193nmLA-ICPMS对国际地质标准参考物质中42种主量和微量元素的分析   总被引：31，自引：16，他引：31  

柳小明  高山  袁洪林  Bodo HATTENDORF  DetlefGNTHER  陈亮  胡圣红 《岩石学报》2002,18(3):408-418

本文采用配备有 193nm Ar F准分子 (excimer)激光器的 Geo L as2 0 0 M剥蚀系统和 Elan6 10 0 DRC ICP- MS对 4个美国地质调查所 (USGS)玻璃标准参考物质以及 3个美国国家标准技术研究院 (NIST)人工合成硅酸盐玻璃标准参考物质中几乎覆盖整个质量数范围 (从 7L i到 2 38U)的 38个微量和 4个主量 (Na、Mg、Ti和 Mn)元素进行了分析。分析结果表明 ,无论是对 USGS还是 NIST玻璃 ,元素分析的相对标准偏差 RSDs和分析值与参考值之间的相对偏差 (RDs)一般优于 10 % ,RSD和RD较大的元素主要出现在含量很低或不均匀样品中。稀土元素的 RSD显示 ,除 AGV- 2 G可能存在不均匀现象外 ,其它所测样品在 6 0 μm尺度上 ,元素分布是均匀的。本研究证明 ,由于 ICP- MS具有 10 8cps(每秒计数 )的动态线性范围 ,本实验室的L A- ICPMS系统可定量分析含量在百分之几的主量元素及微量元素。分析精密度和准确度可与常规溶液雾化进样 ICP- MS方法相媲美  相似文献   

A Reanalysis and Reinterpretation of Geodetic and Geological Evidence of Glacial-Isostatic Adjustment in the Churchill Region, Hudson Bay     

Detlef Wolf  Volker Klemann  Johann Wünsch  Fei-peng Zhang 《Surveys in Geophysics》2006,27(1):19-61

We review the historical, geological, tide-gauge, GPS and gravimetric evidence advanced in favour of, or against, continuing land uplift around Hudson Bay, Canada. We also reanalyse the tide-gauge and GPS data for Churchill using longer time series than those available to previous investigators. The dependence of the mean rate of relative sea-level change obtained from the tide-gauge record on the length and mid-epoch of the observation interval considered is investigated by means of a newly developed linear-trend analysis diagram. For studying the shorter-period variability of the tide-gauge record, the wavelet transform is used. The mean rate of land uplift obtained from GPS is based on a new analysis using IGS solutions of GFZ. To include the post-glacial land uplift, sea-level indicators from the Churchill region representing the relative sea-level history during the past 8000 years are also used. Finally, the values of the four observables are jointly inverted in terms of mantle viscosity. The optimum values are ~3.2 × 10²⁰ Pa s and ~1.6 × 10²² Pa s for the upper- and lower-mantle viscosities, respectively.  相似文献   

The Consistency of IPCC's SRES Scenarios to 1990–2000 Trends and Recent Projections     

Detlef P. van Vuuren  Brian C. O'Neill 《Climatic change》2006,75(1-2):9-46

The greenhouse gas emissions scenarios published by the IPCC in the Special Report on Emission Scenarios (SRES) continue to serve as a primary basis for assessing future climate change and possible response strategies. These scenarios were developed between 1996 and 1999 and sufficient time has now passed to make it worth examining their consistency with more recent data and projections. The comparison performed in this paper includes population, GDP, energy use, and emissions of CO₂, non-CO₂ gases and sulfur. We find the SRES scenarios to be largely consistent with historical data for the 1990–2000 period and with recent projections. Exceptions to this general observation include (1) in the long-term, relatively high population growth assumptions; in some regions, particularly in the A2 scenario; (2) in the medium-term, relatively high economic growth assumptions in the LAM (Latin America, Africa and Middle East) region in the A1 scenario; (3) in the short-term, CO₂ emissions projections in A1 that are somewhat higher than the range of current scenarios; and (4) substantially higher sulfur emissions in some scenarios than in historical data and recent projections. In conclusion, given the relatively small inconsistencies for use as global scenarios there seems to be no immediate need for a large-scale IPCC-led update of the SRES scenarios that is solely based on the SRES scenario performance vis-a-vis data for the 1990–2000 period and/or more recent projections. Based on reported findings, individual research teams could make, and in some cases already have made, useful updates of the scenarios.  相似文献   

