Chemical Mechanism Development: Laboratory Studies and Model Applications     

Harald Geiger  Ian Barnes  Karl H. Becker  Birger Bohn  Theo Brauers  Birgit Donner  Hans-Peter Dorn  Manfred Elend  Carlos M. Freitas Dinis  Dirk Grossmann  Heinz Hass  Holger Hein  Axel Hoffmann  Lars Hoppe  Frank Hülsemann  Dieter Kley  Björn Klotz  Hans G. Libuda  Tobias Maurer  Djuro Mihelcic  Geert K. Moortgat  Romeo Olariu  Peter Neeb  Dirk Poppe  Lars Ruppert  Claudia G. Sauer  Oleg Shestakov  Holger Somnitz  William R. Stockwell  Lars P. Thüner  Andreas Wahner  Peter Wiesen  Friedhelm Zabel  Reinhard Zellner  Cornelius Zetzsch 《Journal of Atmospheric Chemistry》2002,42(1):323-357

Within the German Tropospheric Research Programme (TFS) numerous kinetic and mechanistic studies on the tropospheric reaction/degradation of the following reactants were carried out: oxygenated VOC, aromatic VOC, biogenic VOC, short-lived intermediates, such as alkoxy and alkylperoxy radicals.At the conception of the projects these selected groups were classes of VOC or intermediates for which the atmospheric oxidation mechanisms were either poorly characterised or totally unknown. The motivation for these studies was the attainment of significant improvements in our understanding of the atmospheric chemical oxidation processes of these compounds, particularly with respect to their involvement in photooxidant formation in the troposphere. In the present paper the types of experimental investigations performed and the results obtained within the various projects are briefly summarised. The major achievements are highlighted and discussed in terms of their contribution to improving our understanding of the chemical processes controlling photosmog formation in the troposphere.  相似文献   

Focal Mechanisms and Stress Field in The Region Vogtland/Western Bohemia     

Wirth  Wolfgang  Plenefisch  Thomas  Klinge  Klaus  Stammler  Klaus  Seidl  Dieter 《Studia Geophysica et Geodaetica》2000,44(2):126-141

We calculated focal mechanisms for 30 of the strongest events (1.5 M _L 3.3) in distinct subregions of Vogtland/Western Bohemia between 1990 and 1998. Our investigations are concerned with events of the swarms near Bad Elster (1991), Haingrün (1991), Nový Kostel (1994 and 1997) and Zwickau (1998), two events from a group of earthquakes near Klingenthal (1997) and eight single events. Seismograms were provided by the digital station networks of the Geophysical Observatory of the University of Munich, the Technical University of Freiberg, the Academy of Sciences of the Czech Republic in Prague, the Masaryk University in Brno and some nearby stations of the German Regional Seismic Network (GRSN). To calculate focal mechanisms two inversion methods were applied. The inferred focal mechanisms do not show a simple, uniform pattern of seismic dislocation. All possible dislocation types – strike-slip, normal and thrust faulting - are represented. The prevailing mechanisms are normal and strike-slip faulting. Considerable differences in the fault plane solutions are noted for the individual subregions as well as in some cases among the individual events of a single swarm. For the Nový Kostel area we succeeded to resolve a change in the orientations of the nodal planes for the two successive swarms of December 1994 and January 1997. Besides this we also observe a change in the mechanisms, namely from strike-slip and normal faulting (December 1994) to strike-slip and thrust faulting (January 1997). Based on the inferred focal mechanisms the stress field was estimated. It turned out, that the dominating stress field in the region Vogtland/Western Bohemia does not substantially differ from the known stress field of West and Central Europe, being characterized by a SE-NW direction of the maximum compressive horizontal stress. We conclude that the seismicity in the Vogtland/Western Bohemia region is not predominantly caused by an independent local stress field, but rather controlled by the dominating stress regime in Central Europe.  相似文献   

Spatial distribution and bonding forms of heavy metals in sediments along the middle course of the River Elbe (km 287ċ390)     

Andrea van der Veen  Corinna Ahlers  Dieter W. Zachmann  Kurt Friese 《洁净——土壤、空气、水》2006,34(3):214-222

Sediments of eight groyne fields along the middle course of the River Elbe (river km 287?390) were geochemically studied. The 78 sediment samples were analysed for pH and grain size distribution. The grain size fraction < 2 μm was used for mineralogical and chemical analysis: semiquantitative clay mineral analysis; total element content (Al, Ca, Fe, K, Mn, Cd, Cr, Cu, Ni, Pb, Zn), total inorganic and organic C, and bonding form fractionation with a six‐step sequential chemical extraction. The latter was performed on selected samples (n = 32). The sediments along the Elbe's course are still contaminated with heavy metals far above the local geogenic background level. An enrichment factor of more than 15 was calculated for zinc. Cr and Ni are the elements with the lowest enrichment. The bonding form analysis of selected heavy metals shows a dominance of relatively immobile bonding forms, e. g. the moderately reducible and the residual fraction, which implies a relative low mobility potential. Only Zn poses a higher potential threat to the environment, since it has a higher percentage of the first three extracted phases: adsorbed, carbonate, and easily reducible fraction.  相似文献   

Field Signatures of the SE-Asian Mega-Tsunami along the West Coast of Thailand Compared to Holocene Paleo-Tsunami from the Atlantic Region     

Dieter Kelletat  Sander R. Scheffers  Anja Scheffers 《Pure and Applied Geophysics》2007,164(2-3):413-431

