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Emissions of biogenic volatile organic compounds (BVOC) were measured using a relaxed eddy accumulation (REA) technique on an above-canopy tower in a temperate forest (Changbai Mountain, Jilin province, China) during the 2010 and 2011 summer seasons. Solar global radiation and photosynthetically active radiation (PAR) were also measured. Based on PAR energy dynamic balance, an empirical BVOC emission and PAR transfer model was developed that includes the processes of BVOC emissions and PAR transfer above the canopy level, including PAR absorption and consumption, and scattering by gases, liquids, and particles (GLPs). Simulated emissions of isoprene and monoterpenes were in agreement with observations. The averages of the relative estimator biases for the flux were 39.3 % for isoprene, and 27.1 % for monoterpenes in the 2010 and 2011 growing seasons, with NMSE (normalized mean square error) values of 0.133 and 0.101, respectively. The observed and simulated mean diurnal variations of isoprene and monoterpenes in the 2010 and 2011 growing seasons were evaluated for the validation of the empirical model. Under observed atmospheric conditions, the sensitivity analysis showed that emissions of isoprene and monoterpenes were more sensitive to changes in PAR than to water vapor content or to the magnitude of the scattering factor. The emissions of isoprene and monoterpenes in the 2010 and 2011 growing seasons (from June to September) were estimated using this empirical model along with hourly observational data, with mean hourly emissions of 1.71 and 1.55 mg m?2 h?1 for isoprene, and 0.48 and 0.47 mg m?2 h?1 for monoterpenes in 2010 and 2011, respectively. As formaldehyde (HCHO) is considered as the main oxidation product of isoprene and monoterpenes, it is necessary to investigate the link between HCHO and BVOC emissions. GOME-2 HCHO vertical column densities (VCDs) can be used to estimate BVOC emission fluxes in the Changbai Mountain temperate forest. 相似文献
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Dana?L.?DrewEmail author Ilya?N.?Bindeman Matthew?W.?Loewen Paul?J.?Wallace 《Contributions to Mineralogy and Petrology》2016,171(1):10
During the onset of caldera cluster volcanism at a new location in the Snake River Plain (SRP), there is an increase in basalt fluxing into the crust and diverse silicic volcanic products are generated. The SRP contains abundant and compositionally diverse hot, dry, and often low-δ18O silicic volcanic rocks produced through time during the formation of individual caldera clusters, but more H2O-rich eruptive products are rare. We report analyses of quartz-hosted melt inclusions from pumice clasts from the upper and lower Arbon Valley Tuff (AVT) to gain insight into the initiation of caldera cluster volcanism. The AVT, a voluminous, caldera-forming rhyolite, represents the commencement of volcanism (10.44 Ma) at the Picabo volcanic field of the Yellowstone hotspot track. This is a normal δ18O rhyolite consisting of early and late erupted members (lower and upper AVT, respectively) with extremely radiogenic Sr isotopes and unradiogenic Nd isotopes, requiring that ~50 % of the mass of these elements is derived from melts of Archean upper crust. Our data reveal distinctive features of the early erupted lower AVT melt including: variable F concentrations up to 1.4 wt%, homogenous and low Cl concentrations (~0.08 wt%), H2O contents ranging from 2.3 to 6.4 wt%, CO2 contents ranging from 79 to 410 ppm, and enrichment of incompatible elements compared to the late erupted AVT, subsequent Picabo rhyolites, SRP rhyolites, and melt inclusions from other metaluminous rhyolites (e.g., Bishop Tuff, Mesa Falls Tuff). We couple melt inclusion data with Ti measurements and cathodoluminescence (CL) imaging of the host quartz phenocrysts to elucidate the petrogenetic evolution of the AVT rhyolitic magma. We observe complex and multistage CL zoning patterns, the most critical being multiple truncations indicative of several dissolution–reprecipitation episodes with bright CL cores (higher Ti) and occasional bright CL rims (higher Ti). We interpret the high H2O, F, F/Cl, and incompatible trace element concentrations in the context of a model involving melting of Archean crust and mixing of the crustal melt with basaltic differentiates, followed by multiple stages of fractional crystallization, remelting, and melt extraction. This multistage process, which we refer to as distillation, is further supported by the complex CL zoning patterns in quartz. We interpret new Δ18O(Qz-Mt) isotope measurements, demonstrating a 0.4 ‰ or ~180 °C temperature difference, and strong Sr isotopic and chemical differences between the upper and lower AVT to represent two separate eruptions. Similarities between the AVT and the first caldera-forming eruptions of other caldera clusters in the SRP (Yellowstone, Heise and Bruneau Jarbidge) suggest that the more evolved, lower-temperature, more H2O-rich rhyolites of the SRP are important in the initiation of a caldera cluster during the onset of plume impingement. 相似文献
187.
