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51.
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Thailand has undergone significant forest cover changes in recent decades, and this is likely to have altered the hydrological functioning of many watersheds; however, such potential impacts are not fully understood. To contribute towards a better understanding of the potential hydrological impacts of forest cover changes, this study examines the temporal trends of several hydrological indices in eight watersheds of Thailand over the period from 1982 to 2013. A number of hydrological indices (runoff coefficient, baseflow index, flow duration indices, streamflow elasticity, dryness index) were analysed using a combined Thiel–Sen/Mann–Kendall trend-testing approach, to assess the magnitude and significance of patterns in the observed data. These trend tests indicated that the change in the hydrological response of watersheds varied with the change in structure and composition of forest species. A significant increase in runoff (viz. average flow) was observed in those watersheds covered with natural forests, whereas a significant reduction in runoff (viz. baseflow and low runoff) was observed in those watersheds where the land cover was changed to Para rubber plantations and reforested areas. It is also noteworthy that the watersheds covered by natural forest showed more streamflow elasticity than plantations or reforested areas. These results highlight the importance of considering both forest types/dynamics and watershed characteristics when assessing hydrological impacts.  相似文献   
53.
The Allende matrix is dominated by micron‐sized lath‐shaped fayalitic olivine grains with a narrow compositional range (Fa40–50). Fayalitic olivines also occur as rims around forsterite grains in chondrules and isolated forsterite fragments in the matrix or as veins cross‐cutting the grains. Allende is a type 3 CV carbonaceous chondrite having experienced a moderate thermal metamorphism. There is therefore a strong chemical disequilibrium between the large forsterite grains and the fayalite‐rich fine‐grained matrix. Chemical gradients at interfaces are poorly developed and thus not accessible using conventional techniques. Here, we used analytical transmission electron microscopy to study the microstructure of the fayalite‐rich matrix grains and interfaces with forsterite fragments. We confirm that fayalitic grains in the matrix and fayalitic rims around forsterite fragments have the same properties, suggesting a common origin after the accretion of the parent body of Allende. Composition profiles at the rim/forsterite interfaces exhibit a plateau in the rim (typically Fa45), a compositional jump of 10 Fa% at the interface, and a concentration gradient in the forsterite grain. Whatever the studied forsterite grain or whatever the nature of the interface, the Fe‐Mg profiles in forsterite grains have the same length of about 1.5 μm. This strongly suggests that the composition profiles were formed by solid‐state diffusion during the thermal metamorphism episode. Time–temperature couples associated with the diffusion process during thermal metamorphism are deduced from profile modeling. Considering the uncertainties on the diffusion coefficient value, we found that the peak temperature in Allende is ranging from 425 to 505 °C.  相似文献   
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Within fractured rock, the irregular and often unpredictable distribution and geometry of hydraulically conductive fractures produces large spatial variations in bore yield and groundwater quality. As fractures act as conduits for flow of both groundwater and electrical charge, methods which can efficiently detect the distribution of electrical pathways can be used to infer characteristics of significant hydrological parameters. This study compares the capabilities and limitations of electrical data obtained from direct current (DC) and electromagnetic (EM) surface azimuthal measurements, and from DC borehole-to-surface and cross-borehole measurements, for the interpretation of major hydrological structures in Clare Valley, South Australia. Electrical and EM surface methods are limited by poor depth sensitivity and the presence of conductive overburden, but provide useful tools for determining directional variations in resistivity at sites lacking bedrock exposure and boreholes. Application of borehole-to-surface methods yielded a better-resolved interpretation of sub-vertical fracture strike and was useful in identifying lateral variations in bedrock heterogeneity. Improved flexibility and sensitivity to measurements at depth permitted cross-borehole electrical tomography data to be used in reconstructing the spatial distribution of sub-horizontal, laterally extensive, electrically conductive zones. While the technique is restricted to small-scale sites with multiple boreholes, inferences can be made on fluid connections over a much larger regional scale. It is important to note, however, that while electrical methods provide valuable information about in-situ hydraulic pathways, they do not provide a complete hydraulic characterisation. Such a task requires integration of surface and borehole geophysics, geologic mapping, sampling and pumping tests of wells with packed-off intervals.
