Economic potential of the ultramafic rocks of Jamaica and Tobago: two contrasting geological settings in the Caribbean     

P. W. Scott  T. A. Jackson  A. C. Dunham 《Mineralium Deposita》1999,34(7):718-723

Ultramafic rocks in Jamaica are dunites with minor lherzolite, often serpentinised, and are part of a dismembered ophiolite complex. In Tobago, dunites, wehrlites, pyroxenites and hornblendites form the lower part of a plutonic complex of island arc affinity. The mineral assemblages and chemistry reflect these differences. Chromite in Jamaica is high in Al and Mg, whereas in Tobago it is rich in Fe, as in Alaskan-type intrusives. Ni-Cu-PGE assemblages in Jamaica are pentlandite, with later low temperature heazlewoodite, awaruite and native copper, the latter with Pt and Pd. In Tobago an assemblage of pentlandite, pyrrhotite, pyrite and chalcopyrite is much less affected by later alteration. PGE phases also occur. The dunites in Jamaica have sufficient MgO to be a potential source of olivine. The higher Fe in olivine from Tobago indicates that olivine cumulates in plutonics from island arc settings are a less suitable source of the mineral. Ni-laterites in Jamaica are unlikely because of high topographic relief. The prospect for Ni-laterites in Tobago is low as there is little Ni in the olivines. Chrysotile asbestos, talc and magnesite are absent in both islands. This is probably a consequence of the lack of secondary serpentine recrystallisation to form fibrous chrysotile veins, the deep tectonic level and lack of hydrothermal circulation for magnesite to form, and the absence of metamorphic/metasomatic events and/or late stage extension tectonics which might have yielded talc. Received: 14 September 1998 / Accepted: 4 March 1999  相似文献   

Formation of feldspathic and metallic melts by shock in enstatite chondrite Reckling Peak A80259     

Timothy j. Fagan  Edward r. d. Scott  Klaus Keil  Thomas f. Cooney  Shiv k. Sharma 《Meteoritics & planetary science》2000,35(2):319-329

Abstract— The enstatite chondrite reckling peak (rkp) a80259 contains feldspathic glass, kamacite, troilite, and unusual sets of parallel fine‐grained enstatite prisms that formed by rapid cooling of shock melts. Metallic Fe,Ni and troilite occur as spherical inclusions in feldspathic glass, reflecting the immiscible Fe‐Ni‐S and feldspathic melts generated during the impact. The Fe‐Ni‐S and feldspathic liquids were injected into fractures in coarse‐grained enstatite and cooled rapidly, resulting in thin (≤ 10 μm) semicontinuous to discontinuous veins and inclusion trails in host enstatite. Whole‐rock melt veins characteristic of heavily shocked ordinary chondrites are conspicuously absent. Raman spectroscopy shows that the feldspathic material is a glass. Elevated MgO and SiO₂ contents of the glass indicate that some enstatite and silica were incorporated in the feldspathic melt. Metallic Fe,Ni globules are enclosed by sulfide and exhibit Nienrichment along their margins characteristic of rapid crystallization from a Fe‐Ni‐S liquid. Metal enclosed by sulfide is higher in Si and P than metal in feldspathic glass and enstatite, possibly indicating lower O fugacities in metal/sulfide than in silicate domains. Fine‐grained, elongate enstatite prisms in troilite or feldspathic glass crystallized from local pyroxene melts that formed along precursor grain boundaries, but most of the enstatite in the target rock remained solid during the impact and occurs as deformed, coarsegrained crystals with lower CaO, Al₂O₃, and FeO than the fine‐grained enstatite. Reckling Peak A80259 represents an intermediate stage of shock melting between unmelted E chondrites and whole‐rock shock melts and melt breccias documented by previous workers. The shock petrogenesis of RKPA80259 reflects the extensive impact processing of the enstatite chondrite parent bodies relative to those of other chondrite types.  相似文献   

Near-infrared adaptive optics imaging of nuclear spiral structure in the Seyfert galaxy NGC 3227     

Scott C. Chapman  †‡  Simon L. Morris ‡  Gordon A. H. Walker 《Monthly notices of the Royal Astronomical Society》2000,319(3):666-676

We present high spatial resolution, near-infrared images in J , H and K of the nucleus of NGC 3227, obtained with the Adaptive Optics Bonnette on the Canada–France–Hawaii Telescope. The ∼0.15 arcsec (17 pc) resolution allows structures to be probed in the core region. Dust obscuration becomes significantly less pronounced at longer wavelengths, revealing the true geometry of the core region. We are able to identify two main features in our maps: (i) a spiralling association of knots with a counterpart in a Hubble Space Telescope F606W image; and (ii) a smaller-scale annulus, orthogonal to the spiral of knots. These features may provide a means to transport material inwards to fuel the active nucleus.  相似文献   

