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91.
We present a multi‐chronometric approach for reconstructing deep‐time thermal histories using southern Baffin Island as a case study. This continuous thermal history begins with the Palaeoproterozoic Trans‐Hudson Orogeny and is derived from inverse and forward models that integrate thermochronometers spanning some 500°C: new apatite U–Pb ages and K‐feldspar 40Ar/39Ar multi‐diffusion domain data, published (U–Th)/He zircon ages and new multi‐kinetic fission‐track results. Integration of data from a wider temperature range reduces ambiguities in thermal‐history modelling and permits us to constrain the timing of geological processes including, extended post‐orogenic cooling, enhanced later Proterozoic cooling, and then episodic burial and exhumation in the Palaeozoic–Mesozoic.  相似文献   
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Parameter estimation from the elliptical variations in the normal-moveout (NMO) velocity in azimuthally anisotropic media is sensitive to the angular separation between the survey lines in 2D, or equivalently, the source-to-receiver azimuth in 3D, and to the set of azimuths used in the inversion procedure. The accuracy in estimating the orientation of an NMO ellipse, in particular the parameter α, is also sensitive to the magnitude of anisotropy. On the other hand, the accuracy in estimating the semi-axes of the NMO-velocity ellipse is about the same for any magnitude of anisotropy.   To invert for the NMO ellipse parameters at least three NMO-velocity measurements along distinct azimuth directions are needed. In order to maximize the accuracy and stability in parameter estimation, it is best to have the azimuths for the three source-to-receiver directions 60° apart. Having more than three distinct source-to-receiver azimuths (e.g. full azimuthal coverage) provides a useful data redundancy that enhances the quality of the estimates.   In order to maximize quality in the inversion process, it is recommended to design the seismic data acquisition such that it contains small sectors (≤10°) with adequate fold and offset distribution.   Using three NMO-velocity measurements, 60° apart, an azimuthally anisotropic layer overlain by an azimuthally isotropic overburden (as might occur for fractured reservoirs) should have a relative thickness (in time) with respect to the total thickness at least equal to the ratio of the error in the NMO (stacking) velocity to the interval anisotropy of the fractured layer. Coverage along more than three azimuths, however, improves this limitation, which is imposed by Dix differentiation, by at most 50%, depending on the number of observations (NMO velocities) that enter the inversion procedure.  相似文献   
96.
Noninvasive geophysical estimation of soil moisture has potential to improve understanding of flow in the unsaturated zone for problems involving agricultural management, aquifer recharge, and optimization of landfill design and operations. In principle, several geophysical techniques (e.g., electrical resistivity, electromagnetic induction, and nuclear magnetic resonance) offer insight into soil moisture, but data‐analysis tools are needed to “translate” geophysical results into estimates of soil moisture, consistent with (1) the uncertainty of this translation and (2) direct measurements of moisture. Although geostatistical frameworks exist for this purpose, straightforward and user‐friendly tools are required to fully capitalize on the potential of geophysical information for soil‐moisture estimation. Here, we present MoisturEC, a simple R program with a graphical user interface to convert measurements or images of electrical conductivity (EC) to soil moisture. Input includes EC values, point moisture estimates, and definition of either Archie parameters (based on experimental or literature values) or empirical data of moisture vs. EC. The program produces two‐ and three‐dimensional images of moisture based on available EC and direct measurements of moisture, interpolating between measurement locations using a Tikhonov regularization approach.  相似文献   
97.
