The reliability of analytical data for tributyltin (TBT) in sea water and its implications on water quality criteria     

James W. Readman  Laurence D. Mee 《Marine environmental research》1991,32(1-4)

To investigate the reliability of analytical data for tributyltin (TBT) in sea water, split water samples were distributed to ten laboratories in six countries. The sub-surface samples comprised: (i) an offshore (0·5 km) water sample, (ii) the same sample but spiked with an undisclosed quantity of TBT standard compound (175 ng TBT⁺ liter⁻¹), and (iii) a sample taken from a yacht marina. The seven acceptable data sets were in good agreement for the spiked sample (178 ± 26 ng TBT⁺ liter⁻¹) but showed a greater variation in concentrations reported for the yacht marina sample (366 ± 93 ng TBT⁺ liter⁻¹). Atomic absorption and gas chromatographic-flame photometric detection techniques produced results of similar accuracy and precision. Samples acidified with 1 ml of 10% (v/v) acetic acid appeared stable for more than 2 weeks when stored refrigerated and in darkness. Analyses of the offshore seawater sample revealed TBT contamination (9 ± 7 ng TBT⁺ liter⁻¹) indicating dispersion of the compound to the shelf waters off Monaco. The spread in values reported by the laboratories demonstrates inherent difficulties in obtaining good precision below approximately 20 ng TBT⁺ liter⁻¹. This observation is discussed with respect to the setting and enforcing of water quality standards.  相似文献   

On the application of the units of measurement of the amount and composition of matter in oceanology     

E. I. Ovsyanyi  V. I. Zaburdaev  A. S. Romanov 《Physical Oceanography》2004,14(4):243-254

We consider the procedures of conversion of the conventional and out-of-system units of measurement of the amount and composition of matter used in oceanology to the International System of Units (SI). The coefficients of conversion are presented in the form of a table. We present the data on the units of measurement of mineralization (scales of salinity) of seawater for the oceanic range of its variability, freshened waters of internal seas, and brines. The contemporary concept of salinity as a dimensionless quantity is discussed.Translated from Morskoi Gidrofizicheskii Zhurnal, No. 4, pp. 61–72, July–August, 2004.  相似文献   

Temperature of the ocean surface as an indicator of thermodynamic processes in the northwest Pacific     

G. A. Vlasova  A. M. Polyakova 《Physical Oceanography》2004,14(5):295-302

The numerical computations and analysis of the anomalies of temperature of the ocean surface in the northwest part of the Pacific Ocean were carried out on the basis of the archival data for 1960 and 1964–1985. A five-year period of general instability of the annual average temperature was revealed (1973–1977). In this period, the year 1974 was the coldest and the year 1977 was characterized as extremely warm. We performed the analysis of the interannual and annual variability of the anomalies of temperature of the ocean surface and revealed common features and distinctions of the seasonal evolution of these anomalies for years with substantially different temperature conditions. A quasistationary zone of maximally heated waters was discovered in the band located (independently of the year and season) between 36 and 46°N to the east of 140°E. This zone coincides in space with the zone of the subarctic front and the south part of the subarctic region. The influence of the meanders of the Kuroshio Current was demonstrated. It is shown that their activity increases after the events of El-Niño and, hence, the thermal energy of the water area considerably increases and remains elevated for a period of 1–2 yr after the indicated events.Translated from Morskoi Gidrofizicheskii Zhurnal, No. 5, pp. 45–52, September–October, 2004.This revised version was published online in May 2005 with corrections to cover date.  相似文献   

Circulation and currents in the southwestern East/Japan Sea: Overview and review     

K.-I. Chang  W.J. Teague  S.J. Lyu  H.T. Perkins  D.-K. Lee  D.R. Watts  Y.-B. Kim  D.A. Mitchell  C.M. Lee  K. Kim 《Progress in Oceanography》2004,61(2-4):105

