Redistribution of HFSE elements during rutile replacement by titanite   总被引：2，自引：0，他引：2  

Friedrich Lucassen  Peter Dulski  Rainer Abart  Gerhard Franz  Dieter Rhede  Rolf L. Romer 《Contributions to Mineralogy and Petrology》2010,160(2):279-295

Titanite growth at the expense of rutile during retrograde hydration of eclogite into amphibolite is a common phenomenon. We investigated an amphibolite sample from the Tromsø eclogite facies terrain in Northern Norway to gain insight into the trace element distribution between rutile and titanite during incomplete resorption of the rutile by titanite. Patchy compositional zoning of Al, Ti, and F in titanite relates to the presence of a fluid with variable Ti/Al and/or F during its growth. Laser ablation ICP–MS and electron microprobe data for high field strength elements (HFSE: Nb, Zr, Ta, and Hf) of rutile resorbed by titanite indicate a pronounced enrichment of these elements in the rim of a large single rutile crystal (~8 mm) and a systematic decrease towards uniform HFSE contents in the large core. HFSE contents of smaller rutile grains (~0.5 mm) and rutile inclusions (<100 μm) in the titanite overgrowth are similar or higher than in the rims of large rutile crystals. Element profiles from the rim inward demonstrate that HFSE enrichment in rutile is controlled by diffusion. HFSE ratios in diffusion-altered rutile show systematic variations compared with the uniform core composition of the large rutile. Modelling of Zr and Nb diffusion in rutile indicates that diffusion coefficients in rutile in fluid-dominated natural systems must be considerably higher than those determined experimentally at 1 bar in dry systems. Variations of HFSE contents in the newly formed titanite show no systematic spatial distribution. HFSE ratios in titanite and the rims of rutile are different, indicating different solid/fluid distribution coefficients in these minerals. Element fractionation by diffusion into the relict rutile and during fluid-mediated growth of new titanite could substantially change the HFSE budget of these minerals and could affect their use for geochemical tracing and other applications, such as Zr-based geothermobarometry.  相似文献   

Size distribution of the Late Devonian ammonoid Prolobites: indication for possible mass spawning events     

Sonny Alexander Walton  Dieter Korn  Christian Klug 《Swiss Journal of Geoscience》2010,103(3):475-494

Worldwide, the ammonoid genus Prolobites is only known from a few localities, and from these fossil beds almost all of the specimens are adults as shown by the presence of a terminal growth stage. This is in marked contrast to the co-occurring ammonoid genera such as Sporadoceras, Prionoceras, and Platyclymenia. Size distribution of specimens of Prolobites from three studied localities show that, unlike in the co-occurring ammonoid species, most of the material belongs to adult individuals. The morphometric analysis of Prolobites delphinus (Sandberger & Sandberger 1851) demonstrates the intraspecific variability including variants with elliptical coiling and that dimorphism is not detectable. The Prolobites material shows close resemblance to spawning populations of Recent coleoids such as the squid Todarodes filippovae Adam 1975. Possible mass spawning events are discussed in the context of the size distribution and limited geographic range of Prolobites. Finally, the potential fecundity and brooding behaviour of Prolobites is hypothesized using the examples of post spawning egg care in Recent coleoids.  相似文献   

Element signatures of subduction-zone fluids. An experimental study of the element partitioning (Dfluid/rock) of natural partly altered igneous rocks from the ODP drilling site 1,256     

Andreas Mutter  Astrid Holzheid  Andreas Klügel  Max Wilke  Jasper Berndt  Dieter Garbe-Schönberg 《International Journal of Earth Sciences》2014,103(7):1917-1927

The trace element signatures of fluids were investigated by leaching experiments on natural samples of partly altered mafic igneous rocks recovered from the drilling site 1,256 of ODP Leg 206 on the Cocos plate (Central America). Experiments with ultrapure water were performed at 400 °C/0.4 GPa and 500 °C/0.7 GPa. Both fluids and residual solids were examined to obtain the partition coefficients (D^fluid/rock) of various trace elements. Element partition coefficients (D^fluid/rock) obtained at 500 °C/0.7 GPa are significantly lower compared to results obtained at 400 °C/0.4 GPa, which is in contrast to observations at higher pressures (2.2–6 GPa) and temperatures between 700 and 1,400 °C (Kessel et al. in Earth Planet Sci Lett 237: 873–892, 2005a; Spandler et al. in Chem Geol 239: 228–249, 2007). This finding may indicate a considerable pressure effect on the leaching processes and strongly divergent fluid–rock interactions in the upper part of a subduction zone at 0.4–0.7 GPa compared to deeper subduction areas with higher pressures. Furthermore, this may be interpreted as one of the earliest fractionation processes during the subduction of crustal material.  相似文献   

