Defect properties of albite     

Stephan Lowitzer  Dan J. Wilson  Björn Winkler  Victor Milman  Julian D. Gale 《Physics and Chemistry of Minerals》2008,35(3):129-135

Knowledge of the defect properties of Lunar and Mercurian minerals has recently become important, with the advent of models which attempt to explain the formation of the thin exosphere of these celestial bodies. Here, we have calculated the formation energies of sodium and oxygen vacancies in the mineral albite (NaAlSi₃O₈), as well as the Schottky defect energy for the removal of a Na₂O unit. We have employed both the supercell and Mott–Littleton approaches, using Kohn–Sham density functional theory and classical interatomic potential methods. As well as reporting the defect energies and structures, we comment upon the relative merits of the methods used.  相似文献   

A neutron diffraction study of alkali cation migration in montmorillonites     

D. Gournis  A. Lappas  M. A. Karakassides  D. Többens  A. Moukarika 《Physics and Chemistry of Minerals》2008,35(1):49-58

Neutron powder diffraction measurements on lithium and cesium saturated montmorillonite samples before and after heat treatment at 300°C are studied, in order to undertake a complete refinement of crystal structure and unravel the migration mechanism for the interlayer cations of Li or Cs. Rietveld analysis of the corresponding diffraction patterns finds that montmorillonite crystallizes in the C2/m space group with unit cell dimensions consistent with the size of the specific interlayer cation. We show that thermal treatment affects the two types of samples in a different way. This is with respect to their unit cell dimensions and the migration of Li from the 2b to the 2c clay lattice site, in constrast to the Cs positioning which remains effectively unchanged.  相似文献   

How a court, a commissioner and a lobby group brought European transport policy to life in 1985     

Marco te Brömmelstroet  Tobias Nowak 《GeoJournal》2008,72(1-2):33-44

Until the mid-1980s, transport policy was considered by many as one of the least successful domains of the European integration project. However, from the early 1990s onwards, there are clear signs of a single European transport policy, along with the accompanying implementation of infrastructure projects. What is the explanation for such a change in pace? This paper aims to offer insight in these processes by looking at the mechanisms which form and transform this policy domain. To understand the state of a policy domain and its dynamics over time an institutional approach is taken. Two concepts in political science, ‘policy arrangements’ and ‘supranational governance’ are combined and used as a framework to analyse the European transport policy domain. This analysis describes the development of several elements: organisations, rules, the transnational society, power, resources, and the central transport discourse. It demonstrates that all of these elements have developed from an intergovernmental setting towards a more supranational one. This development was slow in the first decennia when European transport policy was rather passive, but it picked up speed in the 1980s and 1990s. In the pivotal year of 1985, pressure from the transnational society resulted in a rapid change of the rules, the resources and the discourse.  相似文献   

Detection of free vertical convection and double-diffusion in groundwater monitoring wells with geophysical borehole measurements     

Susann Berthold  Frank Börner 《Environmental Geology》2008,54(7):1547-1566

Two algorithms for in-situ detection and identification of vertical free convective and double-diffusive flows in groundwater monitoring wells or boreholes are proposed. With one algorithm the causes (driving forces) and with the other one the effects (convection or double-diffusion) of vertical transport processes can be detected based on geophysical borehole measurements in the water column. Five density-driven flow processes are identified: thermal, solutal, and thermosolutal convection leading to an equalization, as well as saltfingers and diffusive layering leading to an intensification of a vertical density gradient. The occurrence of density-driven transport processes could be proven in many groundwater monitoring wells and boreholes; especially shallow sections of boreholes or groundwater monitoring wells are affected dramatically by such vertical flows. Deep sections are also impaired as the critical threshold for the onset of a density-driven flow is considerably low. In monitoring wells or boreholes, several sections with different types of density-driven vertical flows may exist at the same time. Results from experimental investigations in a medium-scale testing facility with high aspect ratio (height/radius = 19) and from numerical modeling of a water column agree well with paramters of in-situ detected convection cells.  相似文献   

