Trace analysis of hydrocarbons in coral cores from Saudi Arabia   总被引：1，自引：0，他引：1  

Anita Poulsen  Kathryn Burns  Janice Lough  Diane Brinkman  Steven Delean 《Organic Geochemistry》2006,37(12):1913

As part of a long-term environmental assessment of the impact of the 1991 Gulf War on coral reefs, the Australian Institute of Marine Science (AIMS) conducted growth and chemistry studies on coral cores from the Arabian Gulf. Twenty-eight cores were collected from four coral reefs located offshore from Saudi Arabia.Annual coral growth bands surrounding the 1991 oil spill were analysed in selected cores. Additionally, in cores that extended to the early 1980s, annual layers from 1980 to 1986 were analysed for possible residues from the 1983–4 oil spill caused by the Nowruz oil field blowout during the Iraq–Iran war. Both major spill events were targeted to provide additional confidence in relating oil concentrations to specific pollution events. We detected petroleum biomarkers in several coral annual bands related to the major pollution events. However, the oil remaining in these cores has been altered over time and the biomarker ratios found in these oil residues differed from Gulf crude oils.The concentrations of hydrocarbons were compared with the growth parameters of the coral cores. Only one sample may have recorded an “impact” of oil exposure. There was no other correspondence between slight changes in growth parameters between years and the trace chemistry. Therefore, chemical analysis enabled detection of the exposure incident, but provided no insight into the amount of oil to which the coral had been exposed. The chemical data can only infer biological impact if growth was significantly decreased.The average coral growth characteristics of Porites from the four sites in the Arabian Gulf were normal, as predicted from the average water temperatures of the region. There was an indication of an overall decline in growth over time, which should be monitored in the future.  相似文献   

Complete Trace Elemental Characterisation of Granitoid (USGS G-2, GSP-2) Reference Materials by High Resolution Inductively Coupled Plasma-Mass Spectrometry     

Wilma Pretorius  Dominique Weis  Gwen Williams  Diane Hanano  Bruno Kieffer  James Scoates 《Geostandards and Geoanalytical Research》2006,30(1):39-54

The United States Geological Survey granitic and granodioritic reference materials G‐2 and GSP‐2 were decomposed in high‐pressure bombs using both HF‐HNO₃ and HF‐HNO₃‐HClO₄ in order to evaluate the feasibility of characterising the entire suite of geologically relevant trace elements through direct analysis with a high‐resolution inductively coupled plasma‐mass spectrometer (HR‐ICP‐MS). The digested samples were diluted to the appropriate levels and analysed at low, medium and high resolution depending on the required sensitivity and potential interferences for each element. Memory effects during analysis of the high field strength elements (HFSE) were negligible when analysed using an all‐Teflon, uncooled sample introduction system and combined with adequate wash times with 4% v/v aqua regia + 0.5% v/v HF between samples. The concentration of the remaining lithophile elements was determined with a conventional, cooled, Scott‐type spray chamber using a wash solution of 1% v/v HNO₃. Total procedural blanks contributed between 0.01 to 0.5% to final sample concentrations and blank subtractions were typically unnecessary. Abundances for Li, Hf, Ba, Zr, Ga, Rb, Sr, La, Ce, Th and U were systematically higher, while those for the heavy rare earth elements (HREEs), Cu and Y were systematically lower in this study compared to USGS values for G‐2 and GSP‐2. This is likely to be related to, respectively, higher recoveries from more efficient digestion of refractory phases (i.e., zircon, tourmaline), and better resolution of interferences when using a HR‐ICP‐MS. Sample digestion experiments also showed that perchloric acid digestion in high pressure bombs resulted in superior recoveries and better precision for the bulk of the trace elements analysed. The concentration of the remaining elements overlapped within uncertainty with recommended reference values and with values determined in other studies using isotope‐dilution TIMS, ICP‐MS and XRF. Concentrations for the elements Cd, Sn, Sb, Ta, Bi, Tb, Ni and Mo are also reported for G‐2 and GSP‐2 reference materials. Our study shows therefore that it is feasible to determine thirty‐nine geologically relevant trace elements accurately and directly in granitoid sample digests when using a HR‐ICP‐MS, thereby negating the need for ion exchange or isotopic spiking.  相似文献   

Spatial and temporal variations of sediment size on a mixed sand and gravel beach     

