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141.
A pilot study of spatial patterns of agricultural drought hazard in the south-central Pacific is presented. The durations of crop stress periods are estimated using a water balance approach. A rainfall approach is used to identify dry periods corresponding to different durations. Strong correlation between the results of the two methods indicates that monthly rainfall data are sufficient for estimating the patterns of agricultural drought hazard in the region. The simpler rainfall method is particularly useful for high islands where data required for the water balance approach are not sufficient to characterize the complex climatic patterns. Drought hazard is greatest in the eastern and southwestern parts of the study area. Great spatial variation in drought hazard is observed in a small area on the high islands of Western Samoa, where the range of values found within a few tens of kilometers is about the same as the range found across thousands of kilometers for low islands.  相似文献   
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143.
The higher-order scalar concentration fluctuation properties are examined in the context of Monin–Obukhov similarity theory for a variety of greenhouse gases that have distinct and separate source/sink locations along an otherwise ideal micrometeorological field site. Air temperature and concentrations of water vapour, carbon dioxide and methane were measured at high frequency (10 Hz) above a flat and extensive peat-land soil in the San Joaquin–Sacramento Delta (California, USA) area, subjected to year-round grazing by beef cattle. Because of the heterogeneous distribution of the sources and sinks of CO2 and especially CH4 emitted by cattle, the scaling behaviour of the higher-order statistical properties diverged from predictions based on a balance between their production and dissipation rate terms, which can obtained for temperature and H2O during stationary conditions. We identify and label these departures as ‘exogenous’ because they depend on heterogeneities and non-stationarities induced by boundary conditions on the flow. Spectral analysis revealed that the exogenous effects show their signatures in regions with frequencies lower than those associated with scalar vertical transport by turbulence, though the two regions may partially overlap in some cases. Cospectra of vertical fluxes appear less influenced by these exogenous effects because of the modulating role of the vertical velocity at low frequencies. Finally, under certain conditions, the presence of such exogenous factors in higher-order scalar fluctuation statistics may be ‘fingerprinted’ by a large storage term in the mean scalar budget.  相似文献   
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145.
Three violent eighteenth-century storms that ravaged the North Sea area (1703), western central Europe (1739) and Portugal (1739) are investigated from the point of view of their meteorological setting, their socio-economic impact, and whether and by what means they secured an enduring place in the cultural memory. The evidence draws on individual narrative sources such as chronicles and poems, and institutional sources such as ship’s logbooks and state-organised ‘windthrow’ inventories of tree loss. Each of the three storms had socio-economic impacts that could be described as ‘war-like’ in the damage caused to buildings and the destruction of forests. The “Great Storm” of December 1703 jeopardized English naval supremacy in the War of the Spanish Succession by sinking a number of Royal Navy ships and taking the life of more than 8000 seamen. In January 1739 two similarly destructive storms swept over mainland Europe. The cultural memory of the three events here considered was however strikingly different. The sequence of storms in January 1739 though being the most protracted of the last centuries, and well-chroniceled, did not persist in the collective memories of those in France, Switzerland and elsewhere who experienced them. Likewise, the “Great Storm” was quickly forgotten on the continent, whereas its memory remained deeply rooted in England through the writings of Defoe (1704). In Portugal the 1739 storm won a lasting place in the country’s cultural memory owing to two poems that it inspired. Furthermore, it was recorded in the Kingdom’s official newspaper, in the astronomical prognoses and in written records of the Old Regime’s cultural elite.  相似文献   
146.
We assess the potential impacts of climate change on the hydrology and water resources of the Nile River basin using a macroscale hydrology model. Model inputs are bias corrected and spatially downscaled 21st Century simulations from 11 General Circulation Models (GCMs) and two global emissions scenarios (A2 and B1) archived from the 2007 IPCC Fourth Assessment Report (AR4). While all GCMs agree with respect to the direction of 21st Century temperature changes, there is considerable variability in the magnitude, direction, and seasonality of projected precipitation changes. Our simulations show that, averaged over all 11 GCMs, the Nile River is expected to experience increase in streamflow early in the study period (2010–2039), due to generally increased precipitation. Streamflow is expected to decline during mid- (2040–2069) and late (2070–2099) century as a result of both precipitation declines and increased evaporative demand. The predicted multimodel average streamflow at High Aswan Dam (HAD) as a percentage of historical (1950–1999) annual average are 111 (114), 92 (93) and 84 (87) for A2 (B1) global emissions scenarios. Implications of these streamflow changes on the water resources of the Nile River basin were analyzed by quantifying the annual hydropower production and irrigation water release at HAD. The long-term HAD release for irrigation increases early in the century to 106 (109)% of historical, and then decreases to 87 (89) and 86 (84)% of historical in Periods II and III, respectively, for the A2 (B1) global emissions scenarios. Egypt’s hydropower production from HAD will be above the mean annual average historical value of about 10,000 GWH for the early part of 21st century, and thereafter will generally follow the streamflow trend, however with large variability among GCMs. Agricultural water supplies will be negatively impacted, especially in the second half of the century.  相似文献   
147.
