Highly alkaline,high-temperature hydrothermal fluids in the early Archean ocean     

Takazo Shibuya  Tsuyoshi Komiya  Kentaro Nakamura  Ken Takai  Shigenori Maruyama 《Precambrian Research》2010

Based on the petrology of hydrothermally altered Archean basaltic greenstones, thermodynamic calculations of phase equilibria were conducted to estimate the composition of a high-temperature (∼350 °C) hydrothermal fluid in an Archean subseafloor basalt-hosted hydrothermal system. The results indicate that the hydrothermal fluid was highly alkaline attributed to the presence of calcite in the alteration minerals under a high-CO₂ condition, and predict a generation of SiO₂-rich, Fe-poor hydrothermal fluids in the Archean subseafloor hydrothermal system. The chemically reactive mixing zones between alkaline hydrothermal fluids and slightly acidic-neutral seawater are characterized by inverse pH and chemical polarity to modern hydrothermal systems, leading to extensive precipitation of silica and iron oxyhydroxides on/under the seafloor. Such processes can be responsible for the abiotic formation of voluminous chert and subseafloor silica dike, the mechanism of silicification, and the pH-controlled generation of banded iron formation that has been arising mainly from the redox chemistry in the Archean ocean. Such high-temperature alkaline fluids could have had a significant role not only in the early ocean geochemical processes but also in the early evolution of life.  相似文献   

Effect of grain growth on cation exchange between dunite and fluid: implications for chemical homogenization in the upper mantle     

Tomohiro Ohuchi  Michihiko Nakamura  Katsuyoshi Michibayashi 《Contributions to Mineralogy and Petrology》2010,160(3):339-357

The effect of grain growth on the cation exchange between synthesized forsterite aggregates (i.e., dunite) and nickel-rich aqueous fluid was evaluated experimentally at 1.2 GPa and 1,200°C. The grain boundary (GB) migration caused nickel enrichment in the area swept by the GBs in a fashion similar to that reported for stable isotope exchange in the quartz aggregates. The progress of the grain growth resulted in an increase in the average nickel concentration in the dunites of up to ~80 times that was calculated for a system having stationary GBs. The overall diffusivity of the nickel along the wet GBs and interconnected fluid networks was found to be 6.5 × 10⁻¹⁹–6.7 × 10⁻¹⁸ m³/s, which is 4–5 orders of magnitude higher than the grain boundary diffusivity in the dry dunite. These results show that the grain growth rate is a fundamental factor in the evaluation of the time scale of chemical homogenization in the upper mantle.  相似文献   

High- and low-velocity impact experiments on porous sintered glass bead targets of different compressive strengths: Outcome sensitivity and scaling     

M. Setoh  A.M. Nakamura  K. Hiraoka  S. Hasegawa  K. Okudaira 《Icarus》2010,205(2):702-711

Impact experiments on porous targets consisting of sintered glass beads have been performed at different impact velocities in order to investigate the disruption impact energy threshold (also called Q^∗) of these targets, the influence of the target compressive strength on this threshold and a scaling parameter of the degree of fragmentation that takes into account material strength. A large fraction of small bodies of our Solar System are expected to be composed of highly-porous material. Depending on their location and on the period considered during the Solar System history, these bodies collide with each other at velocities which cover a wide range of values from a few m/s to several km/s. Determining the impact response of porous bodies in both high- and low-velocity regimes is thus crucial to understand their collisional evolution over the entire Solar System history, from the early stages of planetary formation through collisional accretion at low impact velocities to the current and future stages during which impact velocities are much higher and lead to their disruption. While these problems at large scale can only be addressed directly by numerical simulations, small scale impact experiments are a necessary step which allows the understanding of the physical process itself and the determination of the small scale behavior of the material used as target. Moreover, they are crucial to validate numerical codes that can then be applied to larger scales.Sintered glass beads targets of different shapes and porosity have been built and their main material properties, in particular their compressive strength and their porosity, have been measured. The outcomes of their disruptions both at low and high impact velocities have then been analyzed.We then found that the value of Q^∗ strongly depends on the target compressive strength. Measuring the particle velocities as a function of their distance to the impact point, we first found that the attenuation rate of the stress wave in our sintered glass bead targets does not depend on the impact velocity regime. Ejecta velocities as a function of the distance from the impact point can thus be well fitted by a power law with an exponent about −2 in both velocity regimes. We then looked for a scaling parameter that can apply to both regimes. We found that the scaling parameter PI, which is related to the initial peak pressure and to the stress wave attenuation can be used to represent the outcome in a general way. Future investigations will be performed to determine whether these results can be generalized to other kinds of porous materials.  相似文献   

Determination of Fluorine and Chlorine by Pyrohydrolysis and Ion Chromatography: Comparison with Alkaline Fusion Digestion and Ion Chromatography     

Qiaoyun Wang  Akio Makishima  Eizo Nakamura 《Geostandards and Geoanalytical Research》2010,34(2):175-183

