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81.
The Queensland Environmental Protection Agency monitored water quality at 133 sites in North Queensland waterways between Cooktown and Bundaburg from 1992 to 2001. Condition of the waterways was rated by comparing recent data with the Queensland Water Quality Guidelines. Long-term trends were analysed using a censored regression technique that incorporates the effects of flow, temperature, seasonality and allows for long-term non-linear trends. Many sites were in good condition; those in poor condition were usually impacted by point source discharges; those in moderate condition were usually impacted by agricultural land use. There were no consistent long-term trends across the whole region. Recommendations for future programs include incorporating pressure indicators, ensuring high standards of quality assurance, including covariates such as rainfall in trend assessment and continuing programs over more than 10 years to allow detection of trends due to changes in land-use. 相似文献
82.
New spectra of Jupiter in the region 0.93–1.63 are presented. Laboratory comparisons of spectra of NH3 and CH4 permit estimates of the absorbing pathlength for various bands of these two gases. Abundances in a single transmission through the Jupiter atmosphere, above the mean reflecting level, vary from 10 to 100 m-atm for CH4 and from 0.2–5 m-atm for NH3, depending on the bands considered. Upper limits for other gases are derived from new laboratory spectra and comparison with the Jupiter spectra presented herein. These are as follows: C2H2<2 m-atm, H2S<0.25 m-atm, HCN<0.05 m-atm, CH3NH2<0.02 m-atm. A table summarizing the chemical composition of Jupiter's atmosphere is presented. 相似文献
83.
Nicholas J. Cox 《The Professional geographer》1980,32(1):51-54
Hitch-hiking has been ignored by traditional geography. In this article it is shown that ideas and techniques from the new geography yield substantial insights into its character as a spatial process. 相似文献
84.
Infrared spectrophotometric measurements of Neptune's satellite Triton obtained between 1980 and 1982 in the spectral range 0.8–2.5 μm show six individual absorption bands attributable to methane. An additional band in the Triton data is not methane. The Triton spectral data conform more closely to a laboratory spectrum of frozen methane than to a synthetic spectrum of methane gas computed for conditions of low temperature expected at the satellite. Additionally, the strength of the bands vary with Triton's orbital position. The data thus suggest that methane in the ice phase is mostly responsible for the bands in Triton's spectrum, and that the ice is distributed nonuniformly around the satellite's surface. 相似文献
85.
Bistability of the thermohaline circulation identified through comprehensive 2-parameter sweeps of an efficient climate model 总被引:2,自引:0,他引:2
R. Marsh A. Yool T. M. Lenton M. Y. Gulamali N. R. Edwards J. G. Shepherd M. Krznaric S. Newhouse S. J. Cox 《Climate Dynamics》2004,23(7-8):761-777
The effect of changes in zonal and meridional atmospheric moisture transports on Atlantic overturning is investigated. Zonal transports are considered in terms of net moisture export from the Atlantic sector. Meridional transports are related to the vigour of the global hydrological cycle. The equilibrium thermohaline circulation (THC) simulated with an efficient climate model is strongly dependent on two key parameters that control these transports: an anomaly in the specified Atlantic–Pacific moisture flux (Fa) and atmospheric moisture diffusivity (Kq). In a large ensemble of spinup experiments, the values of Fa and Kq are varied by small increments across wide ranges, to identify sharp transitions of equilibrium THC strength in a 2-parameter space (between Conveyor On and Off states). Final states from this ensemble of simulations are then used as the initial states for further such ensembles. Large differences in THC strength between ensembles, for identical combinations of Fa and Kq, reveal the co-existence of two stable THC states (Conveyor On and Off)—i.e. a bistable regime. In further sensitivity experiments, the model is forced with small, temporary freshwater perturbations to the mid-latitude North Atlantic, to establish the minimum perturbation necessary for irreversible THC collapse in this bistable regime. A threshold is identified in terms of the forcing duration required. The model THC, in a Conveyor On state, irreversibly collapses to a Conveyor Off state under additional freshwater forcing of just 0.1 Sv applied for around 100 years. The irreversible collapse is primarily due to a positive feedback associated with suppressed convection and reduced surface heat loss in the sinking region. Increased atmosphere-to-ocean freshwater flux, under a collapsed Conveyor, plays a secondary role. 相似文献
86.
