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The cone penetration test (CPT) is widely used, and although initially developed as a stratigraphic logging tool its excellent repeatability and accuracy offers a benchmark quantitative test for sand in particular. A continuing difficulty, however, is that the CPT does not measure any soil property directly, so that parameters of interest must be recovered from solution of an inverse boundary value problem, which is difficult. To date most CPT interpretations in sand have been based on very limited calibration testing carried out in large chambers on a few sands from which mappings are developed. But there are differences in the CPT response from one sand to another leaving the interpretation imprecise (and arguably even speculative) because these differences remain poorly understood. In this paper we use the familiar spherical cavity expansion analogy to the CPT including large strains and a good, critical-state-based, soil model to develop a pattern of behaviour which we then compare to some of the reference chamber test data. We find that one of the issues of dispute in the empirical interpretation methods, the so-called stress-level effect, is caused by neglect of elasticity and that there are several additional parameters of first-order significance to cavity expansion in sands. More generally, we show that the difference in CPT response between various chamber sands in predicted. Our results are cast in dimensionless form and the inversion illustrates that extreme care is required in interpreting CPT data if the in situ sand state is to be determined with precision approaching that suggested as achievable by the repeatability of the CPT data itself. Aspects requiring particular care in interpreting CPT data in sand are discussed. © 1998 John Wiley & Sons, Ltd.  相似文献   
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The northern Gulf of Mexico and its diverse natural resources are threatened by population and development pressure, and by the impacts of rising sea level and severe storms. In the wake of the devastating 2005 hurricane season, and in response to the complex management issues facing the region, the U.S. Geological Survey organized the multidisciplinary “Northern Gulf of Mexico Ecosystem Change and Hazards Susceptibility” project. This special issue of Geo-Marine Letters hosts a few of the early results in the form of 11 papers covering three themes: (1) the control exerted by the underlying geologic framework on geomorphology and nearshore processes and features; (2) impact of human activities on nearshore water quality; and (3) hurricanes and associated effects.  相似文献   
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During several decades of investigation, the East Pacific Rise seafloor-spreading center at 9°-10°N has been explored by marine geologists, geophysicists, chemists, and biologists, and has emerged as one of the best studied sections of the global midocean ridge. It is an example of a region for which there is now a great wealth of observational data, results, and data-driven theoretical studies. However, these have yet to be fully utilized, either by research scientists or educators. While the situation is improving, a large amount of data, results, and related theoretical models still exist either in an inert, noninteractive form (e.g., journal publications) or as unlinked and currently incompatible computer data or algorithms. Presented here is the prototype of a computational environment and toolset, called the Virtual Research Vessel, to improve the situation by providing marine scientists and educators with simultaneous access to data, maps, and numerical models. While infrastructure is desired and needed for ready access to data and the resulting maps via web GIS in order to link disparate data sets (data to data), it is argued that data must also be linked to models for better exploration of new relations between observables, refinement of numerical simulations, and the quantitative evaluation of scientific hypotheses. For widespread data access, web GIS is therefore only a preliminary step rather than a final solution, and the ongoing implementation of the Virtual Research Vessel (scheduled for final completion in 2004-2005) is a case study for the midocean ridge community to test the effectiveness of moving beyond the data-to-data mode towards data-to-models and data-to-interpretation.  相似文献   