A review is made of circulation and currents in the southwestern East/Japan Sea (the Ulleung Basin), and the Korea/Tsushima Strait which is a unique conduit for surface inflow into the Ulleung Basin. The review particularly concentrates on describing some preliminary results from recent extensive measurements made after 1996. Mean flow patterns are different in the upstream and downstream regions of the Korea/Tsushima Strait. A high velocity core occurs in the mid-section in the upstream region, and splits into two cores hugging the coasts of Korea and Japan, the downstream region, after passing around Tsushima Island located in the middle of the strait. Four-year mean transport into the East/Japan Sea through the Korea/Tsushima Strait based on submarine cable data calibrated by direct observations is 2.4 Sv (1 Sv = 10⁶ m³ s⁻¹). A wide range of variability occurs for the subtidal transport variation from subinertial (2–10 days) to interannual scales. While the subinertial variability is shown to arise from the atmospheric pressure disturbances, the longer period variation has been poorly understood.Mean upper circulation of the Ulleung Basin is characterized by the northward flowing East Korean Warm Current along the east coast of Korea and its meander eastward after the separation from the coast, the Offshore Branch along the coast of Japan, and the anticyclonic Ulleung Warm Eddy that forms from a meander of the East Korean Warm Current. Continuous acoustic travel-time measurements between June 1999 and June 2001 suggest five quasi-stable upper circulation patterns that persist for about 3–5 months with transitions between successive patterns occurring in a few months or days. Disappearance of the East Korean Warm Current is triggered by merging the Dok Cold Eddy, originating from the pinching-off of the meander trough, with the coastal cold water carried Southward by the North Korean Cold Current. The Ulleung Warm Eddy persisted for about 20 months in the middle of the Ulleung Basin with changes in its position and spatial scale associated with strengthening and weakening of the transport through the Korea/Tsushima Strait. The variability of upper circulation is partly related to the transport variation through the Korea/Tsushima Strait. Movements of the coastal cold water and the instability of the polar front also appear to be important factors affecting the variability.Deep circulation in the Ulleung Basin is primarily cyclonic and commonly consists of one or more cyclonic cells, and an anticyclonic cell centered near Ulleung Island. The cyclonic circulation is conjectured to be driven by a net inflow through the Ulleung Interplain Gap, which serves as a conduit for the exchange of deep waters between the Japan Basin in the northern East Sea and the Ulleung Basin. Deep currents are characterized by a short correlation scale and the predominance of mesoscale variability with periods of 20–40 days. Seasonality of deep currents is indistinct, and the coupling of upper and deep circulation has not been clarified yet.  相似文献   

Late Holocene estuarine–inner shelf interactions; is there evidence of an estuarine retreat path for Tampa Bay, Florida?     

B. T. Donahue  A. C. Hine  S. Tebbens  S. D. Locker  D. C. Twichell   《Marine Geology》2003,200(1-4):219-241

The purpose of this study was to determine if and how a large, modern estuarine system, situated in the middle of an ancient carbonate platform, has affected its adjacent inner shelf both in the past during the last, post-glacial sea-level rise and during the present. An additional purpose was to determine if and how this inner shelf seaward of a major estuary differed from the inner shelves located just to the north and south but seaward of barrier-island shorelines. Through side-scan sonar mosaicking, bathymetric studies, and ground-truthing using surface grab samples as well as diver observations, two large submarine sand plains were mapped – one being the modern ebb-tidal delta and the other interpreted to be a relict ebb-tidal delta formed earlier in the Holocene. The most seaward portion of the inner shelf studied consists of a field of lobate, bathymetrically elevated, fine-sand accumulations, which were interpreted to be sediment-starved 3D dunes surrounded by small 2D dunes composed of coarse molluscan shell gravel. Additionally, exposed limestone hardbottoms supporting living benthic communities were found as well. This modern shelf sedimentary environment is situated on a large, buried shelf valley, which extends eastward beneath the modern Tampa Bay estuary. These observations plus the absence of an incised shelf valley having surficial bathymetric expression, and the absence of sand bodies normally associated with back-tracking estuarine systems indicate that there was no cross-shelf estuarine retreat path formed during the last rise in sea level. Instead, the modern Tampa Bay formed within a mid-platform, low-relief depression, which was flooded by rising marine waters late in the Holocene. With continued sea-level rise in the late Holocene, this early embayment was translated eastward or landward to its present position, whereby a larger ebb-tidal delta prograded out onto the inner shelf. Extensive linear sand ridges, common to the inner shelves to the north and south, did not form in this shelf province because it was a low-energy, open embayment lacking the wave climate and nearshore zone necessary to create such sand bodies. The distribution of bedforms on the inner shelf and the absence of seaward-oriented 2D dunes on the modern ebb-tidal delta indicate that the modern estuarine system has had little effect on its adjacent inner shelf.  相似文献   

