The present study focuses on the nutrient sources and gradients in Paranaguá Bay (Southern Brazil), where nutrient inputs are related to losses from fertilizer loading in Paranaguá harbour and the discharge of untreated waste water. The input of dissolved inorganic nutrients to the bay from the harbour and city, as well as from river and atmospheric deposition, amounted to 642?t?year?1 DIN-N and 92?t?year?1 PO4-P. Harbour losses accounted for 6?% of total DIN-N and 39?% of total PO4-P loads to the bay, whereas sewage inputs from the city were responsible for 21?% and 22?%, respectively. River inputs made up 68?% of DIN-N, mainly in the form of nitrate, and 35?% of PO4-P loads, while atmospheric wet deposition was estimated to be in the order of 5?% of DIN-N and 4?% of PO4-P loads. Local maxima in nutrient levels deriving from highly concentrated sewage discharge were observed in front of the harbour and city of Paranaguá, but the plumes are diluted rapidly due to short residence times. DIN concentrations are negatively correlated with salinity, indicating the importance of freshwater input as a main factor controlling nitrogen distribution. Elevated phosphate levels in the stratified middle section of the bay may result both from harbour emissions and phosphate remobilization from sediments. Generally lower DIN and PO4 concentrations during the warmer rainy season are supposed to be due to intensified assimilation rates especially in the middle section of the bay where dense phytoplankton blooms are observed. The bay as a whole cannot be classified as being seriously eutrophic, albeit eutrophication symptoms prevail in some restricted locations in front of Paranaguá harbour. 相似文献
The present study focuses on the nutrient sources and gradients in Paranaguá Bay (Southern Brazil), where nutrient inputs are related to losses from fertilizer loading in Paranaguá harbour and the discharge of untreated waste water. The input of dissolved inorganic nutrients to the bay from the harbour and city, as well as from river and atmospheric deposition, amounted to 642 t year−1 DIN-N and 92 t year−1 PO4-P. Harbour losses accounted for 6 % of total DIN-N and 39 % of total PO4-P loads to the bay, whereas sewage inputs from the city were responsible for 21 % and 22 %, respectively. River inputs made up 68 % of DIN-N, mainly in the form of nitrate, and 35 % of PO4-P loads, while atmospheric wet deposition was estimated to be in the order of 5 % of DIN-N and 4 % of PO4-P loads. Local maxima in nutrient levels deriving from highly concentrated sewage discharge were observed in front of the harbour and city of Paranaguá, but the plumes are diluted rapidly due to short residence times. DIN concentrations are negatively correlated with salinity, indicating the importance of freshwater input as a main factor controlling nitrogen distribution. Elevated phosphate levels in the stratified middle section of the bay may result both from harbour emissions and phosphate remobilization from sediments. Generally lower DIN and PO4 concentrations during the warmer rainy season are supposed to be due to intensified assimilation rates especially in the middle section of the bay where dense phytoplankton blooms are observed. The bay as a whole cannot be classified as being seriously eutrophic, albeit eutrophication symptoms prevail in some restricted locations in front of Paranaguá harbour.
Biological markers of produced water (PW) exposure were studied in Atlantic cod (Gadus morhua) in both laboratory and field experiments, using authentic PW from a North Sea oil field. In the laboratory study, the PW exposure yielded significantly elevated levels of metabolites of polycyclic aromatic hydrocarbons (PAHs) and alkylphenols (APs) in bile even at the lowest exposure dose (0.125% PW). Other biomarkers (hepatic CYP1A induction and DNA adduct formation) responded at 0.25% and 0.5% PW concentrations. In the field study, bile metabolite markers and hepatic CYP1A were clearly increased in fish caged close to the PW outfall. Induction of plasma vitellogenin was not found in laboratory or field exposures, suggesting that the levels of oestrogen agonists (such as APs) might not have been sufficient to elicit induction, under the present conditions. The applicability of the biomarkers for use in water column biomonitoring programs is discussed. 相似文献
Volcanic ash produced during explosive eruptions can have very severe impacts on modern technological societies. Here, we use reconstructed patterns of fine ash dispersal recorded in terrestrial and marine geological archives to assess volcanic ash hazards. The ash-dispersal maps from nine Holocene explosive eruptions of Italian volcanoes have been used to construct frequency maps of distal ash deposition over a wide area, which encompasses central and southern Italy, the Adriatic and Tyrrhenian seas and the Balkans. The maps are presented as two cumulative-thickness isopach maps, one for nine eruptions from different volcanoes and one for six eruptions from Somma-Vesuvius. These maps represent the first use of distal ash layers to construct volcanic hazard maps, and the proposed methodology is easily applicable to other volcanic areas worldwide. 相似文献
The two-scalar covariance budget is significant within the canopy sublayer (CSL) given its role in modelling scalar flux budgets using higher-order closure principles and in estimating the segregation ratio for chemically reactive species. Despite its importance, an explicit expression describing how the two-scalar covariance is modified by inhomogeneity in the flow statistics and in the vertical variation in scalar emission or uptake rates within the canopy volume remains elusive even for passive scalars. To progress on a narrower version of this problem, an analytical solution to the two-scalar covariance budget in the CSL is proposed for the most idealized flow conditions: a stationary and planar homogeneous flow inside a uniform and dense canopy with a constant leaf area density distribution. The foliage emission (or uptake) source strengths are assumed to vary exponentially with depth while the forest floor emission is represented as a scalar flux. The analytical solution is a superposition of a homogeneous part that describes how the two-scalar