The age of the Roter Kamm impact crater,Namibia: Constraints from 40Ar-39Ar,K-Ar,Rb-Sr,fission track,and 10Be-26Al studies     

Christian Koeberl  Jack B. Hartung  Michael J. Kunk  Jeffrey Klein  Jun-Ichi Matsuda  Keisuke Nagao  Wolf Uwe Reimold  Dieter Storzer 《Meteoritics & planetary science》1993,28(2):204-212

Abstract The well-preserved 2.5 km diameter Roter Kamm impact crater is located in the Namib desert in Namibia. The impact has occurred in Precambrian granitic and granodioritic orthogneisses of the 1200–900 Ma old Namaqualand Metamorphic Complex which were partly covered by Gariep metasediments; the granites are invaded by quartz veins and quartz-feldspar-pegmatites. Previous geological field evidence suggested a crater age of about 5–10 Ma. In order to constrain this age, we selected a set of basement rocks (granites, granodiorites) exposed at the crater rim and studied the Rb-Sr, K-Ar, ⁴⁰Ar-³⁹Ar, and ¹⁰Be-²⁶Al isotopic systems as well as apatite fission track ages of these samples. The Rb-Sr isotopic systematics confirm the derivation of these samples from the Namaqualand basement (age about 1.29 Ga), which underwent Damaran orogenesis at about 650 Ma. No basement rocks with Rb-Sr ages younger than about 410 Ma were identified. The K-Ar ages of pseudotachylite and melt breccia samples show that these samples are dominated by incompletely degassed fragments of basement rocks, with some retaining their original metamorphic ages of about 470 Ma. The apatite fission track ages range from 20–28 Ma, which may be interpreted as an extension of the 25 Ma Burdigalian peneplanation event, or as incomplete resetting of the apatite fission tracks during the impact event. The ¹⁰Be and ²⁶Al exposure age of a quartz sample isolated from a quartz-pegmatite was found to be 150 ka; it is likely that the exposure of the sample began after material covering it had been removed by erosion 150 ka ago. Two glassy fractions extracted from a rim granite were dated by ⁴⁰Ar-³⁹Ar analysis. One sample gives practically a plateau age of 3.7 ± 0.3 Ma, while the other gives a minimum age of 3.6 Ma. The best available age estimate for the Roter Kamm crater is therefore 3.7 ± 0.3 Ma.  相似文献   

SUJETS A TRAITER POUR L'ASSEMBLÉE DE 1960     

Dr.-Ing. Dieter LAUTERBACH  Eberhard GLOS 《水文科学杂志》2013,58(3):9-12

ABSTRACT

The present paper reports on some practical experiences gained in computing unit hydrographs (UH) according to the “classical” linear theory. The sizes of the drainage basins varied from 50 to 800 km² of hilly country.  相似文献   

An interpretation of initial stress and strain methods,and numerical stability     

Dieter F. E. Stolle 《国际地质力学数值与分析法杂志》1991,15(6):399-416

This paper explores similarities and differences between initial stress and initial strain methods of analyses. The author takes the position that both methods, although perhaps conceptually different, are actually numerically the same. A simple approach for providing closed-form stability criteria for explicit and implicit time-marching procedures is described. For the case of associated, non-hardening viscoplasticity the approach provides criteria which are identical to those of Cormeau for explicit schemes. An implicit time-marching scheme which avoids the compliance matrix inversions at the constitutive level is also presented. Like many other implicit methods, this implicit time-marching scheme is unconditionally stable for θ≥½. The connection between initial strain plasticity and an explicit viscoplastic time-marching scheme is also addressed.  相似文献   

THE IMPACT-FLOOD CONNECTION: DOES IT EXIST?*     

Alexander Deutsch  Christian Koeberl  Joel D. Blum  Bevan M. French  Billy P. Glass  Richard Grieve  Peter Horn  Elmar K. Jessberger  Gero Kurat  Wolf Uwe Reimold  Jan Smit  Dieter Stöffler  Stuart Ross Taylor 《地学学报》1994,6(6):644-650