In many river basins, floodplain soils have accumulated a variety of metal contaminants, which might be released during periods of flooding. We investigated the dynamics of copper, cadmium, lead, zinc, and nickel in a contaminated freshwater floodplain soil under a realistic sulfate-limited flooding regime in microcosm experiments. We found that most contaminants were initially mobilized by processes driven by the reductive dissolution of Fe(III) and Mn(IV, III) (hydr)oxides. Subsequently, bacterial sulfate respiration resulted in the transformation of the entire available sulfate (2.3 mmol/kg) into chromous reducible sulfur (CRS). Cu K-edge X-ray absorption fine structure (XAFS) spectroscopy revealed that the soil Cu speciation changed from predominantly Cu(II) bound to soil organic matter (SOM) intermittently to 14% metallic Cu(0) and subsequently to 66% copper sulfide (CuxS). These CuxS precipitates accounted for most of the formed CRS, suggesting that CuxS was the dominant sulfide phase formed in the flooded soil. Sequential metal extractions, in agreement with CRS results, suggested that easily mobilizable Cd was completely and Pb partially sequestered in sulfide precipitates, controlling their dissolved concentrations to below detection limits. In contrast, Zn and Ni (as well as Fe) were hardly sequestered into sulfide phases, so that micromolar levels of dissolved Zn and Ni (and millimolar dissolved Fe(II)) persisted in the reduced soil. The finding that Cu, Cd, and Pb were sequestered (but hardly any Zn, Ni, and Fe) is consistent with the thermodynamically predicted sulfide ladder following the increasing solubility products of the respective metal sulfides. The observation that Cd and Pb were sequestered in sulfides despite the presence of remaining SOM-bound Cu(II) suggested that the kinetics of Cu(II) desorption, diffusion, and/or CuxS precipitation interfered with the sulfide ladder. We conclude that the dynamics of multiple metal contaminants are intimately coupled under sulfate limitation by the relative thermodynamic stabilities and formation kinetics of the respective metal sulfides.  相似文献   
148.
The suspended particulate organic matter, SPOM, in the autumnal Black Sea has been characterised using catalytic hydropyrolysis (HyPy) of the total (bound plus free) lipid material. The technique, which generates maximum yields of volatile products from sediments, kerogens and phytoplankton, was followed using gas chromatography and gas chromatography/mass spectrometry. The generated alkanes were dominated by n-C18, hypothesised to arise predominantly from unsaturated C18 fatty acids. Steranes were generated from reductive conversion of free and bound sterols. The generation of branched alkanes and especially of hopanes provided formal evidence for the participation of bacteria in the mineralisation of the SPOM. Whereas similar distributions of n-alkanes were generated from SPOM sampled from different depths of the comparatively well-stirred Rhodes Gyre (eastern Mediterranean), mineralisation of the SPOM at each depth of the central Black Sea produced characteristic changes in the composition and concentration of the HyPy products. Depth profiles of the n-alkanes generated from SPOM in the region of the Rim Current were affected by the local hydrography. Polynuclear aromatic hydrocarbons (PAHs) of anthropogenic origin were present in the surface waters of the central Black Sea. Some methyl benzenes, thiophenes and pyrroles were also generated.  相似文献   
149.
Embodiment is a central concept in Krieger’s ecosocial theory, and is said to be of relevance to the understanding of the relationship between social conditions and a variety of adverse health outcomes. The most detailed empirical investigation of this in Krieger’s work is to be found in her studies of the relationship between racial discrimination and high blood pressure. Of especial relevance here is the idea of internalized oppression which is said to explain the observed association between self-reports of no racial discrimination and increased levels of blood pressure among working-class African Americans. Here we critically examine the empirical evidence pertaining to internalized oppression. Specifically, we focus on the measurement of the construct and the quality of the empirical evidence that has been presented in support of the hypothesis that there is an association between internalized oppression and adverse health outcomes. We argue that the validity of the concept has yet to be established and that the available data linking it to poor health outcomes are open to alternative explanations, notably measurement error and misclassification.
Eugenia CondeEmail:
  相似文献   
150.
The Northern Iberian margin is a typical example of a continental margin subjected to seasonal highly energetic regime (waves and tides) and receiving inputs of continental sediments via riverine discharges. The principal goal of this study has been to use clay minerals as indicators of sedimentary dynamics in the open shelf system. The distributions of clay mineral in the top layer of the sedimentary cover are shown to be related to their continental sources, but also reflect the influences of winter storms and longshore currents in determining the pathways of sediment transport.The mineralogical composition of the material issuing from the rivers is very similar to the general mineralogical composition of the fine fractions of the seabed sediments. Those deposits that are directly influenced by riverine discharges have higher contents of kaolinite (>20%), whereas those that are not have higher contents of illite (>80%). The available data indicate no significant quantities of terrigenous particles are being discharged from the Spanish rias. Therefore, we conclude that physical processes are controlling the clay mineral distributions and that, despite contributions from the Minho River, the main source of fine detrital particles to the shelf region is the Douro River discharge. These particles settle on the middle shelf, below the 60 m isobath. During storm events these particles are re-suspended and advected northwards to the Galician shelf or into deeper domains. Thus the distributions of the clays indicate there is a net transport of fine sediments both northwards and off-shelf.  相似文献   
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