Heat capacity of wadeite-type K2Si4O9 and the pressure-induced stable decomposition of K-feldspar     

Detlef W. Fasshauer  Bernd Wunder  Niranjan D. Chatterjee  Günther W. H. Höhne 《Contributions to Mineralogy and Petrology》1998,131(2-3):210-218

The heat capacity of synthetic, stoichiometric wadeite-type K₂Si₄O₉ has been measured by DSC in the 195≤T(K)≤598 range. Near the upper temperature limit of our data, the heat capacity observed by DSC agrees with that reported by Geisinger et al. (1987) based on a vibrational model of their infrared and Raman spectroscopic data. However, with decreasing temperature, the Cp observed by DSC is progressively higher than that predicted from the vibrational model, suggesting that the standard entropy of K₂Si₄O₉ is likely to be larger than 198.9 ± 4.0 J/K · mol computed from the spectroscopic data. A fit to the DSC data gave: Cp(T) = 499.13 (±1.87) − 4.35014 · 10³(±3.489 · 10¹) · T ^−0.5, with T in K and average absolute percent deviation of 0.37%. The room-temperature compressibilities of kalsilite and leucite, hitherto unknown, have been measured as well. The data, fitted to the Murnaghan equation of state, gave K _o = 58.6 GPa, K _o ^′ = 0.1 for kalsilite and K _o = 45 GPa, K _o ^′ = 5.7 for α-leucite. Apart from the above mentioned data on the properties of the individual phases, we have also obtained reaction-reversals on four equilibria in the system K₂O-Al₂O₃-SiO₂. The Bayesian method has been used simultaneously to process the properties of 13 phases and 15 reactions between them to derive an internally consistent thermodynamic dataset for the K₂O-Al₂O₃-SiO₂ ternary. The enthalpy of formation of K₂Si₄O₉ wadeite is in perfect agreement with its revised calorimetric value, the standard entropy is 232.1 ± 10.4 J/K · mol, ∼15% higher than that implied by vibrational modeling. The phase diagram, generated from our internally consistent thermodynamic dataset, shows that for all probable P-T trajectories in the subduction regime, the stable pressure-induced decomposition of K-feldspar will produce coesite + kalsilite rather than coesite + kyanite + K₂Si₄O₉ (cf. Urakawa et al. 1994). Received: 11 June 1997 / Accepted: 2 December 1997  相似文献   

Small-scale diffusion experiments in the Baltic surface-mixed layer under different weather conditions     

Prof. Dr. Friedrich Schott  Mafred Ehlers  Lutz Hubrich  Detlef Quadfasel 《Ocean Dynamics》1978,31(6):195-215

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Comparison of different methods of current measurements     

Detlef Quadfasel  Prof. Dr. Friedrich Schott 《Ocean Dynamics》1979,32(1):27-38

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Consistent realization of Celestial and Terrestrial Reference Frames     

Younghee Kwak  Mathis Bloßfeld  Ralf Schmid  Detlef Angermann  Michael Gerstl  Manuela Seitz 《Journal of Geodesy》2018,92(9):1047-1061

