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81.
Pore-water dissolved organic carbon (PWDOC) concentrations were examined in vegetated and bare sediments of aHalodule wrightii seagrass bed, and in a mud bottom sediment of a southern Texas estuary. Temporal variability was examined at diel (dawn and noon) and bimonthly time scales. Distribution patterns of PWDOC were compared with physical, chemical, and biological factors thought to exert control on PWDOC. Concentration of PWDOC, bacterial production, and resultant PWDOC turnover times displayed statistically significant spatial and temporal variability. Concentration of PWDOC ranged from 14 mg C 1?1 to 107 mg C 1?1 of pore water, or 9–71 μg C cm?3 wet sediment. PWDOC was more variable and was approximately 5 times higher than DOC concentrations in the water column. Low PWDOC concentrations (mean = 14.6 μg C cm?3) and high bacterial production rates (mean = 1.92 μg C cm?3 h?1) were observed at the mud station, whereas PWDOC concentrations were high (mean = 24.6 μg C cm?3) and bacterial production rates were low (mean = 0.43 μg C cm?3 h?1) at the bare station. PWDOC turnover times (Tt), assuming 50% bacterial growth efficiency (1–840 h) were shortest at the mud station (mean=13 h) and longest at the bare station (mean=180 h). In the overlying water column, Tt values were longer, ranging from 1,000–10,000 h. PWDOC concentrations were 25% higher in vegetated sediments than in neighboring bare sediments. This difference was probably due to inputs of labile photosynthetic excretia, since bacterial production rates in vegetated sediments displayed significant diel variability and were 4 times greater than that of bare sediments. Based upon the entire data set, PWDOC was significantly related to macrofaunal biomass, sediment POC, sediment C:N ratios, and oxygen metabolism, but was significantly correlated only to the latter two variables in stepwise multiple regression. Our findings suggest that organism activities and detrital quality are the major determinants controlling variability in PWDOC. 相似文献
82.
Ronald Christensen 《Mathematical Geology》1990,22(6):655-664
A proof is provided that the predictions obtained from kriging based on intrinsic random functions of orderk are identical to those obtained from anappropriate universal kriging model. This is a theoretical result based on known variability measures. It does not imply that people performing traditional universal kriging will get the same predictions as those using intrinsic random functions, because traditionally these methods differ in how variability is modeled. For intrinsic random functions, the same proof shows that predictions do not depend on the specific choice of the generalized covariance function. It is argued that the choice between these methods is really one of modeling and estimating the variability in the data. 相似文献
83.
Fraser Goff Sue J. Goff Sharad Kelkar Lisa Shevenell Alfred H. Truesdell John Musgrave Heinz Rüfenacht Wilmer Flores 《Journal of Volcanology and Geothermal Research》1991,45(1-2)
Results of drilling, logging, and testing of three exploration core holes, combined with results of geologic and hydrogeochemical investigations, have been used to present a reservoir model of the Platanares geothermal system, Honduras. Geothermal fluids circulate at depths ≥ 1.5 km in a region of active tectonism devoid of Quaternary volcanism. Large, artesian water entries of 160 to 165°C geothermal fluid in two core holes at 625 to 644 m and 460 to 635 m depth have maximum flow rates of roughly 355 and 560 l/min, respectively, which are equivalent to power outputs of about 3.1 and 5.1 MW(thermal). Dilute, alkali-chloride reservoir fluids (TDS ≤ 1200 mg/kg) are produced from fractured Miocene andesite and Cretaceous to Eocene redbeds that are hydrothermally altered. Fracture permeabillity in producing horizons is locally greater than 1500 and bulk porosity is ≤ 6%. A simple, fracture-dominated, volume-impedance model assuming turbulent flow indicates that the calculated reservoir storage capacity of each flowing hole is approximately 9.7 × 106 l/(kg cm−2), Tritium data indicate a mean residence time of 450 yr for water in the reservoir. Multiplying the natural fluid discharge rate by the mean residence time gives an estimated water volume of the Platanares system of ≥ 0.78 km3. Downward continuation of a 139°C/km “conductive” gradient at a depth of 400 m in a third core hole implies that the depth to a 225°C source reservoir (predicted from chemical geothermometers) is at least 1.5 km. Uranium-thorium disequilibrium ages on calcite veins at the surface and in the core holes indicate that the present Platanares hydrothermal system has been active for the last 0.25 m.y. 相似文献
84.
85.
Preferential leakage of H2O from fluid inclusions containing multiple gas components has been suspected in natural metamorphic rocks and has been demonstrated experimentally for synthetic H2O-CO2-rich inclusions in natural quartz. Knowledge of the physical and chemical characteristics of the leakage mechanism, which may be very complex, increases the value of natural fluid inclusions to metamorphic geology. It is proposed that crystal defects play a major role in nondecrepitative preferential H2O leakage through quartz, and remain effective during metamorphism. Inclusions with either an internal overpressure or underpressure produce strain in the adjacent quartz crystal via the nucleation of many dislocations and planar defects (like Dauphiné twin boundaries). These defects allow preferential loss of H2O from H2O-CO2-rich inclusions at supercritical conditions. The transport capacity of this leakage mechanism is enhanced by nucleation of small bubbles on defect structures. The nucleation of these bubbles seems to be a recovery process in strained crystals. Solubility gradients of quartz in water in a crystal with internally underpressurized inclusions may result in optical visible implosion halos in a three dimensional spatial arrangement, caused by the growth of small bubbles at the expense of the larger original fluid inclusion. Natural fluid inclusions from Naxos (Greece) are always associated with numerous interlinked dislocations. These dislocations may have been produced by plastic derormation or by crystal growth related processes (e.g. crack healing). The presence of small bubbles on these dislocations indicates that a similar leakage mechanism for H2O must have occurred in these rocks. 相似文献
86.