Structure of the mesoscale variability of the troposphere and stratosphere found from radio refraction measurements via CHAMP satellites     

N. M. Gavrilov 《Izvestiya Atmospheric and Oceanic Physics》2007,43(4):451-460

Data of an experiment on radio occultation sounding of the atmosphere with the use of GPS signals were used to obtain global distributions of the variances of mesoscale variations in the refractive index in the troposphere and stratosphere. The experiment was carried out with the CHAMP satellite during the period 2001–2005. Measured vertical profiles were smoothed inside 5–10-km-thick layers centered at different altitudes in the troposphere and stratosphere with the use of second-degree polynomials. Deviations from the smoothed quantities and the corresponding variances were obtained for each profile and averaged for each month during the analyzed interval of the CHAMP experiment. Altitude-longitude-latitude inhomogeneities in the distribution of refractive index variances were analyzed. Altitude and latitude distributions of maxima and minima of refractive index variances depend on altitude and season. Turbulence and acoustic gravity waves can be the causes of small-scale and mesoscale variations in the refractive index of the troposphere and stratosphere. The variances of variations in the refractive index are greater in the regions of tropospheric jet streams and in the zones of near-equatorial deep convection. Atmospheric disturbances increase over mountain systems.  相似文献   

Correlative changes in metabolism and DNA damage in turbot (Scophthalmus maximus) exposed to benzo[a]pyrene     

Telli-Karakoç F  Ruddock PJ  Bird DJ  Hewer A  Van Schanke A  Phillips DH  Peters LD 《Marine environmental research》2002,54(3-5):511-515

Juvenile turbot (Scophthalmus maximus) were injected intraperitoneally with either corn oil or 5 mg/kg benzo[a]pyrene (BaP) dissolved in corn oil and sampled I and 3 days after injection. After 1 day, no elevation of 7-ethoxyresorufin O-deethylase (EROD) activity was observed, however bile metabolites (BaP-7,8 dihydrodiol representing 70% of the total metabolites) and a single hepatic DNA adduct spot (0.47 adducts/10(8) nucleotides) identified by 32P-postlabelling were formed. No BaP metabolites or DNA adducts were observed in either control or carrier control fish. Fish sampled after 3 days reported 5-fold higher (P < 0.05) levels of EROD activity, a shift in the bile metabolite profile towards BaP phenol formation (1OH and 30H BaP comprising up to 60% of total metabolites detected) and the formation of two adduct spots (0.86 and 0.71 adducts/10(8) nucleotides). These results show that BaP can be metabolised and form hydrophobic DNA adducts in turbot without EROD elevation. Following EROD elevation, a shift in the profile of both BaP metabolites and BaP metabolite-DNA interactions occurs indicative of other oxidative processes.  相似文献   

Regional variation in springtime ichthyoplankton assemblages in the northeast Pacific Ocean     

Miriam J. Doyle  Kathryn L. Mier  Morgan S. Busby  Richard D. Brodeur   《Progress in Oceanography》2002,53(2-4)

