Identification of stoichiometric iron-phosphorus colloids produced in a eutrophic lake     

Charles-Philippe Lienemann  Marc Monnerat  Janusz Dominik  Didier Perret 《Aquatic Sciences - Research Across Boundaries》1999,61(2):133-149

: Iron-rich colloids formed at the oxic-anoxic interface of a eutrophic lake (Lake Lugano; CH) were characterized by bulk chemical methods and analytical electron microscopy. Fractionation of raw waters showed that non-dissolved iron is particulate above the oxicline and mainly colloidal in the anoxic part of the hypolimnion, while non-dissolved ortho-phosphate is mostly colloidal through the water column. Because of these differences, filtration did not prove helpful for the determination of the role of iron-rich species in the scavenging of ortho-phosphate. On the other hand, analytical electron microscopy revealed that iron-rich nano-granules (ca. 50nm) are associated to the surface of bacterially produced fibrillar polysaccharides. Iron colloids in these complex entities contain important and constant amounts of phosphorus ([PO4]part:[Fe]part = 0.48 - 0.11, n = 1096 Fe-rich entities analyzed by electron microscopy), which suggests that phosphates are stoichiometrically incorporated into the hydrous iron oxide phase, with a tentative composition Fe2[OOH]1-x[(OH)3]x[PO4], during its genesis.  相似文献   

Potential of EPR imaging to detect traces of primitive life in sedimentary rocks     

Laurent Binet  Didier Gourier  Sylvie Derenne 《Earth and Planetary Science Letters》2008,273(3-4):359-366

In the prospect of the search for traces of primitive life on Earth and Mars, we investigated the possibility to detect and visualize the spatial distribution of minute amounts of organic matter in ancient rocks, in a non-destructive way, by Electron Paramagnetic Resonance Imaging (EPRI). We studied a series of non- or moderately metamorphosed siliceous rocks (cherts) of different ages ranging from 45 Ma to 3490 Ma and embedding fossile organic matter. In the case of the oldest cherts containing only mature insoluble organic matter (IOM), with IOM^• radicals characterized by a single Electron Paramagnetic Resonance (EPR) line, we could obtain three-dimensional images with sub-millimetric resolution of the organic matter distribution inside samples containing as low as 10¹⁴–10¹⁵ radicals per gram. In the case of younger cherts, containing less mature organic matter, and thus several types of organic radicals, we showed that selective imaging of each type of radical was possible provided that the EPR spectra did not overlap. Selective imaging of either the organic radicals or of the oxygen vacancy (E' centres) of the mineral matrix, which are ubiquitous in siliceous rocks, was possible, selecting either one or the other paramagnetic species with high power in-phase, 1st harmonic detection or with 90°-out-of-phase, 2nd harmonic detection of the EPR. The influence of ferromagnetic inclusions in the mineral matrix on the EPRI of the organic matter was also addressed. Image artifacts due to the ferromagnetic resonance signal of these inclusions could be easily removed by background substraction from the EPR spectra before image reconstruction. We thus showed that selective imaging by EPR of minute amounts of fossile organic matter in ancient rocks could be possible despite the magnetic complexity of such materials.  相似文献   

Impact of terrestrial runoff on organic matter,trophic state,and phytoplankton in a tropical,upland reservoir     

Duc Anh Trinh  Thi Nguyet Minh Luu  Quan Hong Trinh  Hai Sy Tran  Tien Minh Tran  Thi Phuong Quynh Le  Thuy Thi Duong  Didier Orange  Jean Louis Janeau  Thomas Pommier  Emma Rochelle-Newall 《Aquatic Sciences - Research Across Boundaries》2016,78(2):367-379

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Holocene phreatomagmatic eruptions alongside the densely populated northern shoreline of Lake Kivu,East African Rift: timing and hazard implications     

Sam Poppe  Benoît Smets  Karen Fontijn  Montfort Bagalwa Rukeza  Antoine De Marie Fikiri Migabo  Albert Kyambikwa Milungu  Didier Birimwiragi Namogo  François Kervyn  Matthieu Kervyn 《Bulletin of Volcanology》2016,78(11):82

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Long-term evolution of fish communities in European mountainous rivers: past log driving effects,river management and species introduction (Salzach River,Danube)     

Gertrud Haidvogl  Didier Pont  Horst Dolak  Severin Hohensinner 《Aquatic Sciences - Research Across Boundaries》2015,77(3):395-410

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Historical ecology of riverine fish in Europe     

Gertrud Haidvogl  Richard Hoffmann  Didier Pont  Mathias Jungwirth  Verena Winiwarter 《Aquatic Sciences - Research Across Boundaries》2015,77(3):315-324

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Non-stationary future return levels for extreme rainfall over Extremadura (southwestern Iberian Peninsula)     

Francisco Javier Acero  Sylvie Parey  Thi Thu Huong Hoang  Didier Dacunha-Castelle  José Agustín García  María Cruz Gallego 《水文科学杂志》2017,62(9):1394-1411

Based on a previous study for temperature, a new method for the calculation of non-stationary return levels for extreme rainfall is described and applied to Extremadura, a region of southwestern Spain, using the peaks-over-threshold approach. Both all-days and rainy-days-only datasets were considered and the 20-year return levels expected in 2020 were estimated taking different trends into account: first, for all days, considering a time-dependent threshold and the trend in the scale parameter of the generalized Pareto distribution; and second, for rainy days only, considering how the mean, variance, and number of rainy days evolve. Generally, the changes in mean, variance and number of rainy days can explain the observed trends in extremes, and their extrapolation gives more robust estimations. The results point to a decrease of future return levels in 2020 for spring and winter, but an increase for autumn.  相似文献   

