Boron isotopic fractionation related to boron sorption on humic acid and the structure of surface complexes formed     

Emmanuel Lemarchand  Jérôme Gaillardet 《Geochimica et cosmochimica acta》2005,69(14):3519-3533

Boron isotopic fractionation during adsorption onto Ca-flocculated Aldrich humic acid (HA) has been investigated experimentally as a function of solution pH at 25°C and I = 0.15 M. Boron aqueous concentration and isotopic composition were determined by Cs₂BO₂⁺ Positive Thermal Ionization Mass Spectrometry analysis, while the structure of B surface complexes on HA was characterized using ¹¹B Magic Angle Spinning Nuclear Magnetic Resonance (MAS NMR). Significant B sorption on HA was observed at 6 < pH < 12 with a maximum value of Kd, the partition coefficient between adsorbed and aqueous boron, equal to 40 at pH = 9.5-10. Combined ¹¹B MAS NMR analysis and FITEQL modeling of B sorption on HA showed that this element forms tetrahedrally coordinated five- or six-membered ring chelates, most likely 1,2-diol and 1,3-diol complexes at alkaline pH (8 < pH < 11) and dicarboxylic complexes at near neutral conditions (6 < pH < 9). Results of this study demonstrate for the first time that boron sorption on HA induces a strong pH-dependent isotope fractionation—with ¹¹B depleted at the surface of HA—that reaches a maximum at 5 < pH < 9 (α = 0.975, Δ = −25‰) and decreases sharply at pH >9. The measured isotope fractionation cannot be modeled assuming that the isotopic composition of the sorbed borate species is identical to that of B(OH)₄^- species in the parent solution. It is shown that the extent of isotopic fractionation depends not only on B aqueous speciation but also on the distribution and structure of the borate surface complexes formed. In agreement with energetic constrains, calculation of the isotope fractionation factors between aqueous boric acid and boron surface complexes suggests that the formation of the strained six-membered ring 1,3-diol complex yields a much higher fractionation (α_BLP1−III = 0.954-0.960, Δ = −41/-47‰) than that of the very stable five-membered ring 1,2-diol (α_BLP2−III = 0.983, Δ = −18‰). The results of this study open new perspectives to understand and model boron biogeochemical cycle. It is predicted that boron sorption onto organic matter can have important consequences for the boron isotopic composition of surface water reservoirs (seawater, groundwater, soil waters) in which either abundant organic surfaces or significant boron concentrations are available. In addition, the large isotope fractionation between aqueous boric acid and surface boron-organic complexes found in the present work makes boron a promising tracer of biologic activity.  相似文献   

Sédimentologie et paléontologie des paléoenvironnements côtiers rupéliens de la Molasse marine rhénane dans le Jura suisse     

Laurent Picot  Damien Becker  Lionel Cavin  Claudius Pirkenseer  Frédéric Lapaire  Gaëtan Rauber  Peter A. Hochuli  Silvia Spezzaferri  Jean-Pierre Berger 《Swiss Journal of Geoscience》2008,101(2):483-513

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The Value of Wastewater Derived Struvite as a Source of Phosphorus Fertilizer          下载免费PDF全文

Chirag M. Mehta  Malcolm N. Hunter  Gaius Leong  Damien J. Batstone 《洁净——土壤、空气、水》2018,46(7)

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On the small-scale fractal geometrical structure of a living coral reef barrier     

Damien Sous  Frédéric Bouchette  Erik Doerflinger  Samuel Meulé  Raphael Certain  Gwladys Toulemonde  Benjamin Dubarbier  Bernard Salvat 《地球表面变化过程与地形》2020,45(12):3042-3054

The topographical complexity of coral reefs is of primary importance for a number of hydrodynamical and ecological processes. The present study is based on a series of high-resolution seabottom elevation measurements along the Maupiti Barrier Reef, French Polynesia. Several statistical metrics and spectral analysis are used to characterize the spatial evolution of the coral geometrical structure from the reef crest to the backreef. A consistent fractal-like power law exists in the spectral density of bottom elevation for length scales between 0.1 and 7 m, while at larger scale, the reef structure shows a different pattern. Such a fine characterization of the reef geometrical structure provides key elements to reconstruct the reef history, to improve the representation of reef roughness in hydrodynamical models and to monitor the evolution of coral reef systems in the context of global change. © 2020 John Wiley & Sons, Ltd.  相似文献   

Exploring the past through lynchet landscapes in the Vosges Mountains and the Lorraine Plateau (France)     

Benjamin Keller  Robin Vincent  Dominique Schwartz  Damien Ertlen 《Geoarchaeology》2024,39(3):300-319

Lynchets are ridges formed by erosion and sediment accumulation downstream of agricultural plots and offer valuable insights into past agricultural activity. These microtopographies cover vast areas and serve as indicators of historical changes in land use. As a result, their ubiquity across Europe makes them particularly interesting. In this study, we propose a geoarchaeological approach to analyze six lynchets, four in the Vosges Mountains and two on the Lorraine Plateau (France). The lynchets can be considered soil archives with no stratigraphic organization or chronological sequence from bottom to top, making it difficult to determine the age of the lynchets and identify changes in land use over time. To this end, we propose the analysis of historical and geo-historical archives combined with the “pedosedimentary” archives of lynchets through charcoal identification and dating combined with near-infrared spectroscopy to determine the age, vegetation, and past land use changes associated with lynchet landscapes. By combining these multiple data sources, we are better able to show the chronological development of these ancient agricultural systems and uncover valuable information on landscape history. Charcoal dating suggests a higher frequency of fires from the Middle Ages. The dating aligns with the regional dynamics of anthropogenic fires, indicating a potential use of fire for cultural purposes. We also demonstrate the difficulty of extrapolating the dating of a lynchet to the entire lynchet system. Our results highlight the difficulties of interpreting the formation and dating of lynchets and the lynchet system on the sole basis of charcoal analysis. However, we highlight the value of applying pedoanthracology to lynchets to determine the dynamics of land use change in former fields.  相似文献