Resumen La geometría, y con frecuencia impredecible, distribución irregular de fracturas hidráulicamente conductivas dentro de roca fracturada genera variaciones espaciales grandes en producción de pozos y calidad de agua subterránea. Debido a que las fracturas actúan como conductos de flujo de agua y carga eléctrica, los métodos que detectan eficientemente la distribución de trayectorias eléctricas pueden utilizarse para inferir las características de parámetros hidrológicos significativos. Este estudio compara las capacidades y limitaciones de datos eléctricos obtenidos de mediciones azimutales superficiales electromagnéticas (EM) y de corriente directa (DC), y de mediciones de DC realizadas en la superficie y pozos así como mediciones realizadas entre pozos para la interpretación de estructuras hidrológicas principales en el Valle Clare, sur de Australia. Los métodos superficiales eléctricos y EM están limitados por sensitividad de profundidad pobre y la presencia de cubierta conductiva, pero aportan herramientas útiles para determinar variaciones direccionales de resistividad en sitios que carecen de pozos y afloramientos rocosos. La aplicación de métodos superficiales y de pozos aportan una mejor interpretación del rumbo de fracturas sub-verticales y fue útil en identificar variaciones laterales en la heterogeneidad del macizo rocoso. El mejoramiento de flexibilidad y sensitividad en las mediciones profundas permitió que los datos de tomografía eléctrica de los pozos fuera utilizado en la reconstrucción de la distribución espacial de zonas eléctricas conductivas, sub-horizontales y lateralmente extensas. Aunque la técnica está restringida a sitios de pequeña escala con múltiples pozos, puede realizarse inferencias sobre relaciones entre fluidos en una escala regional mucho más grande. Sin embargo, es importante notar que aunque los métodos eléctricos aportan información valiosa acerca de las trayectorias hidráulicas in-situ, aún no proporcionan una caracterización hidráulica completa. Esta tarea requiere integrar geofísica superficial y de pozos, mapeo geológico, muestreo y pruebas de bombeo en pozos con intervalos sin empaque.

Résumé Au sein des roches fracturées, lirrégularité et limprédictible distribution et géométrie des fractures par lesquelles sécoulent leau souterraine produit de larges variations spatiales entre les débits des forages et les paramètres de la qualité de leau. Comme les fractures conduisent et leau et les charges électriques, les méthodes qui peuvent de manière efficiente détecter la distribution des courants électriques peuvent être utilisées pour analyser les caractéristiques des principaux paramètres hydrologiques. Cette étude compare les capacités et les limites des données produites par Courant Direct (DC en Anglais) et par mesure Electromagnétique azimutale de surface (EM en Anglais), et par DC entre surface et forage et entre plusieurs forages, pour linterprétation de la structure hydrologique de la Vallée de Clare, Australie du Sud. Les méthodes électriques et électromagnétiques sont limitées par la faible sensitivité à la profondeur et la présence dune couverture conductrice, mais procure des outils utiles pour déterminer les variations directionnelles en terme de résistivité là où la roche nest pas affleurante et dans les puits. Lapplication de la méthode dinvestigation «forage à surface» apporte une meilleure interprétation des fractures sub-verticales et des hétérogénéités latérales. Les tomographies électriques entre forage bénéficient de la flexibilité et de la sensibilité des mesures en profondeur, et permettent de délimiter lextension latérale des hétérogénéités sub-horizontales de zones conductrices. Alors que la technique est restreinte à de petits sites comprenant de nombreux forages, il est possible de reconstituer les connections hydrauliques à des échelles régionales. Il est important de noter que les méthodes fournissent des informations intéressantes mais pas des caractérisations hydrauliques complètes. Pour cela les données pourraient être complétées par des études plus poussées intégrant les différentes prospections géophysique, les données des cartes géologiques, des échantillonnages et des essais de pompage à différents intervalles de profondeur.
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56.
We report silicon isotopic determinations for USGS rock reference materials BHVO-1 and BHVO-2 using a Nu Plasma multi-collector (MC)-ICP-MS, upgraded with a new adjustable entrance slit, to obtain medium resolution, as well as a stronger primary pump and newly designed sampler and skimmer cones ("B" cones). These settings, combined with the use of collector slits, allowed a resolution to be reached that was sufficient to overcome the 14N16O and 14N2 interferences overlying the 30Si and the 28Si peaks, respectively, in an earlier set-up. This enabled accurate measurement of both δ30Si and δ29Si. The δ value is expressed in per mil variation relative to the NBS 28 quartz reference material. Based on data acquired from numerous sessions spread over a period of six months, we propose a recommended average δ30Si of −0.33 ± 0.05‰ and −0.29 ± 0.11‰ (2se) for BHVO-1 and BHVO-2, respectively. Our BHVO grand mean silicon isotope composition (δ30Si =−0.31 ± 0.06‰) is significantly more negative than the only published value for BHVO-2, but is in very good agreement with the recently established average value of ocean island basalts (OIB), confirming the conclusion that the OIB reservoir has a distinct isotopic composition from the solar reservoir as sampled by chondrites.  相似文献   
57.
