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81.
82.
Jon D. Woodhead Russell S. Harmon Donald G. Fraser 《Earth and Planetary Science Letters》1987,83(1-4)
Quaternary lavas from the Northern Mariana Islands have respective O- and S-isotope ranges ofδ18O = +5.7 to +6.6 (‰ SMOW) andδ34S = +2.0to+20.7 (‰ CDT). Chemically evolved andesites and dacites with meanδ18O = +6.3 ± 0.2 are slightly enriched in18O with respect to unfractionated basalts of<53%SiO2 with meanδ18O = +6.0 ± 0.1. This18O enrichment can be explained in terms of differentiation of parental mafic magmas havingδ18O values between +5.7 to +6.2‰ through closed-system crystal fractionation because the lavas from all nine islands of the arc define a coherentδ18OSiO2 trend. The S-isotope composition of oxidized magmas is not modified extensively through the degassing of SO2; therefore, the meanδ34S value of ca. +11‰ for the Mariana lavas is considered to be representative of their source region.The enrichment of18O and34S in Mariana Arc parental magmas relative to ocean floor basalts withδ18O ca. + 5.7‰ andδ34S = ca.0.3‰ is attributed to the recycling of18O- and34S-rich crustal components (sediment withδ18O = ca. + 25‰ and seawater sulfate withδ34S = ca. +20‰ into the upper mantle source region for these arc magmas. This interpretation is consistent with enrichments of radiogenic Sr and Pb in the same lavas relative to ocean-floor basalts erupted either side of the arc, which are presumed to share a common upper mantle source. This enrichment is considered to reflect the mixing of two components, one having a typical upper mantle composition and the other having a more radiogenic character similar to that of western Pacific pelagic sediments. 相似文献
83.
84.
Krystyna W. Semkow Ronald A. Rizzo Larry A. Haskin David J. Lindstrom 《Geochimica et cosmochimica acta》1982,46(10):1879-1889
Cyclic voltammetry has been done for Ni2+, Co2+, and Zn2+ in melts of diopside composition in the temperature range 1425 to 1575°C. Voltammetric curves for all three ions excellently match theoretical curves for uncomplicated, reversible charge transfer at the Pt electrode. This implies that the neutral metal atoms remain dissolved in the melt. The reference electrode is a form of oxygen electrode. Relative to that reference assigned a reduction potential of 0.00 volt, the values of standard reduction potential for the ions are , , and . The electrode reactions are rapid, with first order rate constants of the order of 10?2 cm/sec. Diffusion coefficients were found to be 2.6 × 10?6 cm2/sec for Ni2+, 3.4 × 10?6 cm2/sec for Co2+, and 3.8 × 10?6 cm2/sec for Zn2+ at 1500°C. The value of (, diopside) is a linear function of temperature over the range studied, with values of ?0.35 V at 1425°C and ?0.29 V at 1575°C. At constant temperature the value of ) was not observed to vary with composition over the range CaO · MgO · 2SiO2 to CaO·MgO·3SiO2 or from 1.67 CaO·0.33MgO·2SiO2 to 0.5 CaO·1.5MgO·2SiO2. The value for the diffusion coefficient for Ni2+ decreased by an order of magnitude at 1525°C over the compositional range CaO · MgO · 1.25SiO2 to CaO · MgO · 3SiO2. This is consistent with a mechanism by which Ni2+ ions diffuse by moving from one octahedral coordination site to another in the melt, with the same Ni2+ species discharging at the cathode regardless of the SiO2 concentration in the melt. 相似文献
85.
Barry G. Oliver Earl M. Thurman Ronald L. Malcolm 《Geochimica et cosmochimica acta》1983,47(11):2031-2035
An operationally defined carboxyl content of humic substances extracted from rivers, streams, lakes, wetlands, and groundwaters throughout the United States and Canada is reported. Despite the diversity of the samples, only small variations were observed in this humic carboxyl content. The dissociation behavior of two combined fulvic/humic acid extracts was studied and it was found that the dissociation of the humics varied in a predictable manner with pH. Using a carboxyl content of 10 μeq/ mg humic organic carbon, and mass action quotient calculated from sample pH, the ionic balances of three highly colored Nova Scotia rivers were estimated. 相似文献
86.
The weathering of a late Tertiary volcanic ash near Jackson, Wyoming, was studied by sampling water percolating through the ash with suction lysimeters, and by examination of the associated solid phases. Soluble organic compounds derived from vegetation control the release and transport of solutes by complexing Al and Fe, and by causing low pH values. The concentrations of Na, K, Ca, and Mg, as well as those of Al and Fe correlate with the dissolved organic carbon concentrations (DOC) and follow an annual cycle with a maximum in spring. DOC concentrations averaged 5O mg C per liter, and values as high as 260 mg/l were observed. Al and Fe concentrations ranged as high as 5 mg/l. The dissolved organic matter was largely in the form of humic acids, although minor amounts of oxalate, acetate, and formate were also present. The pH of the percolating waters ranged from 4.3 to 6.5 with a mean of 5.2.During laboratory weathering experiments with the same ash in the absence of dissolved organic compounds, pH values ranged from 7.3 to 9.5, dissolved Al and Fe concentrations were below the detection limit, and there was little resemblance between the compositions of the solutions and the compositions observed in the field. Any model attempting to describe weathering in a comparable setting must incorporate biological mechanisms as the dominant controls. 相似文献
87.