The Celestial Reference System (CRS) is currently realized only by Very Long Baseline Interferometry (VLBI) because it is the space geodetic technique that enables observations in that frame. In contrast, the Terrestrial Reference System (TRS) is realized by means of the combination of four space geodetic techniques: Global Navigation Satellite System (GNSS), VLBI, Satellite Laser Ranging (SLR), and Doppler Orbitography and Radiopositioning Integrated by Satellite. The Earth orientation parameters (EOP) are the link between the two types of systems, CRS and TRS. The EOP series of the International Earth Rotation and Reference Systems Service were combined of specifically selected series from various analysis centers. Other EOP series were generated by a simultaneous estimation together with the TRF while the CRF was fixed. Those computation approaches entail inherent inconsistencies between TRF, EOP, and CRF, also because the input data sets are different. A combined normal equation (NEQ) system, which consists of all the parameters, i.e., TRF, EOP, and CRF, would overcome such an inconsistency. In this paper, we simultaneously estimate TRF, EOP, and CRF from an inter-technique combined NEQ using the latest GNSS, VLBI, and SLR data (2005–2015). The results show that the selection of local ties is most critical to the TRF. The combination of pole coordinates is beneficial for the CRF, whereas the combination of \(\varDelta \hbox {UT1}\) results in clear rotations of the estimated CRF. However, the standard deviations of the EOP and the CRF improve by the inter-technique combination which indicates the benefits of a common estimation of all parameters. It became evident that the common determination of TRF, EOP, and CRF systematically influences future ICRF computations at the level of several \(\upmu \)as. Moreover, the CRF is influenced by up to \(50~\upmu \)as if the station coordinates and EOP are dominated by the satellite techniques.  相似文献   

An ESA NEOCC Effort to Eliminate High Palermo Scale Virtual Impactors     

Marco Micheli  Detlef Koschny  Gerhard Drolshagen  Olivier Hainaut  Fabrizio Bernardi 《Earth, Moon, and Planets》2014,113(1-4):1-13

In this work we summarize the initial results of a targeted effort of the ESA NEO Coordination Centre to obtain additional observational data in order to eliminate or reduce the impact probability estimate of a subset of the known near-Earth objects representing the highest fraction of the total known impact risk, as measured by the Palermo Scale.  相似文献   

A proposal for a new scenario framework to support research and assessment in different climate research communities   总被引：1，自引：0，他引：1  

Detlef P. van Vuuren  Keywan Riahi  Richard Moss  Jae Edmonds  Allison Thomson  Nebojsa Nakicenovic  Tom Kram  Frans Berkhout  Rob Swart  Anthony Janetos  Steven K. Rose  Nigel Arnell 《Global Environmental Change》2012,22(1):21-35

In this paper, we propose a scenario framework that could provide a scenario “thread” through the different climate research communities (climate change – vulnerability, impact, and adaptation - and mitigation) in order to support assessment of mitigation and adaptation strategies and climate impacts. The scenario framework is organized around a matrix with two main axes: radiative forcing levels and socio-economic conditions. The radiative forcing levels (and the associated climate signal) are described by the new Representative Concentration Pathways. The second axis, socio-economic developments comprises elements that affect the capacity for mitigation and adaptation, as well as the exposure to climate impacts. The proposed scenarios derived from this framework are limited in number, allow for comparison across various mitigation and adaptation levels, address a range of vulnerability characteristics, provide information across climate forcing and vulnerability states and span a full century time scale. Assessments based on the proposed scenario framework would strengthen cooperation between integrated-assessment modelers, climate modelers and vulnerability, impact and adaptation researchers, and most importantly, facilitate the development of more consistent and comparable research within and across these research communities.  相似文献   

Adaptation in integrated assessment modeling: where do we stand?     

Anthony G. Patt  Detlef P. van Vuuren  Frans Berkhout  Asbjørn Aaheim  Andries F. Hof  Morna Isaac  Reinhard Mechler 《Climatic change》2010,99(3-4):383-402

Adaptation is an important element on the climate change policy agenda. Integrated assessment models, which are key tools to assess climate change policies, have begun to address adaptation, either by including it implicitly in damage cost estimates, or by making it an explicit control variable. We analyze how modelers have chosen to describe adaptation within an integrated framework, and suggest many ways they could improve the treatment of adaptation by considering more of its bottom-up characteristics. Until this happens, we suggest, models may be too optimistic about the net benefits adaptation can provide, and therefore may underestimate the amount of mitigation they judge to be socially optimal. Under some conditions, better modeling of adaptation costs and benefits could have important implications for defining mitigation targets.  相似文献