The legal context of intellectual property rights and marine biotechnology     

Geoffrey R. Scott 《Ocean & Coastal Management》1998,38(3):229-277

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Influence of chronic exposure to silver and mercury in the field on the bioaccumulation potential of the bivalve Macoma balthica     

Florence Boisson  Mark G.J. Hartl  Scott W. Fowler  Claude Amiard-Triquet   《Marine environmental research》1998,45(4-5)

In order to assess the adaptation to metals previously observed in the bioindicator organism, Macoma balthica, subjected to chronic contamination by silver and mercury in the French Loire estuary, the bioaccumulation potential of individual organisms originating from the contaminated Loire estuary and a relatively uncontaminated control estuary (Somme) was evaluated using both radiotracers and stable isotopes of Ag (80 μg Ag litre⁻¹) and Hg (100 μg Hg litre⁻¹). Clams from the contaminated estuary were more sensitive to Ag (LT₅₀ = 9d) than those originating from the Somme estuary (LT₅₀ > 15d), even though the former bioaccumulated Ag to a significantly lower degree. This is attributed to a consequence of the chronic stress induced by Ag while clams were living in their natural environment. Therefore, past history of trace metal contamination should be considered when evaluating the susceptibility of M. balthica to heavy metal exposure. Lower uptake rates obtained for Hg (during the initial uptake phase only) and for Ag in clams from the polluted estuary suggest the presence of an adaptive trait for survival in contaminated areas. However, the lower degree of bioconcentration observed for Ag was not sufficiently low to reduce the sensitivity of the organisms to Ag and allow them to resist the toxic stress. Clams that survived Ag or Hg exposure at LT₅₀ did not protect themselves against metal toxicity by accumulating a significantly lesser amount of these metals than clams which did not survive metal stress. The results suggest that the bioaccumulation potential of each individual was not a factor which can explain the survival ability of M. balthica exposed to chronic Ag and Hg contamination in estuaries. In this case, cellular, biochemical and genetic levels of adaptation are presumed to be of greater importance.  相似文献   

Evidence for cyanobacterial inputs and heterotrophic alteration of lipids in sinking particles in the Alboran Sea (SW Mediterranean)     

Jordi Dachs  Josep M. Bayona  Scott W. Fowler  Juan-Carlos Miquel  Joan Albaigs 《Marine Chemistry》1998,60(3-4)

The different sources of lipid compounds present in sinking particles collected in a sediment trap mooring deployed in the Alboran Sea (SW Mediterranean) were elucidated using the molecular marker concept. A significant contribution of cyanobacterial lipids was identified based on the occurrence of a series of 3- and 5-methylalkanes and dimethylalkanes. Further evidence of cyanobacterial inputs was obtained by principal component analysis of all data showing diploptene and n-alkanes in the range C₁₄–C₂₂ clustered together with those branched alkanes. The use of methyl and dimethyl alkanes to trace cyanobacterial sources in the water column is proposed with advantage to sterols which are usually masked by phytoplanktonic sterols. The sterol distribution indicates phytoplankton as a major source with a contribution from heterotrophic zooplanktonic. Both fossil and biogenic sources can be contributors to the large unresolved complex mixture (UCM) found in these samples.  相似文献   

Transience of channel head locations following disturbance          下载免费PDF全文

Ellen Wohl  Daniel N. Scott 《地球表面变化过程与地形》2017,42(7):1132-1139

We used annual re‐surveys of two populations of channel heads affected by a severe wildfire in 2012 to monitor changes in channel head location with time following disturbance. Relative to channel heads in surrounding unburned areas, the median contributing drainage area of burned channel heads decreased by two orders of magnitude immediately after the fire, but then returned to values comparable to unburned areas within four years. We distinguish three types of channel heads. Permanent channel heads, which constitute 4% of the total population, occur in well‐developed swales in association with stable features such as bedrock outcrops: these channel heads appear to have been unaffected by the fire. Persistent channel heads, which are 40% of the total population, also occur within hillslope concavities, but the exact location of the channel head moves upslope and downslope through time in response to varying inputs of water and sediment. Transient channel heads form on straight and convex slopes immediately following disturbance, but disappear as regrowth of ground cover limits overland flow and sediment movement. The majority of the position changes for persistent and transient channel heads occurred abruptly when viewed as annual time steps. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   

Grazing impacts on gully dynamics indicate approaches for gully erosion control in northeast Australia   总被引：1，自引：0，他引：1       下载免费PDF全文

Scott N. Wilkinson  Anne E. Kinsey‐Henderson  Aaron A. Hawdon  Peter B. Hairsine  Rebecca Bartley  Brett Baker 《地球表面变化过程与地形》2018,43(8):1711-1725