National flood discharge mapping in Austria   总被引：5，自引：0，他引：5  

Ralf Merz  Günter Blöschl  Günter Humer 《Natural Hazards》2008,46(1):53-72

This article presents the approach and the results of a study in which 30, 100 and 200 year return period flood discharges were estimated for 26,000 km of Austrian streams. Three guiding principles were adopted: combination of automatic methods and manual assessments by hydrologists to allow speedy processing and account for the local hydrological situation; combination of various sources of information including flood peak samples, rainfall data, runoff coefficients and historical flood data; and involvement of the Hydrographic Services to increase the accuracy and enhance the acceptance of results. The flood discharges for ungauged catchments were estimated by the Top-kriging approach with manual adjustment to the local flood characteristics. The adopted combination approach proved to be very efficient both in terms of the project time required and in terms of the accuracy and acceptability of the estimated flood discharges of given return periods.  相似文献   

Zur Kenntnis der Bauxite des Parnass-Kiona-Gebirges     

György Bardossy  Erwin Mack 《Mineralium Deposita》1967,2(4):334-348

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Buchbesprechungen     

F. Steinhauser  W. Mörikofer  K. Cehak 《Theoretical and Applied Climatology》1967,15(3):313-328

Ohne Zusammenfassung  相似文献   

Buchbesprechungen     

F. Steinhauser  O. Burkard  W. Mörikofer  M. Toperczer 《Meteorology and Atmospheric Physics》1962,13(2):290-304

Ohne Zusammenfassung  相似文献   

Die Intensitätsverteilung der Himmelsstrahlung während der totalen Sonnenfinsternis Am 15. 2. 1961 auf Grund photographischer Messungen     

Dieter Lorenz 《Pure and Applied Geophysics》1962,53(1):143-158

Zusammenfassung Es wird über eine photographische Methode berichtet, die gestattet, die Verteilung der Himmelsstrahlung zu bestimmen. Der Himmel wird mit einer Weitwinkelkamera photographiert und die Aufnahmen werden mit einem Photometer ausgewertet. Über einen Graukeil, der auf das gleiche filmmaterial aufbelichtet und mit den Aufnahmen zusammen entwickelt wird, lassen sich die mit dem Photometer ermittelten Schwärzungswerte in (relative) Intensitätswerte der Himmelsstrahlung umrechnen. Der durch das Photoobjektiv bedingte Helligkeitsabfall von der Bildmitte aus nach den Bildrändern zu wird experimentell ermittelt und als Korrektur an den Meßwerten angebracht. Die Intensitätsverteilung der Himmelsstrahlung während der totalen Sonnenfinsternis am 15. Februar 1961 in Viareggio (Norditalien), am Abend zuvor und am Folgetag wird wiedergegeben und diskutiert. Während der totalen Verfinsterung spiegelt sich insbesondere die Wanderung des Mondschattens relativ zum Beobachtungsort in den Darstellungen wieder. Während der partiellen Verfinsterung ist dagegen die relative Helligkeitsverteilung praktisch die gleiche wie bei unverfinsterter Sonne.

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Summary A photographic method is described which permits to determinate the distribution of the sky radiation. The sky is photographed by a wide angle camera and the resulting pictures are evaluated by a photometer. A photometric step wedge copied on a film of the same type and number is developed together with the pictures. Then the density values measured by the photometer can be transformed into (relative) intensity values of the sky radiation. The decrease in brightness from the centre of the picture to the rim caused by the photographic lens is determined experimentally and is taken into account as a correction to the density values. The distribution of intensity of the sky radiation in Viareggio (North Italy) during the total eclipse of the sun on the 15th of february 1961, on the previous evening and on the following day are shown and discussed. During the total eclipse especially the migration of the moon's shadow in relation to the observation point is clearly defined. During the partial eclipse, however, practically the same relative distribution of sky radiation is found as without eclipse.

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Buchbesprechungen     

Mörikofer  W.  Steinhauser  F.  Untersteiner  N. 《Theoretical and Applied Climatology》1962,11(4):566-570

Ohne Zusammenfassung  相似文献