Employing first-principles methods, the docking sites for H were determined and H, Al, and vacancy defects were modeled with an infinite periodic array of super unit cells each consisting of 27 contiguous symmetry nonequivalent unit cells of the crystal structure of stishovite. A geometry optimization of the super-cell structure reproduces the observed bulk structure within the experimental error when P1 translational symmetry was assumed and an array of infinite extent was generated. A mapping of the valence electrons for the structure displays mushroom-shaped isosurfaces on the O atom, one on each side of the plane of the OSi3 triangle in the nonbonded region. An H atom, placed in a cell near the center of the super cell, was found to dock upon geometry optimization at a distance of 1.69 Å from the O atom with the OH vector oriented nearly perpendicular to the plane of the triangle such that the OH vector makes a angle of 91° with respect to [001]. However, an optimization of a super cell with an Al atom replacing Si and an H atom placed nearby in a centrally located cell resulted in an OH distance of 1.02 Å with the OH vector oriented perpendicular to [001] as observed in infrared studies. The geometry-optimized position of the H atom was found to be in close agreement with that (0.44, 0.12, 0.0) determined in an earlier study of the theoretical electron density distribution. The docking of the H atom at this site was found to be 330 kJ mol–1 more stable than a docking of the atom just off the shared OO edge of the octahedra as determined for rutile. A geometry optimization of a super cell with a missing Si generated a vacant octahedra that is 20% larger than that of the SiO6 octahedra. The valence electron density distribution displayed by the two-coordinate O atoms that coordinate the vacant octahedral site is very similar to those displayed by the bent SiOSi angles in coesite. The internal distortions induced by the defect were found to diminish rather rapidly with distance, with the structure annealing to that observed in the bulk crystal to within about three coordination spheres. 相似文献
87.
Mesoscale structures in Paleozoic rocks of the Ozark plateaus reveal four Pennsylvanian deformation episodes in midcontinent North America. The two earliest episodes can be assigned to progressive northwestward docking of the Ouachita terrane with North America. Early extensional structures (Event 1) indicate a northwest/southeast maximum horizontal stress (Hmax) during Early Pennsylvanian Ouachita terrane advance. Event 2 extensional and strike-slip structures indicate Hmax across the Ozark plateaus that varies systematically from north-northwest/south-southeast in the south to northeast/southwest in the north. This suggests development of a slip-line deformation field in response to minor northeastward lateral escape of lithospheric blocks away from the northwestward-moving Ouachita terrane's leading edge, which acted as an indenter in western Arkansas, southeastern Oklahoma, and Texas. Younger contractional and strike-slip structures of Event 3 indicate northeast/southwest Hmax across the entire Ozark plateaus, and deformation orientation and intensity are not readily assigned to Ouachita foreland deformation and may be related to Middle Pennsylvanian Ancestral Rockies contractional deformation. Finally, Event 4 contractional structures indicate northwest/southeast Hmax consistent with southern Appalachian late stage convergence.Deformation episodes are localized along basement fault zones, particularly at major bends, suggesting minor restraining-bend uplifts along strike-slip faults. Geometries of conjugate normal fault and hybrid shear joint arrays indicate localized areas of high differential stress consistent with basement block uplift at these bends. High-angle faults reactivated in a reverse sense and bedding-parallel veins suggest tensile minimum stresses and pore fluid pressures exceeding lithostatic stress, consistent with brine pulses driven into the midcontinent during Late Paleozoic orogeny (as proposed by other authors). 相似文献
88.
89.
90.
We analyze the dynamics of the broadband frequency spectrum of 338 microwave bursts observed in the years 2001?–?2002 with the Owens Valley Solar Array. A subset of 38 strong microwave bursts that show a single spectral maximum are studied in detail. Our main goal is to study changes in spectral peak frequency ν pk with time. We show that, for a majority of these simple bursts, the peak frequency shows a high positive correlation with flux density – it increases on the rise phase in ≈83% of 24 bursts where it could be cleanly measured, and decreases immediately after the peak time in ≈62% of 34 bursts. This behavior is in qualitative agreement with theoretical expectations based on gyrosynchrotron self-absorption. However, for a significant number of events (≈30?–?36%) the peak frequency variation is much smaller than expected from self-absorption, or may be entirely absent. The observed temporal behavior of ν pk is compared with a simple model of gyrosynchrotron radio emission. We show that the anomalous behavior is well accounted for by the effects of Razin suppression, and further show how an analysis of the temporal evolution of ν pk can be used to uniquely determine the relative importance of self-absorption and Razin suppression in a given burst. The analysis technique provides a new, quantitative diagnostic for the gyrosynchrotron component of solar microwave bursts. Applying this analysis technique to our sample of bursts, we find that in most of the bursts (60%) the spectral dynamics of ν pk around the time of peak flux density is caused by self-absorption. On the other hand, for a significant number of events (≈70%), the Razin effect may play the dominant role in defining the spectral peak and dynamics of ν pk, especially on the early rise phase and late decay phase of the bursts. 相似文献