Biogeochemical cycles of carbon, sulfur, and free oxygen in a microbial mat   总被引：11，自引：0，他引：11  

Canfield DE  Des Marais DJ 《Geochimica et cosmochimica acta》1993,57(16):3971-3984

Complete budgets for carbon and oxygen have been constructed for cyanobacterial mats dominated by Microcoleus chthonoplastes from the evaporating ponds of a salt works located in Guerrero Negro, Baja California Sur, Mexico. Included in the budget are measured rates of O2 production, sulfate reduction, and elemental exchange across the mat/brine interface, day and night, at various temperatures and times of the year. We infer from this data the various sinks for O2, as well as the sources of carbon for primary production. To summarize, although seasonal variability exists, a major percentage of the O2 produced during the day did not diffuse out of the mat but was used within the mat to oxidize both organic carbon and the sulfide produced by sulfate reduction. At night, most of the O2 that diffused into the mat was used to oxidize sulfide, with O2 respiration of minor importance. During the day, the internal mat processes of sulfate reduction and O2 respiration generated as much or more inorganic carbon (DIC) for primary production as diffusion into the mat. Also, oxygenic photosynthesis was the most important process of carbon fixation, although anoxygenic photosynthesis may have been important at low light levels during some times of the year. At night, the DIC lost from the mat was mostly from sulfate reduction. Elemental fluxes across the mat/brine interface indicated that carbon with an oxidation state of greater than zero was taken up by the mat during the day and liberated from the mat at night. Overall, carbon with an average oxidation state of near zero accumulated in the mat. Both carbon fixation and carbon oxidation rates varied with temperature by a similar amount. These mats are thus closely coupled systems where rapid rates of photosynthesis both require and fuel rapid rates of heterotrophic carbon oxidation.  相似文献   

The concentration and isotopic composition of carbon in basaltic glasses from the Juan de Fuca Ridge, Pacific Ocean     

Blank JG  Delaney JR  Des Marais DJ 《Geochimica et cosmochimica acta》1993,57(4):875-887

The abundance and 13C/12C ratios of carbon were analyzed in basaltic glass from twenty locations along the Juan de Fuca Ridge using a 3-step combustion/extraction technique. Carbon released during the first two combustion steps at 400-500 degrees C and 600-650 degrees C is interpreted to be secondary, and only the carbon recovered during a final combustion step at approximately 1200 degrees C is thought to be indigenous to the samples. For carbon released at approximately 1200 degrees C, glasses analyzed as 1-2 mm chips contained 23-146 ppm C with delta 13C values of -4.8 to -9.3%, whereas samples crushed to 38-63 microns or 63-90 microns yielded 56-103 ppm C with delta 13C values of -6.1 to -9.2%. The concentrations and isotopic compositions of the primary carbon dissolved in the glasses and present in the vesicles are similar to those previously reported for other ocean-ridge basalts. The Juan de Fuca basaltic magmas were not in equilibrium with respect to carbon when they erupted and quenched on the sea floor. Evidence of disequilibrium includes (1) a large range of carbon contents among glasses collected at similar depths, (2) a highly variable calculated carbon isotopic fractionation between melt and vapor determined by comparing crushed and uncrushed splits of the same sample, and (3) a lack of correlation between vesicle abundance, carbon concentration, and depth of eruption. Variations in carbon concentration and delta 13C ratios along the ridge do not correlate with major element chemistry. The observed relationship between carbon concentrations and delta 13C values may be explained by late-stage, variable degrees of open-system (Rayleigh-like) degassing.  相似文献   

Molecular and bulk isotopic analyses of organic matter in marls of the Mulhouse Basin (Tertiary, Alsace, France)     

Hollander DJ  Sinninghe Damste JS  Hayes JM  de Leeuw JW  Huc AY 《Organic Geochemistry》1993,20(8):1253-1263

