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21.
Perfluorinated compounds (PFCs) have emerged as significant global environmental pollutants with persistent, bioaccumulative and toxic properties. The aim of this study was to determine the occurrence of PFCs in water (wastewater, submarine emissaries and port-waters), sediment and transplanted mussels in estuarine areas of high urban and industrial impact from Northern Spain. Five PFCs of industrial use were studied: perfluorooctanesulfonate, perfluorohexanesulfonate, perfluorobutanesulfonate, perfluorooctanoate acid and perfluorononanoate acid. After selective extraction, samples were analyzed by Ultra Performance Liquid Chromatography coupled to tandem mass spectrometry. ΣPFCs ranged from 0.06 to 10.9 ng/L in water, with higher levels in wastewater treatment plants effluents and port waters than in submarine emissaries. Little accumulation was observed in sediments and mussels with ΣPFCs ranging from 0.01-0.13 ng/g dw and 0.01-0.06 ng/g ww, respectively. Most ubiquitous compounds were PFOS and PFOA. Mass fluxes of PFCs to the Cantabrian Sea are estimated and the impact to the coastal ecosystem is discussed.  相似文献   
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As a result of their morphological complexity, large macroalgae show intra-thallus variations in their nutritional composition and secondary metabolite content, which influences the trophic ecology of herbivorous invertebrates, and ultimately their fitness. In this study, we evaluated for the first time the variability in nutritional quality (protein content, carbohydrates, lipids, and total organic matter), secondary metabolites (phlorotannins), and structure (shape and toughness) between blades and stipes of the macroalgae Durvillaea Antarctica. Specifically, we looked at their effect on feeding preference, rate of consumption, absorption efficiency, and growth rate of the amphipod Orchestoidea tuberculata, one of the most abundant organisms on Chilean sandy beaches. Proteins, carbohydrates, total organic matter and phlorotannin contents were significantly higher in blades than in stipes. Preference experiments revealed that the amphipods preferred blades when fresh pieces of blades and stipes were offered at the same time. Similar results were found when artificial food (in which structures of both parts of the alga were standardized) was offered, suggesting that shape and toughness of the two different parts of the alga did not influence preference patterns of O. tuberculata. Absorption efficiency of O. tuberculata was higher on blades compared to stipes. When the amphipods were kept with each of the algal parts separately (i.e. no choice), they consumed a significantly higher amount of stipe, which suggests that O. tuberculata used food quantity to compensate for the lower nutritional quality of stipes. The higher nutritional values of blades compared to stipes appears to explain observed preference patterns by O. tuberculata. Phlorotannin content did not appear to inhibit blade consumption, suggesting that the nutritional quality of the food could be more important than chemical defense in determining food choice in O. tuberculata. Growth did not differ between the amphipods maintained with either blades or stipes (i.e. no choice), which is consistent with the hypothesis of compensatory feeding. To conclude, O. tuberculata can actively select specific parts of an alga and this selection appears to be based on nutritional quality. The capacity for using different feeding strategies allow O. tuberculata, in some cases, to successfully exploit food types with different nutritional qualities.  相似文献   
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We studied the occurrence of large high frequency temperature fluctuations and their potential association with settlement of intertidal invertebrates during the spring/summer period 1999/2000 at Las Cruces, on the coast of central Chile. Our results showed the existence of internal tidal bores, characterized by sharp drops in water temperature at the surface and near the bottom, and subsequent temperature increases, which occurred with a semidiurnal periodicity. Measured currents support the hypothesis of alternating onshore and offshore movement of warm-water fronts. The frequency of the events varied through the summer and their amplitude seems to be modulated by onshore winds. The strongest events were observed when strong onshore winds occurred in late afternoon hours and the entire water column showed a semidiurnal temperature signal. Highest values of chlorophyll concentration in the intertidal zone and daily settlement of bivalves, gastropods and crustaceans were observed at times when conditions were favorable for occurrence of internal tidal bores. Results suggest that internal tidal bore warm fronts could play an important role in the transport of neustonic larval invertebrates and the delivery of phytoplankton to at least some intertidal sites along the coast of Chile.  相似文献   