A method to determine F and Cl in silicate materials by employing pyrohydrolysis and ion chromatography (IC) is described. Pyrohydrolysis involved mixing a pulverised sample (∼ 40 mg) with V₂O₅ (∼ 160 mg) and heating to 1100 °C under a wet oxygen flow in a quartz tube. Recovery yields of F and Cl were ∼ 97% using a NaF + NaCl standard solution. Detection limits of the pyrohydrolysis-IC method for silicate samples were 0.36 and 0.69 μg g^-1 for F and Cl, respectively. Fluorine and Cl concentrations were determined in the reference materials JB-2, JB-3 and JA-1 from the GSJ; BCR-2, BHVO-1, BHVO-2, AGV-1 and AGV-2 from the USGS; and NIST SRM 610, 612 and 614 glasses. Precisions (RSD) for determinations of F were 1–13% (except NIST SRM 614) and 2–19% for Cl, and were dependent on the concentration and blank correction. Most results obtained in this study were in good agreement with those of previous studies. In comparison, the Na₂CO₃ + ZnO fusion method at 900 °C showed that the yields of F and Cl by alkaline fusion systematically decreased with fusion duration time. The yields were 84% and 83% for JB-3, inferring that F and Cl were lost in this alkaline fusion.  相似文献   

Condensation and aggregation of solar corundum and corundum‐hibonite grains     

T. M. Nakamura  N. Sugiura  M. Kimura  A. Miyazaki  A. N. Krot 《Meteoritics & planetary science》2007,42(7-8):1249-1265

Abstract— Forty‐three corundum grains (1–11 μm in size) and 5 corundum‐hibonite grains with corundum overgrown by hibonite (4–7 μm in size), were found in the matrix of the mineralogically pristine, ungrouped carbonaceous chondrite Acfer 094 by using cathodoluminescence imaging. Some of the corundum and corundum‐hibonite grains occur as aggregates of 2 to 6 grains having similar sizes. The oxygen isotopic compositions of some of the corundum‐bearing grains suggest their solar nebula origin. ²⁶Al‐²⁶Mg systematics of one corundum grain showed the canonical initial ²⁶Al/²⁷Al ratio, also suggesting a solar nebula origin. Quantitative evaluation of condensation and accretion processes made based on the homogeneous nucleation of corundum, diffusion‐controlled hibonite formation, collisions of grains in the nebula, and critical velocity for sticking, indicates that, in contrast to the hibonite‐bearing aggregates of corundum grains, the hibonite‐free corundum aggregates could not have formed in the slowly cooling nebular region with solar composition. We suggest instead that such aggregates formed near the protosun, either in a region that stayed above the condensation temperature of hibonite for a long time or in a chemically fractionated, Ca‐depleted region, and were subsequently physically removed from this hot region, e.g., by disk wind.  相似文献   

The effect of YORP on Itokawa     

D.J. Scheeres  M. Abe  R. Nakamura  P.A. Abell 《Icarus》2007,188(2):425-429

The effect of solar radiation on the near-term rotation rate of Asteroid Itokawa via the YORP effect is predicted using the detailed shape model, rotation pole, mass estimate, and optical properties derived from the Hayabusa mission to Itokawa. Based on these estimates Itokawa is decelerating at a rate which will halve its rotation rate in only 50-90 thousand years, a large deceleration that should be detectable in a future appartion. The implications of such a large deceleration for Itokawa's past history are discussed and related to possible seismic shaking.  相似文献   

Changes in magnetic and fractal properties of fractured granites near the Nojima Fault, Japan   总被引：2，自引：0，他引：2  

Norihiro Nakamura  Hiroyuki Nagahama 《Island Arc》2001,10(3-4):486-494

Abstract Anisotropy of magnetic susceptibility (AMS) has been used to infer finite strain fabrics in plastically deformed rocks, but there are few studies of magnetic properties in fractured fault rocks. Changes in magnetic and fractal properties of fractured granites from the Disaster Prevention Research Institute, Kyoto University (DPRI) 500 m drilling core towards the Nojima Fault and of the well-foliated fault gouge are described. Fractal analysis of fractured granites shows that the fractal dimension ( D ) increases linearly toward the gouge zone of the fault. In weakly fractured granites ( D = 1.05–1.24), it was found that the degree of AMS correlates positively with the fractal dimension, suggesting a fracture-related magnetic fabric due to fracturing. In strongly fractured granites ( D = 1.25–1.50), weaker, nearly isotropic AMS is found, suggesting erasure by the fragmentation of the magnetic minerals. Within the fault gouge zone, an isotropic AMS fabric was found, as well as twofold increases in magnetic intensity and susceptibility. These changes reflect the production of new magnetite grains, subsequently confirmed by hysteresis studies, which suggests that fault gouge might be regarded as the source of the regional geomagnetic field contrast along active faults. Thus, AMS is clearly a potentially useful tool for inferring the fracturing texture of magnetic minerals in fractured rocks and detecting active faults from the high susceptibility contrast of fault gouge.  相似文献   

Role of precursory less-viscous mixed magma in the eruption of phenocryst-rich magma: evidence from the Hokkaido-Komagatake 1929 eruption     