Drainage network extension in semi‐arid rangelands has contributed to a large increase in the amount of fine sediment delivered to the coastal lagoon of the Great Barrier Reef, but gully erosion rates and dynamics are poorly understood. This study monitored annual erosion, deposition and vegetation cover in six gullies for 13 years, in granite‐derived soils of the tropical Burdekin River basin. We also monitored a further 11 gullies in three nearby catchments for 4 years to investigate the effects of grazing intensity. Under livestock grazing, the long‐term fine sediment yield from the planform area of gullies was 6.1 t ha^‐1 yr^‐1. This was 7.3 times the catchment sediment yield, indicating that gullies were erosion hotspots within the catchment. It was estimated that gully erosion supplied between 29 and 44% of catchment sediment yield from 4.5% of catchment area, of which 85% was derived from gully wall erosion. Under long‐term livestock exclusion gully sediment yields were 77% lower than those of grazed gullies due to smaller gully extent, and lower erosion rates especially on gully walls. Gully wall erosion will continue to be a major landscape sediment source that is sensitive to grazing pressure, long after gully length and depth have stabilised. Wall erosion was generally lower at higher levels of wall vegetation cover, suggesting that yield could be reduced by increasing cover. Annual variations in gully head erosion and net sediment yield were strongly dependent on annual rainfall and runoff, suggesting that sediment yield would also be reduced if surface runoff could be reduced. Deposition occurred in the downstream valley segments of most gullies. This study concludes that reducing livestock grazing pressure within and around gullies in hillslope drainage lines is a primary method of gully erosion control, which could deliver substantial reductions in sediment yield. Copyright © 2018 John Wiley & Sons, Ltd.  相似文献   

A Practical Modeling Framework for Non‐Fickian Transport and Multi‐Species Sequential First‐Order Reaction          下载免费PDF全文

Daniel K. Burnell  Jie Xu  Scott K. Hansen  Lawrence S. Sims  Charles R. Faust 《Ground water》2018,56(4):524-540

Many studies indicate that small‐scale heterogeneity and/or mobile–immobile mass exchange produce transient non‐Fickian plume behavior that is not well captured by the use of the standard, deterministic advection‐dispersion equation (ADE). An extended ADE modeling framework is presented here that is based on continuous time random walk theory. It can be used to characterize non‐Fickian transport coupled with simultaneous sequential first‐order reactions (e.g., biodegradation or radioactive decay) for multiple degrading contaminants such as chlorinated solvents, royal demolition explosive, pesticides, and radionuclides. To demonstrate this modeling framework, new transient analytical solutions are derived and are inverted in Laplace space. Closed‐form, steady‐state, multi‐species analytical solutions are also derived for non‐Fickian transport in highly heterogeneous aquifers with linear sorption–desorption and matrix diffusion for use in spreadsheets. The solutions are general enough to allow different degradation rates for the mobile and immobile zones. The transient solutions for multi‐species transport are applied to examine the effects of source remediation on the natural attenuation of downgradient plumes of both parent and degradation products in highly heterogeneous aquifers. Results for representative settings show that the use of the standard, deterministic ADE can over‐estimate cleanup rates and under‐predict the cleanup timeframe in comparison to the extended ADE analytical model. The modeling framework and calculations introduced here are also applied for a 30 year groundwater cleanup program at a site in Palm Bay, Florida. The simulated plume concentrations using the extended ADE exhibited agreement with observed long concentration tails of trichloroethene, cis 1,2 DCE, and VC that remained above cleanup goals.  相似文献   

Quantifying River‐Groundwater Interactions of New Zealand's Gravel‐Bed Rivers: The Wairau Plain          下载免费PDF全文

Thomas Wöhling  Moritz J. Gosses  Scott R. Wilson  Peter Davidson 《Ground water》2018,56(4):647-666

New Zealand's gravel‐bed rivers have deposited coarse, highly conductive gravel aquifers that are predominantly fed by river water. Managing their groundwater resources is challenging because the recharge mechanisms in these rivers are poorly understood and recharge rates are difficult to predict, particularly under a more variable future climate. To understand the river‐groundwater exchange processes in gravel‐bed rivers, we investigate the Wairau Plain Aquifer using a three‐dimensional groundwater flow model which was calibrated using targeted field observations, “soft” information from experts of the local water authority, parameter regularization techniques, and the model‐independent parameter estimation software PEST. The uncertainty of simulated river‐aquifer exchange flows, groundwater heads, spring flows, and mean transit times were evaluated using Null‐space Monte‐Carlo methods. Our analysis suggests that the river is hydraulically perched (losing) above the regional water table in its upper reaches and is gaining downstream where marine sediments overlay unconfined gravels. River recharge rates are on average 7.3 m³/s, but are highly dynamic in time and variable in space. Although the river discharge regularly hits 1000 m³/s, the net exchange flow rarely exceeds 12 m³/s and seems to be limited by the physical constraints of unit‐gradient flux under disconnected rivers. An important finding for the management of the aquifer is that changes in aquifer storage are mainly affected by the frequency and duration of low‐flow periods in the river. We hypothesize that the new insights into the river‐groundwater exchange mechanisms of the presented case study are transferable to other rivers with similar characteristics.  相似文献