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In the present study, the dynamic response of a coupled SPM-feeder-cage system under irregular waves and shear currents is analyzed. A numerical model is developed by using the commercial software Orca Flex. Hydrodynamics coefficients of the vessel are calculated by using a 3D diffraction/radiation panel program. First- and second-order wave forces are included in the calculations. Morison equation is used to compute the drag force on line elements representing the net. Drag coefficients are determined at every time step in the simulation considering the relative normal velocity between the structural elements and the fluid flow. The dynamic response of the coupled system is analyzed for various environments and net materials. The results of the study show the effects of solidity ratio of the net and vertical positions of the cage on the overall dynamic response of the system, confirming the viability of this type of configuration for future development of offshore aquaculture in deep waters.  相似文献   
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This work presents the preliminary results of the first field calibration campaign performed in the Atacama Desert, Chile, between the 18 and 22 August 2014, called the Atacama Field Campaign (ATAFIC 2014). In situ measurements were performed in order to spectrally characterize the surface reflectance spectra between 0.3 and 2.5?µm, radiometric temperature (8.0–14.0?µm) and atmospheric measurements. A soil sample was collected and analyzed using Fourier Transform Infrared Spectroscopy and X-Ray Diffraction techniques to characterize the surface reflectance spectra and mineralogical composition, respectively. ASTER land surface emissivity in addition to GOES, MODIS and Landsat-8 land surface temperature (LST) were also used. Results showed that the spectral features of the Atacama soil and the characteristics of this geographical zone, which is featured as the most hyper-arid and cloudless place in the world, make this area a potential target for surface reflectance characterization. Day and night LST comparison between field and remote sensing data are lower than 2?K and the Root Mean Square Error for land surface emissivity is close to 2%. This work opens the possibilities to consider the Atacama Desert as a reference target for calibration and validation activities for earth observation missions’ purposes.  相似文献   
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Natural Hazards - Empirical relationships between MSK macroseismic intensity and several engineering ground motion parameters are developed using the macroseismic and instrumental data available...  相似文献   
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The MODIS snowcover product is one of many geophysical products derived from MODIS data. A cross‐validation of the MODIS snowcover daily products with data obtained from the meteorological network stations was conducted for the entire territory of Romania. The validation time interval covered the period between 29 October, 2004 and 1 May, 2005. The overall accuracy for the whole set of cloud‐free useful data proved to be 95%. The validation time interval included the three common snow situations: (1) late autumn months where 37.1% of the initial set of the data was used, and the overall accuracy was 98.6%; (2) the “winter” months where the clouds reduced the set of useful data – 31.75%– and the overall accuracy was 93.7%; and (3) the months of February and March which returned the highest accuracy (> 95%). Additionally, a cross‐validation using Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) high‐resolution imagery was carried out. Furthermore, the MODIS, meteorological data and ASTER data were integrated into a Geographic Information System (GIS) environment to perform flexible and comprehensive cross‐checking followed by a thematic analysis based on additional sets of data such as digital elevation models (DEMs) and land‐cover datasets.  相似文献   
30.
Anomalously high levels of mercury in sediment in the Lenga estuary, Chile are comparable to the most contaminated sites previously reported elsewhere. Total mercury (Hgtotal) concentrations range from 0.5 to 129 mg kg−1 and organic mercury (Hgorg) from 11 to 53 μg kg−1. The highest levels are in areas near the previous wastewater outfall of a chlo-alkali plant. The results show that the proportion of Hgorg/Hgtotal in the sediment varies by more than two orders of magnitude (0.02–5.7%) according to the concentration of Hgtotal. No correlation between the concentration of Hgorg and Hgtotal was found. The lack of correlation does contrast with the findings of other authors in culture media. Our results indicate that even at very high concentrations of Hgtotal and organic matter do not influence organic mercury formation in estuary sediments. The disparity in Hgtotal and Hgorg concentrations also attests to environmental differences in the formation.  相似文献   
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