Experimental determination of the fluid-absent melting relations in the pelitic system   总被引：47，自引：0，他引：47  

Daniel Vielzeuf  John R. Holloway 《Contributions to Mineralogy and Petrology》1988,98(3):257-276

In order to provide additional constraints on models for partial melting of common metasediments, we have studied experimentally the melting of a natural metapelite under fluid-absent conditions. The starting composition contains quartz, plagioclase, biotite, muscovite, garnet, staurolite, and kyanite. Experiments were done in a halfinch piston-cylinder apparatus at 7, 10, and 12 kbar and at temperatures ranging from 750° to 1250° C. The following reactions account for the mineralogical changes observed at 10 kbar between 750° and 1250° C: Bi+Als+Pl+Q=L+Gt+(Kf), Ky=Sill, Gt+Als=Sp+Q, Gt=L+Sp+Q, and Sp+Q=L+Als.The compositions of the phases (at T>875° C) were determined using an energy-dispersive system on a scanning electron microscope. The relative proportions of melt and crystals were calculated by mass balance and by processing images from the SEM. These constraints, together with other available experimental data, are used to propose a series of P-T, T-XH₂O, and liquidus diagrams which represent a model for the fluid-present and fluid-absent melting of metapelites in the range 2–20 kbar and 600°–1250° C.We demonstrate that, even under fluid-absent conditions, a large proportion (40%) of S-type granitic liquid is produced within a narrow temperature range (850°–875° C), as a result of the reaction Bi+Als+Pl+Q=L+Gt(+/-Kf). Such liquids, or at least some proportion of them, are likely to segregate from the source, leaving behind a residue composed of quartz, garnet, sillimanite, plagioclase, representing a characteristic assemblage of aluminous granulites.The production of a large amount of melt at around 850° C also has the important effect of buffering the temperature of metamorphism. In a restitic, recycled, lower crust undergoing further metamorphism, temperature may reach values close to 1000° C due to the absence of this buffering effect. Partial melting is the main process leading to intracontinental differentiation. We discuss the crustal cross-section exposed in the North Pyrenean Zone in the context of our experiments and modelling.  相似文献   

High-Ca,low-alkali carbonatite volcanism at Fort Portal,Uganda     

Daniel S. Barker  Peter H. Nixon 《Contributions to Mineralogy and Petrology》1989,103(2):166-177

A Quaternary volcanic field at Fort Portal, SW Uganda, contains approximately 50 vents that erupted only carbonatite. The vents are marked by monogenetic tuff cones defining two ENE-trending belts. Lava from a fissure at the west end of the northern belt formed a flow 0.3 km² in area and 1–5 m thick. The lava is vesicular throughout with a scoriaceous top, and probably formed by agglutination of spatter from lava fountains. Phenocrysts are olivine, clinopyroxene, phlogopite, and titanomagnetite enclosing blebs of pyrrhotite. Rims of monticellite, gehlenite, and reinhardbraunsite surround olivine, clinopyroxene and phlogopite, and magnetite is rimmed by spinel. The reaction relations suggest that these phenocryst phases are actually xenocrysts, perhaps from a source similar to that which supplied phlogopite clinopyroxenite xenoliths in the Katwe-Kikorongo volcanic field 75 km SW of Fort Portal. The groundmass of fresh carbonatite lava consists of tabular calcite, spurrite, periclase, hydroxylapatite, perovskite, spinel, pyrrhotite, and barite. The lava was readily altered; where meteoric water had access, spurrite and periclase are lacking, and some calcite is recrystallized. Vesicles in lava and rare dike rocks are partly filled with calcite, followed by jennite and thaumasite. Pyroclastic deposits cover 142 km² and are far more voluminous than lava. Carbonatite ejecta were identical to lava in primary mineralogy, but are much more contaminated by crustal rock fragments and xenocrysts. At Fort Portal, eruption of a CaO-MgO-CO₂-SiO₂-P₂O₅-SO₂-H₂O-F liquid was unaccompanied by that of a more silica-rich or alkali-rich liquid. Alkali-rich carbonatite lavas and pyroclastic deposits have been documented elsewhere in East Africa, and calcite-rich volcanic carbonatites have been attributed to replacement of magmatic alkali carbonates by calcite. However, the alkali-poor volcanic carbonatites at Fort Portal were not formed by leaching of alkalis in meteoric water; tabular calcite is not pseudomorphous after alkali carbonates such as nyerereite. The Fort Portal magma was low in alkalis at the time of eruption.  相似文献   

The Coastal Ground-Water Boundary     

Daniel W. Urish  Melih M. Ozbilgin 《Ground water》1989,27(3):310-315

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Settling-velocity distributions and sorting processes on a longitudinal dune: A case study     

