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21.
We describe empirical results from a multi-disciplinary project that support modeling complex processes of land-use and land-cover change in exurban parts of Southeastern Michigan. Based on two different conceptual models, one describing the evolution of urban form as a consequence of residential preferences and the other describing land-cover changes in an exurban township as a consequence of residential preferences, local policies, and a diversity of development types, we describe a variety of empirical data collected to support the mechanisms that we encoded in computational agent-based models. We used multiple methods, including social surveys, remote sensing, and statistical analysis of spatial data, to collect data that could be used to validate the structure of our models, calibrate their specific parameters, and evaluate their output. The data were used to investigate this system in the context of several themes from complexity science, including have (a) macro-level patterns; (b) autonomous decision making entities (i.e., agents); (c) heterogeneity among those entities; (d) social and spatial interactions that operate across multiple scales and (e) nonlinear feedback mechanisms. The results point to the importance of collecting data on agents and their interactions when producing agent-based models, the general validity of our conceptual models, and some changes that we needed to make to these models following data analysis. The calibrated models have been and are being used to evaluate landscape dynamics and the effects of various policy interventions on urban land-cover patterns.  相似文献   
22.
Pressures of Crystallization of Icelandic Magmas   总被引:1,自引:0,他引:1  
Iceland lies astride the Mid-Atlantic Ridge and was createdby seafloor spreading that began about 55 Ma. The crust is anomalouslythick (20–40 km), indicating higher melt productivityin the underlying mantle compared with normal ridge segmentsas a result of the presence of a mantle plume or upwelling centeredbeneath the northwestern edge of the Vatnajökull ice sheet.Seismic and volcanic activity is concentrated in 50 km wideneovolcanic or rift zones, which mark the subaerial Mid-AtlanticRidge, and in three flank zones. Geodetic and geophysical studiesprovide evidence for magma chambers located over a range ofdepths (1·5–21 km) in the crust, with shallow magmachambers beneath some volcanic centers (Katla, Grimsvötn,Eyjafjallajökull), and both shallow and deep chambers beneathothers (e.g. Krafla and Askja). We have compiled analyses ofbasalt glass with geochemical characteristics indicating crystallizationof ol–plag–cpx from 28 volcanic centers in the Western,Northern and Eastern rift zones as well as from the SouthernFlank Zone. Pressures of crystallization were calculated forthese glasses, and confirm that Icelandic magmas crystallizeover a wide range of pressures (0·001 to 1 GPa), equivalentto depths of 0–35 km. This range partly reflects crystallizationof melts en route to the surface, probably in dikes and conduits,after they leave intracrustal chambers. We find no evidencefor a shallow chamber beneath Katla, which probably indicatesthat the shallow chamber identified in other studies containssilica-rich magma rather than basalt. There is reasonably goodcorrelation between the depths of deep chambers (> 17 km)and geophysical estimates of Moho depth, indicating that magmaponds at the crust–mantle boundary. Shallow chambers (<7·1 km) are located in the upper crust, and probablyform at a level of neutral buoyancy. There are also discretechambers at intermediate depths (11 km beneath the rift zones),and there is strong evidence for cooling and crystallizing magmabodies or pockets throughout the middle and lower crust thatmight resemble a crystal mush. The results suggest that themiddle and lower crust is relatively hot and porous. It is suggestedthat crustal accretion occurs over a range of depths similarto those in recent models for accretionary processes at mid-oceanridges. The presence of multiple stacked chambers and hot, porouscrust suggests that magma evolution is complex and involvespolybaric crystallization, magma mixing, and assimilation. KEY WORDS: Iceland rift zones; cotectic crystallization; pressure; depth; magma chamber; volcanic glass  相似文献   
23.
The crystallographic structures of the synthetic cheralite, CaTh(PO4)2, and its homolog CaNp(PO4)2 have been investigated by X-ray diffraction at room temperature. Rietveld analyses showed that both compounds crystallize in the monoclinic system and are isostructural to monazite LnPO4 (Ln = La to Gd). The space group is P21/n (I.T. = 14) with Z = 2. The refined lattice parameters of CaTh(PO4)2 are a = 6.7085(8) Å, b = 6.9160(6) Å, c = 6.4152(6) Å, and β = 103.71(1)° with best fit parameters R wp = 4.87%, R p = 3.69% and R B = 3.99%. For CaNp(PO4)2, we obtained a = 6.6509(5) Å, b = 6.8390(3) Å, c = 6.3537(8) Å, and β = 104.12(6)° and R wp = 6.74%, R p = 5.23%, and R B = 6.05%. The results indicate significant distortions of bond length and angles of the PO4 tetrahedra in CaTh(PO4)2 and to a lesser extent in CaNp(PO4)2. The structural distortions were confirmed by Raman spectroscopy of CaTh(PO4)2. A comparison with the isostructural compounds LnPO4 (Ln = Ce and Sm) confirmed that the substitution of the large rare earth trivalent cations with Ca2+ and Th4+ introduces a distortion of the PO4 tetrahedra.  相似文献   
24.