Modelling of internal erosion based on mixture theory: General framework and a case study of soil suffusion     

Tuan-Anh Bui  Rachel Gelet  Didier Marot 《国际地质力学数值与分析法杂志》2019,43(15):2407-2430

A general thermo-hydro-mechanical framework for the modelling of internal erosion is proposed based on the theory of mixtures applied to two-phase porous media. The erodible soil is partitioned in two phases: one solid phase and one fluid phase. The solid phase is composed of nonerodible grains and erodible particles. The fluid phase is composed of water and fluidized particles. Within the fluid phase, species diffuse. Across phases, species transfer. The modelling of internal erosion is contributed directly by mass transfer from the solid phase towards the fluid phase. The constitutive relations governing the thermomechanical behaviour, generalised diffusion, and transfer are structured by the dissipation inequality. The particular case of soil suffusion is investigated with a focus on constitutive laws. A new constitutive law for suffusion is constructed based on thermodynamic conditions and experimental investigations. This erosion law is linearly related to the power of seepage flow and to the erosion resistance index. Owing to its simplicity, this law tackles the overall trend of the suffusion process and permits the formulation of an analytical solution. This new model is then applied to simulate laboratory experiments, by both analytical and numerical methods. The comparison shows that the newly developed model, which is theoretically consistent, can reproduce correctly the overall trend of the cumulated eroded mass when the permeability evolution is small. In addition, the results are provided for four different materials, two different specimen sizes, and various hydraulic loading paths to demonstrate the applicability of the new proposed law.  相似文献   

Late Neogene sequence stratigraphic evolution of the Foz do Amazonas Basin,Brazil     

Christian Gorini  Bilal U. Haq  Antonio Tadeu dos Reis  Cleverson Guizan Silva  Alberto Cruz  Emilson Soares  Didier Grangeon 《地学学报》2014,26(3):179-185

The margin of the Foz do Amazonas Basin saw a shift from predominantly carbonate to siliciclastic sedimentation in the early late Miocene. By this time, the Amazon shelf had also been incised by a canyon that allowed direct influx of sediment to the basin floor, thus confirming that the palaeo‐Amazon fan had already initiated by that time (9.5–8.3 Ma). Above this interval, during a prolonged lowstand, Messinian third‐order sequences are preserved only in the incised‐valley fills of the canyon with no equivalent strata on the shelf. Third‐ and fourth‐order sequences younger than Messinian are preserved on the shelf after sea‐level rise above the shelf by the early Pliocene. Sequences younger than 3.8 Ma often show fourth‐order cyclicity with an average duration of 400 ka (larger scale eccentricity cycles) often preserved in high‐sedimentation‐rate areas of river deltas. Mass wasting and transportation of slope sediments to the basin began to play an important role in sediment dispersal at least as far back as the mid‐Pliocene, after rapid progradation had produced steeper slopes more prone to failure.  相似文献   

Isotopic composition of precipitation during strong El Niño–Southern Oscillation events in the Southeast Region of Brazil     

Vinícius dos Santos  Marcelo Dias de Oliveira  Jan Boll  Ricardo Snchez‐Murillo  Amauri Antonio Menegrio  Luiz Felippe Gozzo  Didier Gastmans 《水文研究》2019,33(4):647-660

Equatorial Pacific sea surface temperature variations interact with processes of atmospheric circulation, creating conditions for the occurrence of El Niño–Southern Oscillation (ENSO). ENSO events represent the most important interannual phenomena affecting climate patterns worldwide and causing significant socio‐economic impacts. In the Brazilian territory, ENSO leads to an increase in drought episodes in the north‐eastern region and an increase in precipitation in the southern region, whereas the effects over the south‐east region are yet not well understood. The main goal of this study is to compare variations of isotopic composition in precipitation across the south‐east portion of the Brazilian territory during two very strong ENSO events: 1997–1998 (ENSO 1) and 2014–2016 (ENSO 2). Daily isotopic records, available from the Global Network of Isotopes in Precipitation database for ENSO 1, and samples collected during ENSO 2 were used to compare the influence of both events on the isotopic composition of precipitation. Seasonal variations indicated more depleted precipitation during the wet seasons (δ¹⁸O = ?5.4 ± 4.0‰) and enriched precipitation during the dry seasons (δ¹⁸O = ?2.8 ± 2.3‰). Observed rainfall variations were associated with atmospheric large‐scale processes and moisture transport from the Amazon region, whereas extreme values (enriched or depleted) appear to be associated with particular convective and stratiform precipitation events. Overall, more depleted isotopic composition of precipitation (δ¹⁸O = ?4.60‰) and higher d‐excess (up to +15‰) were observed during the dry season of ENSO 1 when compared with ENSO 2 dry season (δ¹⁸O‰ = ?2.80‰, d‐excess lower than +14‰). The latter is explained by greater atmospheric moisture content, particularly associated with recycling of transpiration fluxes from the Amazon region, during dry season of ENSO 1. No significant differences for δ¹⁸O and δ²H were observed during the wet season; however, d‐excess from ENSO 2 was greater than ENSO 1, due to the slightly greater atmospheric moisture content and very strong upward motion observed. Our findings highlight the opportunity that environmental isotopes offer towards understanding hydrometeorological processes, particularly, the evolution of extreme climatic events of global resonance such as ENSO.  相似文献