Diane P. Horn  Susan M. Walton 《Sedimentary Geology》2007,202(3):509-528

Mixed sand and gravel beaches have been the subject of comparatively few studies in the UK. This paper describes the sediment distribution before, during and after a programme of beach nourishment along a section of mixed sand and gravel beach forming part of the Pevensey Bay Coastal Defences, in East Sussex, UK. The beach was recharged in September 2002, and beach profiles were measured along three cross-shore transects from August 2002 to February 2003. Sediment samples were taken along the transects between August and November 2002, and a total of 147 sediment samples were analysed, 40 before nourishment and 107 after nourishment. The majority of the sediment samples were strongly bimodal, with mean sizes varying between a minimum of 0.18 mm (2.48 ?) for the sand fraction and a maximum of 27 mm (− 4.74 ?) for the gravel. The recharge material was also bimodal but contained more fine sediment than the natural beach material, particularly on the upper beach. The recharge sediment had grain sizes and sorting similar to some of the natural material but lower bimodality parameters than any of the natural sediment. The sediment distributions after recharge contained significantly more fine sediment, particularly on the upper beach. Over time, the beach profile lowered and fine sediment appeared to be selectively transported seawards from the beachface.  相似文献   

An evaluation of accuracy, precision, and speed of several zooplankton subsampling techniques   总被引：4，自引：1，他引：3  

van Guelpen  Louis; Markle  Douglas F.; Duggan  Diane J. 《ICES Journal of Marine Science》1982,40(3):226-236

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Origin of silicic volcanic rocks in Central Costa Rica: a study of a chemically variable ash-flow sheet in the Tiribí Tuff     

Rachel S. Hannah  Thomas A. Vogel  Lina C. Patino  Guillermo E. Alvarado  Wendy Pérez  Diane R. Smith 《Bulletin of Volcanology》2002,64(2):117-133

Chemical heterogeneities of pumice clasts in an ash-flow sheet can be used to determine processes that occur in the magma chamber because they represent samples of magma that were erupted at the same time. The dominant ash-flow sheet in the Tiribí Tuff contains pumice clasts that range in composition from 55.1 to 69.2 wt% SiO₂. It covers about 820 km² and has a volume of about 25 km³ dense-rock equivalent (DRE). Based on pumice clast compositions, the sheet can be divided into three distinct chemical groupings: a low-silica group (55.1-65.6 wt% SiO₂), a silicic group (66.2-69.2 wt% SiO₂), and a mingled group (58.6-67.7 wt% SiO₂; all compositions calculated 100% anhydrous). Major and trace element modeling indicates that the low-silica magma represents a mantle melt that has undergone fractional crystallization, creating a continuous range of silica content from 55.1-65.6 wt% SiO₂. Eu/Eu*, MREE, and HREE differences between the two groups are not consistent with crystal fractionation of the low-silica magma to produce the silicic magma. The low-silica group and the silicic group represent two distinct magmas, which did not evolve in the same magma chamber. We suggest that the silicic melts resulted from partial melting of relatively hot, evolved calc-alkaline rocks that were previously emplaced and ponded at the base of an over-thickened basaltic crust. The mingled group represents mingling of the two magmas shortly before eruption. Electronic supplementary material to this paper can be obtained by using the Springer LINK server located at http://dx.doi.org/10.1007/s00445-001-0188-8.  相似文献   

Sources of osmium to the modern oceans: new evidence from the Pt-Os system     

Diane K. McDaniel  Richard J. Walker  Mary F. Horan  Richard I. Grauch 《Geochimica et cosmochimica acta》2004,68(6):1243-1252

High precision Os isotope analysis of young marine manganese nodules indicate that whereas the composition of modern seawater is radiogenic with respect to ¹⁸⁷Os/¹⁸⁸Os, it has ¹⁸⁶Os/¹⁸⁸Os that is within uncertainty of the chondritic value. Marine Mn nodule compositions thus indicate that the average continental source of Os to modern seawater had long-term high Re/Os compared to Pt/Os. Analyses of loess and freshwater Mn nodules support existing evidence that average upper continental crust (UCC) has resolvably suprachondritic ¹⁸⁶Os/¹⁸⁸Os, as well as radiogenic ¹⁸⁷Os/¹⁸⁸Os. Modeling the composition of seawater as a two-component mixture of oceanic/cosmic Os with chondritic Os compositions and continentally-derived Os demonstrates that, insofar as estimates for the composition of average UCC are accurate, congruently weathered average UCC cannot be the sole continental source of Os to seawater. Our analysis of four Cambrian black shales confirm that organic-rich sediments can have ¹⁸⁷Os/¹⁸⁸Os ratios that are much higher than average UCC, but ¹⁸⁶Os/¹⁸⁸Os compositions that are generally between those of chondrites and average-UCC. Preferential weathering of black shales can result in dissolved Os discharged to the ocean basins that has a much lower ¹⁸⁶Os/¹⁸⁸Os than does average upper crust. Modeling the available data demonstrates that augmentation of estimated average UCC compositions with less than 0.1% additional black shale and 1.4% additional ultramafic rock can produce a continental end-member Os isotopic composition that satisfies the requirements imposed by the marine Mn nodule data. The interplay of these two sources provides a mechanism by which the ¹⁸⁷Os/¹⁸⁸Os of seawater can change as sources and weathering conditions change, yet seawater ¹⁸⁶Os/¹⁸⁸Os varies only minimally.  相似文献   

