extent of aqueous alteration. Based on these estimates, we suggest that Boriskino clasts originated from a single parent body with heterogeneous distribution of water either due to local differences in the material permeability or in the initial content of ice available. These conditions would have produced microenvironments with differing geochemical conditions thus leading to a range of degrees of aqueous alteration. 相似文献
26.
A new protocol for oxygen isotope analysis of authigenic and biogenic fine silica grains using laser-extraction technique 总被引:1,自引:0,他引:1
J. Crespin A. Alexandre C. Sonzogni F. Sylvestre 《Journal of Geochemical Exploration》2006,88(1-3):423
We report here a 30 W CO2 laser heating protocol for analyzing oxygen isotope composition (δ18O in ‰ vs. V-SMOW) of quartz and amorphous silica grains lower than 50 and 2 μm with a good external precision (1σ < 0.15‰). This technique is used to investigate δ18O composition of macro-, micro- and crypto-crystalline quartz cements of quartzite levels occurring in a sand sequence from the South of France (Apt Series), after a physical separation of the quartz cements. δ18O data obtained from this technique are compared with δ18O data obtained from in situ ion microprobe analyses. This study also presents promising results on δ18O analysis of phytoliths obtained with the laser heating protocol (1σ < 0.1‰). 相似文献
27.
Ronan Pavic Martin G. Koller Pierre-Yves Bard Corinne Lacave-Lachet 《Journal of Seismology》2000,4(1):59-77
An assessment of uncertainties for ground motion predictions with the aid of the empirical Green's function (EGF) technique is presented. The main input parameters were identified, and their respective uncertainties were assessed by means of an international expert inquiry. The repercussion of these input uncertainties on the final ground motion estimates were investigated by means of the Latin Hypercube Sampling technique. The mean ground motion estimates (response spectra) and their standard deviations were compared with results obtained from empirical attenuation laws. The most sensitive input parameter turned out to be the seismic moment corresponding to the EGF. In general, if the source parameters are well determined, equivalent uncertainties, statistically speaking, can be expected from the EGF technique and from the application of attenuation laws. Therefore, if EGFs with well known source parameters are available, the EGF technique seems to be preferable: site effects are automatically taken into account, and physically realistic acceleration time histories can be obtained. However, further investigations on the reliability of the EGF technique should be performed, and finally, it is recalled that the EGF technique is based on the assumption of linearity. If conditions are such that this assumption cannot be maintained, the EGF technique should be combined with non-linear geotechnical methods. 相似文献
28.
29.
Yann Sonzogni Ariel Provost Pierre Schiano 《Contributions to Mineralogy and Petrology》2011,161(3):497-510
Glass inclusions in clinopyroxene phenocrysts from La Sommata (Vulcano Island, Aeolian Arc) were reheated and submitted to
a sustained thermal gradient. Each remelted inclusion undergoes a transient textural and chemical reequilibration and concomitantly
begins to migrate along a crystallographic direction, at a small angle with the thermal gradient. The completion of morphological
evolution requires a characteristic time that is governed by chemical diffusion. Chemical reequilibration results in the formation
of a colored halo that delineates the former location and shape of the inclusion after it has migrated away. Transcrystalline
migration proceeds by dissolution of the host clinopyroxene ahead and precipitation astern. Its rate is not limited by Fick’s
law, but by the crystal-melt interface kinetics. Clinopyroxene dissolution and growth are slower than for olivine in similar
conditions but obey the same analytical law, which can be transposed to equally or more sluggish melting or crystallization
events in nature. When a gas bubble is initially present, it responds to elastic forces by quickly shifting toward the cold
end of the inclusion, where it soon becomes engulfed as an isolated fluid inclusion in the reprecipitated crystal. This study
confirms that transcrystalline melt migration, beside its possible implications for small-scale melt segregation and fluid-inclusion
generation in the Earth’s mantle, provides an experimental access to interfacial kinetic laws in near-equilibrium conditions. 相似文献
30.
Bernhard Chapligin Melanie J. Leng Anne Alexandre Akira Ijiri Aldo Shemesh Ulrike Herzschuh Hanno Meyer Yusuke Okazaki Zachary D. Sharp Corinne Sonzogni Florence Sylvestre Ruth Yam 《Geochimica et cosmochimica acta》2011,75(22):7242-7256
Several techniques have been introduced in the last decades for the dehydration and release of O2 from biogenic silica (opal-A) for oxygen-isotope analysis. However, only one silica standard is universally available: a quartz standard (NBS28) distributed by the IAEA, Vienna. Hence, there is a need for biogenic silica working standards. This paper compares the existing methods of oxygen-isotope analyses of opal-A and aims to characterize additional possible working standards to calibrate the δ18O values of biogenic silica. For this purpose, an inter-laboratory comparison was organized. Six potential working standard materials were analysed repeatedly against NBS28 by eight participating laboratories using their specific analytical methods. The materials cover a wide range of δ18O values (+23 to +43‰) and include diatoms (marine, lacustrine), phytoliths and synthetically-produced hydrous silica. To characterize the proposed standards, chemical analyses and imaging by scanning electron microscopy (SEM) were also performed. Despite procedural differences at each laboratory, all methods are in reasonable agreement with a standard deviation (SD) for δ18O values between 0.3‰ and 0.9‰ (1σ). Based on the results, we propose four additional biogenic silica working standards (PS1772-8: 42.8‰; BFC: 29.0‰; MSG60: 37.0‰; G95-25-CL leaves: 36.6‰) for δ18O analyses, available on request through the relevant laboratories. 相似文献