We test the hypothesis that flexural isostatic compensation of the mass removed by enhanced Quaternary erosion is responsible for uplift of the Western European Alps and their forelands. We use two well‐preserved and well‐dated (1.8 Ma) abandonment surfaces of foreland basin remnants in SE France (the Chambaran and Valensole plateaux) as passive benchmarks for tilting of the foreland. Estimating their initial slope from morphometric scaling relationships, we determine bulk post‐depositional tilting of 0.5–0.8% for these surfaces. The calculated isostatic response of the Alpine lithosphere to erosional unloading, using the method recently proposed by Champagnac et al. [Geology 35 (2007) 195–198] , yields a predicted tilting of 0.3–0.4% in the considered areas, explaining approximately half of the determined post‐depositional tilting. Such long‐term deformation being insensitive to cyclic loading/unloading because of glaciations, we suspect the other half to be related to as yet undetermined long‐wavelength and long‐lived tectonic process(es).  相似文献   
25.
A statistical model is developed to predict wave overtopping volume and rate of extreme waves on a fixed deck. The probability density function for the volume and rate of overtopping water are formulated based on the truncated Weibull distribution with the assumption of local sinusoidal profile for small amplitude waves. Sensitivity to the wave nonlinearity parameter and deck clearance is discussed. The statistical model is compared to laboratory data of the instantaneous free surface elevation measured in front of a fixed deck, and overtopping volume and overtopping rate measured at the leading edge of the deck. The statistical theory compared well with the measured exceedance probability seaward of the deck. The model prediction of the exceedance probability of deck overtopping gave qualitatively good agreement for large overtopping values.  相似文献   
26.
27.
A Lagrangian particle method embedded within a 2-D finite element code, is used to study the transport and ocean–estuary exchange processes in the well-mixed Great Bay Estuarine System in New Hampshire, USA. The 2-D finite element model, driven by residual, semi-diurnal and diurnal tidal constituents, includes the effects of wetting and drying of estuarine mud flats through the use of a porous medium transport module. The particle method includes tidal advection, plus a random walk model in the horizontal that simulates sub-grid scale turbulent transport processes. Our approach involves instantaneous, massive [O(500,000)] particle releases that enable the quantification of ocean–estuary and inter-bay exchanges in a Markovian framework. The effects of the release time, spring–neap cycle, riverine discharge and diffusion strength on the intra-estuary and estuary–ocean exchange are also investigated.The results show a rather dynamic interaction between the ocean and the estuary with a fraction of the exiting particles being caught up in the Gulf of Maine Coastal Current and swept away. Three somewhat different estimates of estuarine residence time are calculated to provide complementary views of estuary flushing. Maps of residence time versus release location uncover a strong spatial dependency of residence time within the estuary that has very important ramifications for local water quality. Simulations with and without the turbulent random walk show that the combined effect of advective shear and turbulent diffusion is very effective at spreading particles throughout the estuary relatively quickly, even at low (1 m2/s) diffusivity. The results presented here show that a first-order Markov Chain approach has applicability and a high potential for improving our understanding of the mixing processes in estuaries.  相似文献   
28.
29.
Geophysical data from 900 km of the Southwest Indian Ridge are used todescribe the pattern of evolution of the plate boundary between 61° Eand 70° E over the past 20 million years. The SWIR is anobliquely-opening, ultra slow-spreading axis, and east of61° E comprises a series of ridge sections, each about 100–120 kmin length. The orientation of these sections varies fromsub-orthogonal to oblique to the approximately N–S spreadingdirection. In general, the suborthogonal sections are shallower, commonlysubdivided into an array of discrete axial segments, and carry recognisablecentral magnetic anomalies. The majority of the oblique sections are single,continuous rifts without continuous axial magnetic signatures.Morphotectonics of the Southwest Indian Ridge crust have not previously beenwell constrained off-axis, and we here present sidescan sonar andswath bathymetric data up to 100 km from the ridge to demonstrate the complexities of its spatial and temporal evolution.A model is proposed that the segmentation style correlates with analong-axis variation between: (a) relatively thick crustal sections which overlie mantle sections with higher magmatic supply created in orthogonally-spreading segments and (b) those oblique sections associated with cooler, magmatically-starved mantle and thinner crust. These latter sections are formed at broad offset zones in theplate boundary, more precisely defined on faster-spreading ridges asnontransform discontinuities. The nonsystematic pattern of crustalconstruction, extensional basin formation and the absence of extension-parallel traces of discontinuities off-axis suggest that the oblique spreading sections are not fixed in space or time.  相似文献   
30.
Euglena gracilis makes two small Cd-binding proteins/peptides (Cd-BP I and Cd-BP II) in response to exposure to Cd2+. These proteins migrate slower than mammalian Cd-metallothionein (Cd-Mt) through Sephadex G-75, but like Cd-Mt also contain Zn and are separated into two species when chromatographed over a DEAE column. Both BPs are much less stable than Cd-Mt under acidic conditions. One source of this instability is that at least Cd-BP II contains acid-labile sulfide co-ordinated to the metals. It has been quantitated in Cd-BP II and shown to have a value of 1·25 ± 0·10 S2−/Cd. The reactivity of the Cd-binding sites in ligand substitution and thioldisulfide exchange reactions has been assessed. The reactions of Cd-BP I and II with pyridylazoresorcinol (PAR) were slow and displayed complex kinetic behavior. Similarly, both Cd-BPs react slowly and with complicated kinetics with 5,5′-dithiobis-(2-nitrobenzoate).  相似文献   
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