Contents of 13C in kerogens and carbonates in 21 samples from a core of the MAX borehole, Mulhouse Evaporite Basin, range from -27.3 to -23.5 and -3.7 to -1.8% vs PDB, respectively. Organic nitrogen in the same samples is enriched in 15N relative to atmospheric N2 by 12.2-15.7%. Hydrogen indices and delta values for kerogens vary systematically with facies, averaging 493 mg HC/g Corg and -25.7% in the most saline facies (dominated by inputs from aquatic sources) and 267 mg HC/g Corg and -23.7% in the least saline facies (50/50 aquatic/terrigenous). Values of delta were measured for individual aliphatic hydrocarbons from three samples representing three different organic facies. For all samples, terrigenous inputs were unusually rich in 13C, the estimated delta value for bulk terrigenous debris, apparently derived partly from CAM plants, being -22.5%. In the most saline facies, isotopic evidence indicates the mixing of 13C-depleted products of photosynthetic bacteria with 13C-enriched products of halotolerant eukaryotic algae. At lower salinities, a change in the producer community is marked by a decrease in the 13C content of algal lipids. The content of 13C in algal lipids increases in the least saline facies, due either to succession of different organisms or to decreased concentrations of dissolved CO2.  相似文献   

Theoretical infrared spectra of some model polycyclic aromatic hydrocarbons: effect of ionization     

De Frees DJ  Miller MD  Talbi D  Pauzat F  Ellinger Y 《The Astrophysical journal》1993,408(2):530-538

In order to test the hypothesis of ionized polycyclic aromatic hydrocarbons (PAHs) as possible carriers of the UIR bands, we realized a computational exploration on selected PAHs of small dimension in order to identify which changes ionization would induce on their IR spectra. In this study we performed ab initio calculations of the spectra of neutral and positively ionized naphthalene, anthracene, and pyrene. The results are significantly important. The frequencies in the cations are slightly shifted with respect to the neutral species, but no general conclusion can be reached from the three molecules considered. By contrast, the relative intensities of most vibrations are strongly affected by ionization, leading to a much better agreement between the calculated CH/CC vibration intensity ratios and those deduced from observations.  相似文献   

Preservation of biological information in thermal spring deposits: developing a strategy for the search for fossil life on Mars   总被引：1，自引：0，他引：1  

Walter MR  Des Marais DJ 《Icarus》1993,101(1):129-143

Current interpretations of the early history of Mars suggest many similarities with the early Earth and therefore raise the possibility that the Archean and Proterozoic history of life on Earth could have a counterpart on Mars. Terrestrial experience suggests that, with techniques that can be employed remotely, ancient springs, including thermal springs, could well yield important information. By delivering water and various dissolved species to the sunlit surface of Mars, springs very likely created an environment suitable for life, which could have been difficult, if not impossible, to attain elsewhere. The chemical and temperature gradients associated with thermal springs sort organisms into sharply delineated, distinctive and different communities, and so diverse organisms are concentrated into relatively small areas in a predictable and informative fashion. A wide range of metabolic strategies are concentrated into small areas, thus furnishing a useful and representative sampling of the existing biota. Mineral-charged springwaters frequently deposit chemical precipitates of silica and/or carbonate which incorporate microorganisms and preserve them as fossils. The juxtaposition of stream valley headwaters with volcanoes and impact craters on Mars strongly implies that subsurface heating of groundwater created thermal springs. On Earth, thermal springs create distinctive geomorphic features and chemical signatures which can be detected by remote sensing. Spring deposits can be quite different chemically from adjacent rocks. Individual springs can be hundreds of meters wide, and complexes of springs occupy areas up to several kilometers wide. Benthic microbial mats and the resultant stromatolites occupy a large fraction of the available area. The relatively high densities of fossils and microbial mat fabrics within these deposits make them highly prospective in any search for morphological evidence of life, and there are examples of microbial fossils in spring deposits as old as 300 Myr.  相似文献   