Daniel Hartmann  Christian Christiansen 《地球表面变化过程与地形》1988,13(7):649-656

The processes acting on a longitudinal dune are inferred from the response in the area size-sorting characteristics of the sediment of the active layer. The sediment size distributions are determined by settling and are best described by a log-hyperbolic model which provides the most information on size-sorting processes. Size-sorting characteristics are markedly different across the low round-crested part of the dune from cross-sections of the high more sharp-crested part. This results in changes in textural parameters along the lee-side consistent with changes in the lee-side separation vortex. This is the first time that the effect of wind speed up on the lee-side is observed to be reflected in the sediment; it can only be detected with the very sensitive log-hyperbolic parameters.  相似文献   

The Location of Office Space in the Metropolitan Service Economy of the United States, 1985–1990     

Daniel Z. Sui  James O. Wheeler 《The Professional geographer》1993,45(1):33-43

As the economic base of most American metropolitan areas relies increasingly on services, office industries have shifted to a more pivotal role in the new metropolitan service economy. Using primary office-space usage data of the time period 1985–1990, the changing spatial patterns of this new metropolitan service economy are investigated. It is found that the primary office activities are predominantly concentrated in a relatively small number of the largest metropolitan areas. However, an emerging spatial dispersion in primary office activities is also exhibited. Such dispersion is extremely strong at the upper end of the urban hierarchy. The Sunbelt-Snowbelt dichotomy fails to reveal any differences in the growth pattern of the new metropolitan service economy. A more diversified growth pattern of primary office activities is observed. Concentrated dispersion is the major spatial characteristic of this new metropolitan service economy.  相似文献   

Orlando '90 optical engineering and photonics in aerospace sensing: 16–20 April 1990, Orlando-USA     

Daniel St-Germain Courcelette 《ISPRS Journal of Photogrammetry and Remote Sensing》1990,45(5-6)

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The Little Ice Age : By Jean Grove. Methuen Publishers, London/New York, 498 pp     

Daniel H. Mann 《Quaternary Research》1990,34(3)

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Multilayer Sampling in the Water-Table Region of a Sandy Aquifer     

Edward Kaplan  Sujit Banerjee  Daniel Ronen  Mordeckai Magaritz  Albert Machlin  Michael Sosnow  Eric Koglin 《Ground water》1991,29(2):191-198

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High concentration of solutes at the upper part of the saturated zone (water table) of a deep aquifer under sewage-irrigated land     

Daniel Ronen  Mordeckai Magaritz 《Journal of Hydrology》1985,80(3-4):311-323

The water-table region (upper 50 cm of the saturated zone) of a 25 m deep phreatic sandstone aquifer, lying under fields irrigated with sewage effluents for up to 22 yrs, was monitored in 1971 and 1984. Average concentrations of NO⁻₃, Cl⁻ and SO²⁻₄ of up to 225, 307 and 155 mg l⁻¹, respectively, were detected in the upper 50 cm of the saturated region in two research wells in 1984. These concentrations, which are related to effluent and fertilizer input to groundwater, were two to four times higher than those found deep (37–55 m) below the water table in nearby (1000 m distant) production wells. Nitrate data and the estimated transit time through the unsaturated zone (2 m yr⁻¹) support the model suggesting that the major source of nitrate pollution in the past should be related to the oxidation of soil organic matter. The SO²⁻₄/Cl⁻ ratio is found to be a useful indicator for the arrival of SO²⁻₄-fertilizers at the groundwater interface. The observations presented in this paper question the suitability of plans for using effluents as a water source for agriculture in regions which are the replenishment areas of phreatic aquifers.  相似文献   

Extension of the specific interaction model to include gas solubilities in high temperature brines     

Leslie Barta  Daniel J. Bradley 《Geochimica et cosmochimica acta》1985,49(1):195-203

A semi-empirical model for gas solubilities in high temperature brines was developed by modification of the Pitzer interaction model (Pitzer, 1973) and evaluated by least-squares fitting to available P-T-X data for carbon dioxide, hydrogen sulfide, and methane in pure water and in aqueous sodium chloride solutions. Over the range of experimental data used (25°–350°C, NaCl concentration 0–6 m, P_CO2 1–150 atm. P_CH4 1–30 atm, P_CH4 1–1700 atm), standard deviations of fit in the natural logarithm of the Henry's law ratio were 0.096 for CO₂, 0.093 for H₂S and 0.116 for CH₄.The model has several advantages. First, it has a theoretical basis which can easily be extended for the inclusion of more than one salt or gas. Second, the equations simplify to the empirically derived equation of Setschenow, in the limit of infinite dilution. Finally, the model is easily integrated into a framework of equations which can yield all of the thermodynamic properties of the system.An example in which values of the model parameters for interaction of gas with salt may be used to estimate the effect of dissolved gas or salt solubility is given.  相似文献