Using Video and GIS to Measure Two-dimensional Water Surface Elevations in the Swash Zone     

Matthew Foote  & Diane Horn 《Transactions in GIS》2002,6(1):43-68

This paper describes initial research into the use of video imaging technologies to provide high-resolution hydrodynamic measurements of two-dimensional cross-shore swash water surfaces. Data collected from a laboratory-based video system and a manual digitisation technique using a desktop GIS are compared with the results from a widely used kinematic model of run-up and backwash. A GIS is then used to produce water surfaces using the kinematic model and then to compare the two graphically. The two-dimensional video technique is believed to provide a novel application of video data for measurement of the swash zone water surface.  相似文献   

Gendered divisions in the new economy: Risks and opportunities     

Diane Perrons 《GeoJournal》2002,56(4):271-280

The concept 'new economy' is widely used to characterise the outcomes of contemporary restructuring processes – but in contrasting ways: by globalisation and the increasing use of communication and information technologies as well as by deregulation, polarisation, feminisation of employment and new, more flexible patterns and hours of work. These tendencies are interlinked and partly account for growing social and gender divisions. They pose problems for social sustainability but also develop differently in different economic and social formations. This paper develops a theoretical understanding of widening social divisions and their gendered form, indicates how these tendencies have developed to different degrees within the European Union and illustrates how the divisions are experienced by people in a local labour market in the neo liberal UK, where social and gender divisions are particularly wide. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Faulting processes of the 1956 San Miguel,Baja California,earthquake sequence     

Diane I. Doser 《Pure and Applied Geophysics》1992,139(1):3-16

Body waveform modeling is used to determine the source processes of three large earthquakes (magnitude 6.8, 6.4, 6.3) occurring between February 9 and 15, 1956 along the San Miguel fault in northern Baja California, Mexico. Results of the modeling suggest that the mainshock on February 9 was responsible for the 20 km of surface faulting observed during the sequence. Although previous researchers have suggested a complex rupture history for the mainshock, uncertainty estimates of source-time function shape indicate single or double source models fit the observed waveforms equally well. The February 15 aftershock, however, appears to have consisted of two events. Locations and focal mechanisms obtained for the three events suggest that the rupture process may have been controlled by cross faults to the main trace of the San Miguel fault. The good correlation between source parameter information and the surficial geology/geometry of the San Miguel fault zone demonstrates the usefulness of waveform modeling studies in unravelling the complexities of historic multi-event earthquake sequences.  相似文献   

Exchange of polychlorinated biphenyls between sediment and water in the Hudson River estuary   总被引：2，自引：0，他引：2  

Diane R. Achman  Bruce J. Brownawell  Lianchu Zhang 《Estuaries and Coasts》1996,19(4):950-965

Sediment-bound polychlorinated biphenyls (PCBs) measured at several sites in the lower Hudson River Estuary are above equilibrium with the overlying water, providing a thermodynamic driving force for exchange from sediment to water. The fluxes of PCB congeners are estimated for a number potential processes: diffusive release of dissolved and colloidal PCBs from the bed, resuspension and subsequent desorption from resuspended particles, and sediment accumulation and burial. All processes are potentially significant, at least for some congeners. The sediment exchange fluxes of PCB solutes for five sites between Governors Island and Haverstraw Bay are estimated to be 20–860 μm m^?2 d^?1, which is between 2 and 100 times more than the flux of dissolved PCBs coming down the river at Haverstraw Bay. Much of the exchange from sediment to water may be balanced by burial of sorbed PCBs by sediment accumulation. Advection down the river and sediment exchange dominate other potential sources of PCBs to the lower estuary under current loading conditions. The magnitude of the calculated fluxes is consistent with the nonconservative behavior of PCBs in the same region but is higher than earlier modeling estimates that employed different assumptions.  相似文献