The smectite-to-chlorite conversion is investigated through long-duration experiments (up to 9 years) conducted at 300 °C. The starting products were the Wyoming bentonite MX80 (79 % smectite), metallic iron and magnetite in contact with a Na–Ca chloride solution. The predominant minerals in the run products were an iron-rich chlorite (chamosite like) and interstratified clays interpreted to be chlorite/smectite and/or corrensite/smectite, accompanied by euhedral crystals of quartz, albite and zeolite. The formation of pure corrensite was not observed in the long-duration experiments. The conversion of smectite into chlorite over time appears to take place in several steps and through several successive mechanisms: a solid-state transformation, significant dissolution of the smectite and direct precipitation from the solution, which is over-saturated with respect to chlorite, allowing the formation of a chamosite-like mineral. The reaction mechanisms are confirmed by X-ray patterns and data obtained on the experimental solutions (pH, contents of Si, Mg, Na and Ca). Because of the availability of some nutrients in the solution, total dissolution of the starting smectite does not lead to 100 % crystallization of chlorite but to a mixture of two dominant clays: chamosite and interstratified chlorite/smectite and/or corrensite/smectite poor in smectite. The role of Fe/(Fe + Mg) in the experimental medium is highlighted by chemical data obtained on newly formed clay particles alongside previously published data. The newly formed iron-rich chlorite has the same composition as that predicted by the geothermometer for diagenetic to low-grade metamorphic conditions, and the quartz + Fe-chlorite + albite experimental assemblage in the 9-year experiment is close to that fixed by water–rock equilibrium.  相似文献   
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59.
In this paper, we present MHYDAS‐Erosion, a dynamic and distributed single‐storm water erosion model developed as a module of the existing hydrological MHYDAS model. As with many catchment erosion models, MHYDAS‐Erosion is able to simulate sediment transport, erosion and deposition by rill and interrill processes. Its originality stems from its capacity to integrate the impact of land management practices (LMP) as key elements controlling the sedimentological connectivity in agricultural catchments. To this end, the water‐sediment pathways are first determined by a specific process‐oriented procedure defined and controlled by the user, which makes the integration of LMP easier. The LMP dynamic behaviours are then integrated into the model as a time‐dependent function of hydrological variables and LMP characteristics. The first version of the model was implemented for vegetative filters and tested using water and sediment discharge measurements at three nested scales of a densely instrumented catchment (Roujan, OMERE Observatory, southern France). The results of discharge and soil loss for simulated rainfall events have been found to acceptably compare with available data. The average R2 values for water and sediment discharge are 0·82 and 0·83, respectively. The sensitivity of the model to changes in the proportion of LMP was assessed for a single rain event by considering three scenarios of the Roujan catchment management with vegetative filters: 0% (Scenario 1), 18% (Scenario 2, real case) and 100% (Scenario 3). Compared to Scenario 2 (real case), soil losses decreased for Scenario 3 by 65% on the agricultural plot scale, 62% on the sub‐catchment scale and 45% at the outlet of the catchment and increased for Scenario 1 by 0% on the plot scale, 26% on the sub‐catchment scale and 18% at the outlet of the catchment. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   
60.
The Kerguelen Archipelago is part of an oceanic plateau with a complex history. Little work has been done on the tectonics of the onshore areas, even though the extensive outcrop renders the islands especially good for structural work. We present the results of three field campaigns and remote sensing analysis carried out in the main Kerguelen Island, around Val Travers valley and Mt Ross volcano (Central Plateau) and in the Rallier du Baty peninsula (SW part of the archipelago). We have mapped faults, fracture sets, and the location and geometry of intrusive bodies. We found that the plateau basalt lavas that make up most of the area are densely fractured, crossed by many veins, dykes and some small faults. This work provides a general framework for the structure of Kerguelen Archipelago that is dominated by 110°-striking faults and veins, dyke swarms and an alignment of recent central volcanoes, which have formed in N-S to NNW-SSE directed extensional stress field. The other structures are fractures, veins and dykes which strike 130–150°, 000° and 030–050°. They are likely related to transform faults of the Indian oceanic crust and to faults of the north Kerguelen Plateau (offshore basement of the archipelago). These buried structures were likely re-activated by a low magnitude stress field.  相似文献   
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