In a recent article in Terra Nova, Kristan-Tollmann and Tollmann (1994) suggested that the Biblical Flood can be explained by seven fragments of a comet that impacted the ocean at seven locations on Earth at 03.00h (C.E.T.) on 23 September, 9545 yr BP. We demonstrate that all the ‘geological proofs’ that allegedly support their conclusions are not supported by the available data on impact cratering. Their hypothesis is based on insufficient and ambiguous data, selective citation, and incomplete comprehension of previous research.  相似文献   

The age of the Saltpan impact crater,South Africa     

Christian Koeberl  Dieter Storzer  Wolf Uwe Reimold 《Meteoritics & planetary science》1994,29(3):374-379

Abstract— The 1.13-km-diameter Pretoria Saltpan impact crater is located about 40 km NNW of Pretoria, South Africa. The crater is situated in 2.05 Ga old Nebo granite of the Bushveld Complex that is locally intruded by about 1.3 Ga old volcanic rocks. In 1988, a borehole was drilled in the center of the crater. At depths >90 m, breccias were found that contained minerals with characteristic shock-metamorphic features, thus confirming the impact origin of the crater. Fragments of impact glass were recovered from the melt breccias and several hundred sub-millimeter-sized glass fragments were subjected to fission track analysis. The measurements were complicated by the inhomogeneous composition of the impact glasses, but analysis of a large number of tracks yielded an age of 220 ± 52 ka for the Saltpan crater.  相似文献   

Shock metamorphism of quartz in nature and experiment: II. Significance in geoscience*     

Richard A. F. Grieve  Falko Langenhorst  Dieter Stffler 《Meteoritics & planetary science》1996,31(1):6-35

Abstract— The occurrence of shock metamorphosed quartz is the most common petrographic criterion for the identification of terrestrial impact structures and lithologies. Its utility is due to its almost ubiquitous occurrence in terrestrial rocks, its overall stability and the fact that a variety of shock metamorphic effects, occurring over a range of shock pressures, have been well documented. These shock effects have been generally duplicated in shock recovery experiments and, thus, serve as shock pressure barometers. After reviewing the general character of shock effects in quartz, the differences between experimental and natural shock events and their potential effects on the shock metamorphism of quartz are explored. The short pulse lengths in experiments may account for the difficulty in synthesizing the high-pressure polymorphs, coesite and stishovite, compared to natural occurrences. In addition, post-shock thermal effects are possible in natural events, which can affect shock altered physical properties, such as refractive index, and cause annealing of shock damage and recrystallization. The orientations of planar microstructures, however, are unaffected by post-impact thermal events, except if quartz is recrystallized, and provide the best natural shock barometer in terms of utility and occurrence. The nature of planar microstructures, particularly planar deformation features (PDFs), is discussed in some detail and a scheme of variations in orientations with shock pressure is provided. The effect of post-impact events on PDFs is generally limited to annealing of the original glass lamellae to produce decorated PDFs, resulting from the exsolution of dissolved water during recrystallization. Basal (0001) PDFs differ from other PDF orientations in that they are multiple, mechanical Brazil twins, which are difficult to detect if not partially annealed and decorated. The occurrence and significance of shock metamorphosed quartz and its other phases (namely, coesite, stishovite, diaplectic glass and lechatelierite) are discussed for terrestrial impact structures in both crystalline (non-porous) and sedimentary (porous) targets. The bulk of past studies have dealt with crystalline targets, where variations in recorded shock pressure in quartz have been used to constrain aspects of the cratering process and to estimate crater dimensions at eroded structures. In sedimentary targets, the effect of pore space results in an inhomogeneous distribution in recorded shock pressure and temperature, which requires a different classification scheme for the variation of recorded shock compared to that in crystalline targets. This is discussed, along with examples of variations in the relative abundances of planar microstructures and their orientations, which are attributed to textural variations in sedimentary target rocks. Examples of the shock metamorphism of quartz in distal ejecta, such as at the K/T boundary, and from nuclear explosions are illustrated and are equivalent to that of known impact structures, except with respect to characteristics that are due to long-term, post-shock thermal effects. Finally, the differences between the deformation and phase transformation of quartz by shock and by endogenic, tectonic and volcanic processes are discussed. We confirm previous conclusions that they are completely dissimilar in character, due to the vastly different physical conditions and time scales typical for shock events, compared to tectonic and volcanic events. Well-characterized and documented shock effects in quartz are unequivocal indicators of impact in the natural environment.  相似文献   

The Chicxulub Scientific Drilling Project (CSDP)     

Jaime Urrutia‐Fucugauchi  Joanna Morgan  Dieter Stffler  Philippe Claeys 《Meteoritics & planetary science》2004,39(6):787-790

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