Introductory courses in Geographic Information Science (GIS) expose students to the concepts and practices necessary for future academic and professional use of GIS tools. Traditional GIS courses balance lectures in the theories of GIS with pre‐built and pre‐packaged lab activities to learn the practices of GIS. This article presents a case study of an experimental introductory course in which students conducted novel, independent project‐based group research under the supervision of graduate or advanced undergraduate students enrolled in the course, culminating in a class presentation and publication quality paper. Surveys and interviews indicated that students reacted more positively to project‐based group research than to traditional activities. Students felt the projects better prepared them for ‘real world’ applications of GIS, and recommend project‐based group research in other GIS coursework. Additionally, our findings indicate that students appreciate interactions with peers of varying skill levels and experiences, as these broaden their capabilities to work with other GIS users. 相似文献
188.
Ran Tao Daniel Strandow Michael Findley Jean‐Claude Thill James Walsh 《Transactions in GIS》2016,20(3):413-425
Territorial control is central to the understanding of violent armed conflicts, yet reliable and valid measures of this concept do not exist. We argue that geospatial analysis provides an important perspective to measure the concept. In particular, measuring territorial control can be seen as an application of calculating service areas around points of control. The modeling challenge is acute for areas with limited road infrastructure, where no complete network is available to perform the analysis, and movements largely occur off road. We present a new geospatial approach that applies network analysis on a hybrid transportation network with both actual road data and hexagon‐fishnet‐based artificial road data representing on‐road and off‐road movements, respectively. Movement speed or restriction can be readily adjusted using various input data. Simulating off‐road movement with hexagon‐fishnet‐based artificial road data has a number of advantages including scalability to small or large study areas and flexibility to allow all‐directional travel. We apply this method to measuring territorial control of armed groups in Sub‐Saharan Africa where inferior transport infrastructure is the norm. Based on the Uppsala Conflict Data Program's (UCDP) Georeferenced Event Data (GED) as well as spatial data on terrain, population locations, and limited transportation networks, we enhance the delineation of the specific areas directly controlled by each warring party during civil wars within a given travel time. 相似文献
189.
Recursive algorithm for fast GNSS orbit fitting 总被引:1,自引:0,他引:1
Gaussian elimination is an efficient and numerically stable algorithm for estimating parameters and their precision. However, before estimating the parameters, it is often prudent to perform statistical tests to achieve the best fitting model. We use Gaussian elimination to select the best fitting model among candidate models. A succinct relationship between the weighted sum of squared residuals and the previous one is revealed by a volume formula. For quick parameter estimation and determination of weighted sum of squared residuals, a recursive elimination algorithm is proposed in the context of Gaussian elimination. In order to improve the model selection efficiency, the parameter estimation and the determination of the weighted sum of squared residuals are carried out in parallel using the proposed recursive elimination algorithm in which the improvement at each recursive stage is judged by the Bayesian information criterion. Ultimately, the computational complexity and numerical stability of the recursive elimination proposed are briefly discussed, and a GNSS orbit interpolation example is used to verify the results. It shows that the proposed recursive elimination algorithm inherits the numerical stability of the Gaussian elimination, and this algorithm can be used to examine the gain from the newly introduced parameter, dynamically assess the fitting model, and fix the optimal model efficiently. The optimal fitting model with the lowest information is very close to the real situation verified by checkpoints. 相似文献
190.
Giovanni?Pugliano Umberto?RobustelliEmail authorView authors OrcID profile Fabio?Rossi Raffaele?Santamaria 《GPS Solutions》2016,20(3):499-508
Multipath remains one of the major challenges in Global Navigation Satellite System (GNSS) positioning because it is considered the dominant source of ranging errors, which can be classified into specular and diffuse types. We present a new method using wavelets to extract the pseudorange multipath in the time domain and breaking it down into the two components. The main idea is an analysis-reconstruction approach based on application of both continuous wavelet transform (CWT) and discrete wavelet transform (DWT). The proposed procedure involves the use of L1 code-minus-carrier (CMC) observable where higher-frequency terms are isolated as residuals. CMC residuals are analyzed by applying the CWT, and we propose the scalogram as a technique for discerning time–frequency variations of the multipath signal. Unlike Fourier transform, the potential of the CWT scalogram for examining the non-stationary and multifrequency nature of the multipath is confirmed as it simultaneously allows fine detection and time localization of the most representative frequencies of the signal. This interpretation of the CWT scalogram is relevant when choosing the levels of reconstruction with DWT, allowing accurate time domain extraction of both the specular and diffuse multipath. The performance and robustness of the method and its boundary applicability are assessed. The experiment was carried out using a receiver of Campania GNSS Network. The results are given in which specular multipath error is achieved using DWT level 7 approximation component and diffuse multipath error is achieved using DWT level 6 denoised detail component. 相似文献