铂族新矿物——峨眉矿OsAs_2的初步研究   总被引：2，自引：0，他引：2  

任迎新  胡钦德  徐进高 《地质学报》1978,52(2)

峨眉矿发现于四川某地铜镍硫化物型铂矿床中。化学成分为锇的二砷化物,化学式为OsAs_2。斜方晶系,晶胞参数为a=5.409,b=6.167,c=3.021。空间群Pnnm或Pnn2。研究结果确定,这是一个铂族金属新矿物。以产地所在省境内的名山——峨眉山命名,称为峨眉矿(Omeiite)。  相似文献   

云南滇东北与玄武岩有关的铜矿床含矿岩系组成与划分   总被引：2，自引：0，他引：2  

侯蜀光  徐章宝  包钢  章正军  钱壮志  高宏光 《矿床地质》2006,25(Z1):75-78

滇东北与玄武岩有关的铜矿床是中国近3年来矿床学研究和资源勘查的热点之一，本文结合科研和资源勘查项目实际工作，对该区域含矿岩系的组成与划分进行了研究和探讨。依据研究，含矿岩系由二叠系峨眉山玄武岩组（P₂e）上部（第三岩性段顶部和第四岩性段）和宣威组（P₂x）底部组成，可划分为5个矿化层，进而对5个矿化层的岩性组成、矿化特征和成矿前景进行全面总结，这将为该区域今后进一步开展找矿和勘查工作提供方向和依据。  相似文献   

环溪河流域土壤氮素含量及影响因素分析     

黄海峰邓良基  胡玉福高雪松 郑小佳 《山地学报》2006,24(B10):98-102

根据67个随机格网样点和分层抽样样点的耕层土壤氮素含量，在ArcGIS9．0平台上运用地统计学等方法研究了环溪河流域土壤氮素含量及其影响因素。结果表明，环溪河流域土壤全氮和碱解氮的平均含量分别为0．60g／kg和53．31mg／kg。研究区土壤全氮含量总体上呈条带状和团块状分布，其低值中心区（〈0．5g／kg）位于团结村不规则三角形区域，并以此为中心向四周增加；高值中心区（〉0．8g／kg）主要位于走马村椭圆状区域。区内土壤碱解氮其高值区（〉75mg／kg）主要分布在深弯村以西，低值区（〈33mg／kg）主要分布于窝窝店村和杨柳村一带。影响区内土壤氮素含量空间分布的因素主要是成土母质、土壤质地、土地利用方式、地貌和坡度。  相似文献   

大别山造山带前陆深地震反射剖面   总被引：18，自引：0，他引：18       下载免费PDF全文

董树文 高锐李秋生  刘晓春钱桂华黄东定  匡朝阳李三忠管烨  白金贺日政  李朋武 《地质学报》2005,79(5):595-601

在大别山南部和扬子地块前陆实施的深地震反射剖面(140 km)揭示出大别山造山带前陆地壳的精细结构。总体北倾的地壳内部结构与向北缓倾的叠瓦状莫霍面反射揭示出扬子陆块向北俯冲的行迹。莫霍面向北插入大别山造山带下与南大别山地壳内南倾反射震相叠置,构成交叉反射图像,刻画出扬子前陆与大别山造山带的碰撞构造面貌。  相似文献   

鲁北平原区暴雨成因及时空分布规律探讨   总被引：3，自引：0，他引：3  

宋少文聂庆林  高广东玉洪超 武俊岭 《水文》2005,25(2):51-53

鲁北平原地处黄泛区，流域坡度较缓，降水量年际变化大，年内分配不均，且多以暴雨形式集中在每年的汛期(6～9月)，同时排涝河道层层建闸拦蓄，造成暴雨期排水不畅，极易积涝成灾。依据1951-2000年实测暴雨资料，对本区暴雨的成因、时空分布规律进行了探讨。  相似文献