covariance at the canopy top is transported and dissipated within the canopy volume, and an inhomogeneous part governed by local production mechanisms of the two-scalar covariance. The homogeneous part is primarily described by the canopy adjustment length scale, and the attenuation coefficients of the turbulent kinetic energy and the mean velocity. Conditions for which the vertical variation of the two-scalar covariance is controlled by the rapid attenuation in the mean velocity and turbulent kinetic energy profiles, vis-à-vis the vertical variation of the scalar source strength, are explicitly established. This model also demonstrates how dissimilarity in the emissions from the ground, even for the extreme binary case with one scalar turned ‘on’ and the other scalar turned ‘off’, modifies the vertical variation of the two-scalar covariance within the CSL. To assess its applicability to field conditions, the analytical model predictions were compared with observations made at two different forest types—a sparse pine forest at the Hyytiälä SMEAR II-station (in Finland) and a dense alpine hardwood forest at Lavarone (in Italy). While the model assumptions do not represent the precise canopy morphology, attenuation properties of the turbulent kinetic energy and the mean velocity, observed mixing length, and scalar source attenuation properties for these two forest types, good agreement was found between measured and modelled two scalar covariances for multiple scalars and for the triple moments at the Hyytiälä site. 相似文献
Anthropogenic sinkholes are generally due to the collapse of man-made underground caves and represent a major threat, especially in urban contexts, where they could cause damage to people, buildings and lifelines. The hinterland of Naples (Campania, Southern Italy) is one of the most urbanized areas of Italy and is historically affected by frequent sinkhole phenomena. This study analyzes a database of both man-made caves and sinkholes collected by the authors over several years. The aim is to comprehend the predisposing and triggering factors of sinkholes in order to attempt a zonation of occurrence. The predisposing factor resulted to be the presence of a preexisting network of caves within the Campanian Ignimbrite tuff and their geometric features. Generally, the shallower the depth of the chamber roof and the lower the thickness of the vault, the higher is the frequency of sinkholes. Furthermore, an intrinsic fragility is represented by the access shafts of vertical wells, usually filled in and abandoned. Meanwhile, the main triggering mechanism identified consists in saturation of the subsoil, due to water leaks coming from buried sewage and water pipelines. The macrozonation of sinkhole occurrence shows that the highest class is achieved where the tuff is shallow and both man-made caves and historical sinkholes are present.
The timing and dynamics of fluid-induced melting in the typical Barrovian sequence of the Central Alps has been investigated
using zircon chronology and trace element composition. Multiple zircon domains in leucosomes and country rocks yield U–Pb
ages spanning from ~32 to 22 Ma. The zircon formed during Alpine melting can be distinguished from the inherited and detrital
cores on the basis of their age, Th/U (<0.1) and trace element composition. Ti-in-zircon thermometry indicates crystallization
temperatures around 620–700°C. Their composition allows discriminating between (1) zircon formation in the presence of early
garnet, (2) zircon in equilibrium with abundant L-MREE-rich accessory phases (allanite, titanite and apatite) typical of metatonalites,
and (3) zircon formed during melting of metasediments in feldspar-dominated assemblages. The distribution of zircon overgrowths
and ages indicate that repeated melting events occurred within a single Barrovian metamorphic cycle at roughly constant temperature;
that in the country rocks zircon formation was limited to the initial stages of melting, whereas further melting concentrated
in the segregated leucosomes; that melting occurred at different times in samples a few meters apart because of the local
rock composition and localized influx of the fluids; and that leucosomes were repeatedly melted when fluids became available.
The geochronological data force a revision of the temperature–time path of the migmatite belt in the Central Alps. Protracted
melting over 10 My followed the fast exhumation of Alpine eclogites contained within the same region and preceded fast cooling
in the order of 100°C/Ma to upper crustal levels. 相似文献
Cr, Cu, Fe, K, Mg, Mn, N, Ni, Pb, S, V and Zn concentrations were determined during a whole seasonal cycle in leaves and in water and sediment roots of the aquatic macrophyte Phragmites australis (Cav.) Trin. ex Steudel from three sites in the Lake Averno (Naples, Italy), a volcanic lake contaminated by trace elements. At the beginning of the research, elemental analysis was also performed on lake sediments, that showed different trace-element concentrations depending on the sites. 相似文献
A high-resolution coastal ocean model is used to investigate salinity variability and water exchange in a complex coastal system off the southern U.S. characterized by three adjacent sounds that are interconnected by a network of channels, creeks, and intertidal areas. Model results are generally highly correlated with observations from the Georgia Coastal Ecosystem Long Term Ecological Research (GCE-LTER) program, revealing a high degree of salinity variability at the Altamaha River and Doboy Sound, decreasing sharply toward Sapelo Sound. A Lagrangian particle tracking method is used to investigate local residence time and connectivity in the system. Local residence time is highly variable, increasing with distance from the Altamaha River and decreasing with river flow, revealing that discharge plays a dominant role on transport processes and estuary-shelf exchange. The Altamaha River and Doboy Sound are connected to each other in all seasons, with exchange occurring both via coastal and estuarine pathways. While particles released at the Altamaha and Doboy rarely reach Sapelo Sound, particles released at Sapelo Sound and the creeks surrounding its main channel can reach the entire estuarine system. 相似文献