The Andaman-Sumatra Tsunami of Dec. 26, 2004, was by far the largest tsunami catastrophe in human history. An earthquake of 9 to 9.3 on the Richter scale, the extension of waves over more than 5000 km of ocean and run-ups up to 35 m are its key features. These characteristics suggest significant changes in coastal morphology and high sediment transport rates. A field survey along the west coast of Thailand (Phuket Island, Khao Lak region including some Similan Islands, Nang Pha mangrove areas and Phi Phi Don Islands) seven to nine weeks after the tsunami, however, discovered only small changes in coastal morphology and a limited amount of dislocated sediments, restricted to the lower meters of the tsunami waves. This is in striking contrast to many paleo-tsunami's events of the Atlantic region. Explanations for this discrepancy are sought in: a. Mechanics of the earthquake. A rather slow shock impulse on the water masses over the very long earthquake zone, b. Shallow water in the earthquake zone, and c. Bathymetry of the foreshore zone at the impacted sites. Shallow water west of Thailand has diminished wave energy significantly. The differences in geomorphological and sedimentological signatures of this tsunami compared with many paleo-tsunami worldwide makes it unsuitable to be used as a model for old and future tsunami imprints by an event of this extreme energy and extension.  相似文献   

Isoseismals of the strongest Friuli aftershocks of September 1976     

Vít Kárník  Dana Procházková  Zdeňka Schenková  Julius Drimmel  Dieter Mayer-Rosa  Dragutin Cvijanovic  Vladimir Kuk  Andelka Miloševič  Francesco Giorgetti  Reviewer J. Janský 《Studia Geophysica et Geodaetica》1978,22(4):411-414

Summary Isoseismal maps of the three strongest Friuli aftershocks of September 1976 were compiled using the contributions from European countries within the shaken area. The characteristic features of the macroseismic fields are discussed.  相似文献   

The thermal circulation of the Central Mexican Meseta region within influence of the trade winds     

Prof. Dr. Wilhelm Lauer  Dr. Dieter Klaus 《Theoretical and Applied Climatology》1975,23(4):343-366

  相似文献   

Mitteilungen     

Dr. Dieter Stadler  Karl Schomaker 《Ocean Dynamics》1975,28(3):117-120

  相似文献   

A method to determine crystallization temperatures of hydrated crystals by intracrystalline oxygen isotope effects     

Karl Heinzinger  Dieter Götz 《Earth and Planetary Science Letters》1975,27(2):219-220

The fractionation of the oxygen isotopes between water molecules from different sites in CuSO₄ · 5H₂O has been measured for crystallization temperatures of 25, 40 and 50°C. The temperature dependence found provides a basis for the determination of crystallization temperatures from such intracrystalline oxygen isotope effects; also for hydrated crystals of mineralogical and geological interest. Necessary suppositions for the application of this method are discussed.  相似文献   

Height dependence of diurnal variations of wind velocity and water temperature near the air-sea interface of the tropical Atlantic     

Dieter Prümm 《Boundary-Layer Meteorology》1974,6(1-2):341-347

From measurements during the Atlantic Trade Wind Experiment (ATEX) 1969, amplitudes and phases of the diurnal harmonic water-temperature variation between the sea surface and 50-m depth and of the semi-diurnal wind variation between 1 and 8 m were obtained. If the vertical diffusion of heat in the ocean is thought to be constant, a coefficient of K= 320 cm² s^–1 in the equation of diffusion fits best the observed data in the mixed layer. However, the measurements point to a decrease of K with depth.The height variation of the semi-diurnal zonal wind wave is caused by the influence of eddy viscosity. Our data are well fitted by results of the equation of diffusion, using the assumption of Lettau (1974) that the transfer coefficient of vertical transport of momentum is not only a function of height but also depends on time because of the semi-diurnal variation of surface stress.  相似文献   

Atmospheric Circulation Changes in Response to an Observed Stratospheric Zonal Ozone Anomaly     

Dieter H. W. Peters  Andrea Schneidereit  Marianne Bügelmayer  Christoph Zülicke  Ingo Kirchner 《大气与海洋》2015,53(1):74-88

Abstract

In a sensitivity study, the influence of an observed stratospheric zonal ozone anomaly on the atmospheric circulation was investigated using the Fifth Generation European Centre Hamburg Model (ECHAM5) which is a general circulation model. The model was run from 1960 to 1999 (40 years) with a mean seasonal cycle of zonally symmetric ozone. In order to isolate the induced dynamical influence of the observed zonally asymmetric part of the three-dimensional stratospheric ozone, a second run was performed for the boreal extratropics using prescribed monthly means from the 40-year reanalysis dataset from the European Centre for Medium-range Weather Forecasts (ERA-40). The main findings are the interdecadal westward shift of the polar vortex at about 65°N and a significant increase in the number of stratospheric sudden warmings during the 1980–99 period. Under the action of zonally asymmetric ozone a decrease in the Arctic Oscillation was identified between the mid-1980s and the mid-1990s. The lag correlation between the mean Arctic Oscillation at the surface and the daily stratospheric northern annular mode increased in mid-winter. Furthermore, we examined the influence of the stratospheric zonal ozone anomaly on Rossby wave breaking in the upper troposphere and found a significant westward shift of poleward Rossby wave breaking events over western Europe in the winter. By this we show that the stratospheric zonal ozone anomaly has a strong influence on the tropospheric circulation as a result of enhanced dynamical coupling processes.  相似文献