The characterization of pore-space connectivity in porous media at the sediment/water interface is critical in understanding contaminant transport and reactive biogeochemical processes in zones of groundwater and surface-water exchange. Previous in situ studies of dual-domain (i.e., mobile/less-mobile porosity) systems have been limited to solute tracer injections at scales of meters to hundreds of meters and subsequent numerical model parameterization using fluid concentration histories. Pairing fine-scale (e.g., sub-meter) geoelectrical measurements with fluid tracer data over time alleviates dependence on flowpath-scale experiments, enabling spatially targeted characterization of shallow sediment/water interface media where biogeochemical reactivity is often high. The Dual-Domain Porosity Apparatus is a field-tested device capable of variable rate-controlled downward flow experiments. The Dual-Domain Porosity Apparatus facilitates inference of dual-domain parameters, i.e., mobile/less-mobile exchange rate coefficient and the ratio of less mobile to mobile porosity. The Dual-Domain Porosity Apparatus experimental procedure uses water electrical conductivity as a conservative tracer of differential loading and flushing of pore spaces within the region of measurement. Variable injection rates permit the direct quantification of the flow-dependence of dual-domain parameters, which has been theorized for decades but remains challenging to assess using existing experimental methodologies.  相似文献   
98.
We investigate the gravitational fragmentation of expanding shells in the context of the linear thin-shell analysis. We make use of two very different numerical schemes; the flash adaptive mesh refinement code and a version of the Benz smoothed particle hydrodynamics code. We find that the agreement between the two codes is excellent. We use our numerical results to test the thin-shell approximation and we find that the external pressure applied to the shell has a strong effect on the fragmentation process. In cases where shells are not pressure-confined, the shells thicken as they expand and hydrodynamic flows perpendicular to the plane of the shell suppress fragmentation at short wavelengths. If the shells are pressure-confined internally and externally, so that their thickness remains approximately constant during their expansion, the agreement with the analytical solution is better.  相似文献   
99.
Monitoring of a well‐defined septic system groundwater plume and groundwater discharging to two urban streams located in southern Ontario, Canada, provided evidence of natural attenuation of background low level (ng/L) perchlorate (ClO4?) under denitrifying conditions in the field. The septic system site at Long Point contains ClO4? from a mix of waste water, atmospheric deposition, and periodic use of fireworks, while the nitrate plume indicates active denitrification. Plume nitrate (NO3?‐N) concentrations of up to 103 mg/L declined with depth and downgradient of the tile bed due to denitrification and anammox activity, and the plume was almost completely denitrified beyond 35 m from the tile bed. The ClO4? natural attenuation occurs at the site only when NO3?‐N concentrations are <0.3 mg/L, after which ClO4? concentrations decline abruptly from 187 ± 202 to 11 ± 15 ng/L. A similar pattern between NO3?‐N and ClO4? was found in groundwater discharging to the two urban streams. These findings suggest that natural attenuation (i.e., biodegradation) of ClO4? may be commonplace in denitrified aquifers with appropriate electron donors present, and thus, should be considered as a remediation option for ClO4? contaminated groundwater.  相似文献   
100.
This study was designed to improve our understanding of, and mechanistically simulate, nitrate (NO3) dynamics in a steep 9.8 ha rural headwater catchment, including its production in soil and delivery to a stream via surface and subsurface processes. A two‐dimensional modelling approach was evaluated for (1) integrating these processes at a hillslope scale annually and within storms, (2) estimating denitrification, and (3) running virtual experiments to generate insights and hypotheses about using trees in streamside management zones (SMZs) to mitigate NO3 delivery to streams. Total flow was mathematically separated into quick‐ and slow‐flow components; the latter was routed through the HYDRUS software with a nitrogen module designed for constructed wetlands. Flow was monitored for two years. High surface‐soil NO3 concentrations started to be delivered to the stream via preferential subsurface flow within two days of the storm commencing. Groundwater NO3‐N concentrations decreased from 1.0 to less than 0.1 mg l?1 from up‐slope to down‐slope water tables, respectively, which was attributed to denitrification. Measurements were consistent with the flushing of NO3 mainly laterally from surface soil during and following each storm. The model accurately accounted for NO3 turnover, leading to the hypotheses that denitrification was a minor flux (<3 kg N ha?1) compared to uptake (98?127 kg N ha?1), and that SMZ trees would reduce denitrification if they lowered the water table. This research provides an example of the measurement and modelling of NO3 dynamics at a small‐catchment scale with high spatial and temporal resolution. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
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