P. J. Fraser M. A. K. Khalil R. A. Rasmussen L. P. Steele 《Journal of Atmospheric Chemistry》1984,1(2):125-135
Results of more than 800 new measurements of methane (CH4) concentrations in the Southern Hemisphere troposphere (34–41° S, 130–150° E) are reported. These were obtained between September 1980 and March 1983 from the surface at Cape Grim, Tasmania, through the middle (3.5–5.5 km) to the upper troposphere (7–10 km). The concentration of CH4 increased throughout the entire troposphere over the measurement period, adding further support to the view that CH4 concentrations are currently increasing on a global scale. For data averaged vertically through the troposphere the rate of increase found was 20 ppbv/yr or 1.3%/yr at December 1981. In the surface CH4 data a seasonal cycle with a peak to peak amplitude of approximately 28 ppbv is seen, with the minimum concentration occurring in March and the maximum in September–October. A cycle with the same phase as that seen at the surface, but with a significantly decreased amplitude, is apparent in the mid troposphere but no cycle is detected in the upper tropospheric data. The phase and amplitude of the cycle are qualitatively in agreement with the concept that the major sink for methane is oxidation by hydroxyl radicals. Also presented is evidence of a positive vertical gradient in methane, with a suggestion that the magnitude of this gradient has changed over the period of measurements. 相似文献
87.
After discussing the changing nature of perceived risk problems, the status of risk assessment is described in relation to its origins and in particular to its roots in the environmental impact statement process. The nature of risk, its component elements and the manner in which existing concepts of risk have been reflected in risk assessment methods are described. The paper considers two emerging schools of thought in current risk assessment studies: one that calls for more accurate measures of risk and increasingly comprehensive event prediction models to determine risk acceptability and another which argues that the acceptance of risk is less dependent on the accuracy of risk analyses than it is on the nature of the decision-making process and in particular on whether compensation is provided for those bearing a disproportionate share of risk. 相似文献
88.
The global distribution of methane in the troposphere 总被引:6,自引:0,他引:6
L. P. Steele P. J. Fraser R. A. Rasmussen M. A. K. Khalil T. J. Conway A. J. Crawford R. H. Gammon K. A. Masarie K. W. Thoning 《Journal of Atmospheric Chemistry》1987,5(2):125-171
Methane has been measured in air samples collected at approximately weekly intervals at 23 globally distributed sites in the NOAA/GMCC cooperative flask sampling network. Sites range in latitude from 90° S to 76° N, and at most of these we report 2 years of data beginning in early 1983. All measurements have been made by gas chromatography with a flame ionization detector at the NOAA/GMCC laboratory in Boulder, Colorado. All air samples have been referenced to a single secondary standard of methane-in-air, ensuring a high degree of internal consistency in the data. The precision of measurements is estimated from replicate determinations on each sample as 0.2%. The latitudinal distribution of methane and the seasonal variation of this distribution in the marine boundary layer has been defined in great detail, including a remarkable uniformity in background levels of methane in the Southern Hemisphere. We report for the first time the observation of a complete seasonal cycle of methane at the South Pole. A significant vertical gradient is observed between a sea level and a high altitude site in Hawaii. Globally averaged background concentrations in the marine boundary layer have been calculated for the 2 year-period May 1983–April 1985 inclusive, from which we find an average increase of 12.8 ppb per year, or 0.78% per year when referenced to the globally averaged concentration (1625 ppb) at the mid-point of this period. We present evidence that there has been a slowing down in the methane growth rate.Presented at the Conference on the Scientific Application of Baseline Observations of Atmospheric Composition (SABOAC), Aspendale, Australia, 7–9 November 1984. 相似文献
89.
P. J. Fraser R. A. Rasmussen J. W. Creffield J. R. French M. A. K. Khalil 《Journal of Atmospheric Chemistry》1986,4(3):295-310
New CH4 emission data from a number of Northern and Southern Hemispheric, tropical and temperate termites, are reported, which indicate that the annual global CH4 source due to termites is probably less than 15 Tg. The major uncertainties in this estimate are identified and found to be substantial. Nevertheless, our results suggest that termites probably account for less than 5% of global CH4 emissions. 相似文献
90.
Over the past decade, photogrammetry has been increasingly applied as a precise three dimensional measuring tool in industrial and engineering works. Analytical photogrammetry is now routinely employed in tasks of measurement as diverse as machine tool inspection and fixture checking, structural deformation monitoring, the provision of control databases to guide industrial robots and the measurement of structures in earth orbit. Traditional photogrammetric techniques and instrumentation are usually inappropriate for industrial work and the development of complete, fully integrated close range photogrammetric systems has recently gained considerable impetus. This paper details some of the significant new developments in industrial photogrammetry, with particular reference to technological advances in the Simultaneous Triangulation and Resection System (STARS) designed by Geodetic Services, Inc. for industrial photograininetry. Practical aspects of industrial measurement are also presented in a review of some of the varying tasks that GSI has carried out in recent years. Emphasis is placed on demonstrating the flexibility, accuracy, reliability and economy of photogrammetry, as well as the progress made in automating this measurement technique. 相似文献