S. Takeuchi  M. Nakamura 《Bulletin of Volcanology》2001,63(6):365-376

During the 1929 activity of Hokkaido-Komagatake volcano, the Plinian eruption of a phenocryst-rich andesite was preceded by a small eruption of more mafic magma formed by magma mixing. A similar eruption sequence has been reported for some other eruptions (Pallister et al. 1996; Venezky and Rutherford 1997), suggesting that eruption of a mixed magma is a precursor of phenocryst-rich magmas. For the purpose of understanding the tapping processes of the phenocryst-rich magma chamber, we investigated the temporal variation in the erupted magma and estimated the viscosity and density of the end-member and mixed magmas with constraints drawn from petrography. For the precursory mixed magma we estimate 33dž vol.% phenocrysts, andesitic-dacitic melt composition, 3 wt.% H₂O content, and temperature of 1040°C. In comparison, for the climactic, silicic end-member magma we estimate 48Dž vol.% phenocryst, high-silica rhyolitic melt, 3 wt.% H₂O, and temperature of 950°C, respectively. The mafic end-member magma, which was not erupted, is thought to be an almost aphyric basaltic-andesitic magma, based on mass balance calculation of the phenocryst content. The proportion of the mafic end-member magma component in the mixed magma was calculated to be 20-40 wt.%. On the basis of these data, we estimate magma viscosities of 10^3.9, 10^6.9, and 10^2.0 Pa s for the mixed, silicic end-member, and mafic end-member magmas, respectively. The calculated density differences among these magmas are inconsequential when possible errors are considered. We calculate the minimum excess pressure required for dike propagation to be 31 MPa for the silicic end-member magma and 8 MPa for the mixed magma, using the estimated viscosity and dike propagation model of Rubin (1995). If we assume that excess pressure is limited by the wall rock strength of the magma chamber, excess pressure retainable in the magma chamber is less than ca. 20 MPa. This suggests that the mixed magma was able to ascend to the surface without freezing, whereas the viscous silicic end-member magma could not. The formation and precursory eruption of the mixed magma are, therefore, effective and necessary initiation processes for the phenocryst-rich, viscous magma eruption.  相似文献   

Clinopyroxenes in the tawhiroko tholeiitic dolerite at Moeraki,north-eastern Otago,New Zealand     

Yasuo Nakamura  D. S. Coombs 《Contributions to Mineralogy and Petrology》1973,42(3):213-228

Clinopyroxenes from various lithologic units in a single tholeiitic dolerite intrusion 50 m thick were analysed with the electron microprobe. Microphenocrysts of augite in the chilled marginal rock have the least scattered CaMgFe ratios, around Ca₃₈Mg₅₀Fe₁₂, and lowest Ti/Al ratios, less than 1/4, of the augites examined; they crystallized prior to emplacement. The augites which crystallized in situ are more Fe-rich and have higher Ti/Al ratios, close to 1/2. Pigeonite started crystallizing later than augite and formed rims to augite crystals. Continuous zoning from augite to subcalcic augite as was previously reported by Benson (1944) for the same dolerite is not observed. Subcaloic ferroaugites, however, link augite and ferropigeonite in the outermost margins of pyroxenes in the later segregations. The small scale differentiation in situ gave rise to globules, veins, and pegmatoids, in which sector-zoning of augite is well developed. The {100} sectors are enriched in MgSiO₃, FeSiO₃, and MnSiO₃ components relative to the {010} and the {110} sectors, and are accordingly depleted in other components. The protosite theory of sector-zoning formation proposed by Nakamura (1973) is further developed and the environment which favours the development of sector-zoning is discussed. The formation of augite rims around quartz-rich xenoliths and the compositional characteristics of the augites concerned are due to local high silica activities. Comments are made concerning some lunar pyroxenes in the light of the present study.  相似文献   

Chondrites with peculiar rare-earth patterns     

Noboru Nakamura  Akimasa Masuda 《Earth and Planetary Science Letters》1973,19(4):429-437

Rare-earth elements and Ba in Khohar, Abee, Indarch, Atlanta, Jajh deh Kot Lalu, and Nakhla were determined accurately by isotope dilution technique; for Atlanta only, Fe (total), Mg and Ca were also determined. Khohar shows in two aliquants a strikingly large, positive anomaly for Ce. A fragment of Abee is outstanding in having a large positive Yb anomaly and a zigzag RE pattern. It is considered that the Yb anomaly is not necessarily associated with the zigzaggedness in question. Anyway, these facts corroborate our previous observations that abundances of Ce and/or Yb could be sometimes anomalous in meteoritic and lunar materials.Atlanta also has a significant negative Eu anomaly, similar to the Eu depletions observed in lunar basalts and Ca-poor achondrites by other workers. Besides, this enstatite chondrite has a RE pattern which indicates that this meteorite is cumulate-type (solid-type) material separated perhaps from a considerably fractionated melt. Accordingly, it is suggested that it is not always appropriate to classify this type II enstatite chondrite as “chondrite”. Two fragments from Abee and Atlanta show different RE patterns. It is also observed that Ba abundances are sometimes sporadically and irregularly high.  相似文献