The coastal regions of the northeast Pacific support large, economically valuable fishery resources and provide nursery areas for many fish species. Over the last few decades, there have been dramatic shifts in species abundance and composition in this area. In this paper, we examine the springtime spatial patterns in the ichthyoplankton of three oceanographically different regions, the Southeast Bering Sea, the Gulf of Alaska and the U.S. West Coast. The data examined are a subset of a larger database (comprising data from cruises conducted from 1972 to 1997) that is being used to investigate spatial, seasonal and interannual patterns in ichthyoplankton of the northeast Pacific in relation to environmental conditions. Ichthyoplankton were collected during seven cruises using 60-cm bongo nets. Spatial patterns of ichthyoplankton were examined using both classification and ordination techniques. Relative Bray-Curtis dissimilarity coefficients calculated from the log₁₀ (n+1) of abundance data were used as input to the numerical classification of species and stations. Nonmetric multidimensional scaling was also applied to the abundance data to examine geometric patterns in the data. The numerical analyses of the species abundance data sets for each cruise revealed spatial patterns in the ichthyoplankton that suggest the occurrence of geographically distinct assemblages of fish larvae in each region. For all three sampling regions, the assemblage structure is primarily related to bathymetry, and Shelf, Slope, and Deep-Water assemblages are described. This shallow to deep-water gradient in species occurrence and abundance reflects the habitat preference and spawning location of the adult fish. Another degree of complexity is superimposed on this primary assemblage structure in each region and seems to be related to local topography and the prevailing current patterns. The patterns in ichthyoplankton assemblages of the three regions in the northeast Pacific Ocean described here form the basis for future investigations of spatial and temporal patterns in the ichthyoplankton of the subarctic Pacific.Regional Index Terms: Northeast Pacific Ocean, Southeast Bering Sea, Gulf of Alaska, U.S. West Coast.  相似文献   

Usefulness of classification and index properties of clay-rich sediments in evaluating sea-bed environmental conditions     

D. Smith  S. Buchan 《Geo-Marine Letters》2002,22(2):60-65

A comprehensive study of undisturbed, mostly silty clay samples, taken from large-diameter surface cores collected in the North Atlantic and its bordering seas, shows that measurement of the Atterberg limits, water content, specific gravity of grains and grain-size distribution can provide the basis for predicting many seabed geotechnical and geophysical properties which can lead to a quick assessment of environmental conditions. Thus, the sediment compression curve can be reconstructed, acoustic properties assessed, electrical and thermal resistivities deduced and an indication of the shearing forces, which have affected the sediment, inferred.  相似文献   

Acoustic imaging,visualization, and quantification of buoyant hydrothermal plumes in the Ocean     

Rona  P.A.  Bemis  K.G.  Silver  D.  Jones  C.D. 《Marine Geophysical Researches》2002,23(2):147-168

We develop and apply visualization and quantification methods to reconstruct hydrothermal plumes in 3D from acoustic images and to make the first direct measurements from the reconstructions of scalar properties that describe the behavior of two buoyant plumes discharging from adjacent black smoker chimneys. The actual behavior is then compared to that predicted by a classic simple buoyant plume model. The images are reconstructed as isointensity surfaces of backscatter from particulate matter suspended in the plumes. The measurements pertinent to the role of the plumes as agents of dispersal of heat and mass into the ocean include change with height of diameter, particle distribution, dilution, centerline attitude, surface protrusions, and connectivity. The protrusions are the surface expression of eddies and appear to follow a bifurcating helical flow pattern that resemble simulation of the naturally forced flow of coherent vortex rings as the eddies rise with the buoyant plume. These direct measurements and the derived entrainment coefficient are generally consistent with behavior predicted by the simple buoyant plume model and support engulfment by vortex shedding as a primary mechanism for entrainment of surrounding seawater. Deviations from predicted buoyant plume behavior are diagnostic of particle dynamics.  相似文献