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A broad community intercalibration exercise for accurate measurement of dissolved organic carbon (DOC) in seawater has been carried out over a period of 5 years. A set of 10 natural samples with DOC content from 40 to 200 μM C were accompanied by two glucose standards and a “zero C” blank; all sealed in glass ampoules. Samples were sent to all interested analysts for “blind” analysis; 62 laboratories in 17 countries participated. A total of 59 separate analyses were determined to be acceptable by screening criteria based on standards and blank; another nine sets of analyses did not pass the screening. The majority of the analyses, both those passing and those that did not, were performed with high temperature combustion (HTC) methods, six sets of analyses were done using wet chemical oxidation methods.From the 53 sets of acceptable HTC analyses, the coefficient of variation (%CV) for analytical comparability of the samples was 10% (“community precision”). It is estimated that the individual replicate injection precision for most instruments was approximately 2% and that no additional variability was caused by differences within the ampoules of individual samples. The additional variability over 2% was likely a result of both random and systematic differences in analytical capabilities from instrument to instrument and from day to day for individual instruments. With an arbitrary selection after the fact, smaller subsets of analysts can show comparability better than 10% and duplicate or triplicate runs on different days of the full sets of samples in several laboratories showed comparability in the 2–6.5% range. Experienced oceanic analysts, with internal or shared reference materials, can now show reproducibility and comparability at a level closer to 2%.Preliminary use of DOC reference materials by 14 participants showed day-to-day reproducibilities for their laboratories in the 2–6% range in most cases; several with poorer reproducibility do not normally perform DOC analyses on samples with concentrations as low as the deep ocean reference used here. Use of these reference materials can also give a demonstration of comparability between laboratories. For credibility of DOC analyses, it is necessary for analysts to use community reference materials and report results of their analytical performance with these references.This paper does not identify individual data nor should it be considered an evaluation of individual laboratories or analysts. The purpose is to show the summary picture of the international community of DOC analysts as it existed in the mid- to late 1990s.  相似文献   
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The precipitation of calcite and aragonite as encrustations directly on the seafloor was an important platform‐building process during deposition of the 2560–2520 Ma Campbellrand‐Malmani carbonate platform, South Africa. Aragonite fans and fibrous coatings are common in unrestricted, shallow subtidal to intertidal facies. They are also present in restricted facies, but are absent from deep subtidal facies. Decimetre‐thick fibrous calcite encrustations are present to abundant in all depositional environments except the deepest slope and basinal facies. The proportion of the rock composed of carbonate that precipitated as encrustations or in primary voids ranges from 0% to > 65% depending on the facies. Subtidal facies commonly contain 20–35%in situ precipitated carbonate, demonstrating that Neoarchaean sea water was supersaturated with respect to aragonite, carbonate crystal growth rates were rapid compared with sediment influx rates, and the dynamics of carbonate precipitation were different from those in younger carbonate platforms. The abundance of aragonite pseudomorphs suggests that sea‐water pH was neutral to alkaline, whereas the paucity of micrite suggests the presence of inhibitors to calcite and aragonite nucleation in the mixed zone of the oceans.  相似文献   
80.
Assessing long-term performance of Category 3 cement wasteforms and accurate prediction for radionuclide encasement requires knowledge of the radionuclide–cement interactions and mechanisms of retention (i.e. sorption or precipitation). A set of sediment-concrete half-cell diffusion experiments was conducted under unsaturated conditions (4% and 7% by weight moisture content) using carbonated and non-carbonated concrete–soil half cells. Results indicate the behavior of Re and I release was comparable within a given half-cell test. Diffusivity in soil is a function of moisture content; a 3% increase in moisture content affords a one to two order of magnitude increase in diffusivity. Release of I and Re was 1–3 orders of magnitude less from non-carbonated, relative to carbonated, concrete monoliths. Inclusion of Fe in non-carbonate monoliths resulted in the lowest concrete diffusivity values for both I and Re. This suggests that in the presence of Fe, I and Re are converted to reduced species, which are less soluble and better retained within the concrete monolith. The release of I and Re was greatest from Fe-bearing, carbonated concrete monoliths, suggesting carbonation negates the effect of Fe on the retention of I and Re within concrete monoliths. This is likely due to enhanced formation of microcracks in the presence of Fe, which provide preferential paths for contaminant migration. Although the release of I and Re were greatest from carbonated concrete monoliths containing Fe, the migration of I and Re within a given half cell is dependent on the moisture content, soil diffusivity, and diffusing species.  相似文献   
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