Interpolated grids of coal bed thickness are being considered for use in a proposed method for taxation of coal in the state of West Virginia (United States). To assess the origin and magnitude of possible inaccuracies in calculated coal tonnage, we used conditional simulation to generate equiprobable realizations of net coal thickness for two coals on a 7
min topographic quadrangle, and a third coal in a second quadrangle. Coals differed in average thickness and proportion of original coal that had been removed by erosion; all three coals crop out in the study area. Coal tonnage was calculated for each realization and for each interpolated grid for actual and artificial property parcels, and differences were summarized as graphs of percent difference between tonnage calculated from the grid and average tonnage from simulations. Coal in individual parcels was considered minable for valuation purposes if average thickness in each parcel exceeded 30 inches. Results of this study show that over 75% of the parcels are classified correctly as minable or unminable based on interpolation grids of coal bed thickness. Although between 80 and 90% of the tonnages differ by less than 20% between interpolated values and simulated values, a nonlinear conditional bias might exist in estimation of coal tonnage from interpolated thickness, such that tonnage is underestimated where coal is thin, and overestimated where coal is thick. The largest percent differences occur for parcels that are small in area, although because of the small quantities of coal in question, bias is small on an absolute scale for these parcels. For a given parcel size, maximum apparent overestimation of coal tonnage occurs in parcels with an average coal bed thickness near the minable cutoff of 30 in. Conditional bias in tonnage for parcels having a coal thickness exceeding the cutoff by 10 in. or more is constant for two of the three coals studied, and increases slightly with average thickness for the third coal. 相似文献
88.
W. David Rust Donald R. MacGorman Eric C. Bruning Stephanie A. Weiss Paul R. Krehbiel Ronald J. Thomas William Rison Timothy Hamlin Jeremiah Harlin 《Atmospheric Research》2005,76(1-4):247
Balloon-borne electric field soundings and lightning mapping data have been analyzed for three of the storms that occurred in the Severe Thunderstorm Electrification and Precipitation Study field program in 2000 to determine if the storms had inverted-polarity electrical structures. The polarities of all or some of the vertically stacked charge regions in such storms are opposite to the polarities observed at comparable heights in normal storms. Analyses compared the charge structures inferred from electric field soundings in the storms with charges inferred from three-dimensional lightning mapping data. Charge structures were inferred from electric field profiles by combining the one-dimensional approximation of Gauss's law with additional information from three-dimensional patterns in the electric field vectors. The three different ways of inferring the charge structure in the storms were found to complement each other and to be consistent overall. Charge deposition by lightning possibly occurred and increased the charge complexity of one of the storms.Many of the cloud flashes in each case were inverted-polarity flashes. Two storms produced ground flash activity comprised predominantly of positive ground flashes. One storm, which was an isolated thunderstorm, produced inverted-polarity cloud flashes, but no flashes to ground. The positive and negative thunderstorm charge regions were found at altitudes where, respectively, negative and positive charge would be found in normal-polarity storms. Thus, we conclude that these storms had anomalous and inverted-polarity electrical structures. Collectively, these three cases (along with the limited cases in the refereed literature) provide additional evidence that thunderstorms can have inverted-polarity electrical structures. 相似文献
89.
Geopositioning Accuracy of Ikonos Imagery: Indications from Two Dimensional Transformations 总被引:1,自引:0,他引:1
Earth observation satellites with 1m resolution, such as Space Imaging's Ikonos system, offer the photogrammetric and remote sensing communities a significant new means for geospatial information collection. These satellites possess the potential for pixel-level geopositioning precision and promise timely, highly automated generation of two dimensional (2D) and three dimensional (3D) spatial information products. This paper concentrates on the pursuit of optimal accuracy and considers an essential first step in the evaluation of the Ikonos imaging system, namely the metric integrity of the sensor system. In the absence of sensor calibration information (the camera model), an empirical evaluation approach has been adopted. This involves an assessment of 2D transformations between image and planar object space. It is shown that based on results obtained in the Melbourne Ikonos Testfield, 2D geopositioning to 0.5 m accuracy is possible from the base-level "Geo"product when a modest amount of good quality ground control is available and sub-pixel image mensuration is achieved. These findings are applicable to both near-nadir imagery and oblique stereo images. Moreover, the results obtained suggest that there are no significant geometric perturbations in the sensor system and initial image processing, which augurs well for the successful application of non-collinearity based 3D orientation and triangulation models for Ikonos imagery. 相似文献
90.
Use of GPS tracking data from different dual-frequency receiver types (cross-correlating vs. codeless) has revealed satellite-dependent
biases in pseudorange observables P1 (Y-code) and C1 (C/A, Clear Acquisition code). These biases can have a direct effect
on clock estimates, carrier phase bias fixing, and other parameters estimated in GPS data processing. A set of satellite-specific
compensatory pseudorange offsets is calculated, and each is applied to a wee of daily global network analyses in which satlellite,
receiver, atmospheric, and Earth rotation parameters are estimated. Results from these analyses are then compared to those
from corresponding baseline cases in which no biases were applied. There is also some evidence that suggests that the pseudorange
biases differ even among codeless receiver models. Hence, a second set of offsets is computed on a different basis, and compared
with the baseline model in a similar manner. A preliminary examination of C1-P1 variations over time is presented. Finally,
recommendations are made for the use of the calculated offsets, and consideration is given to a future dissemination of updates
to these values as necessary. ? 2001 John Wiley & Sons, Inc. 相似文献