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91.
92.
Groundwater salinization in the Azores archipelago (Portugal)   总被引:1,自引:1,他引:0  
Groundwater salinization in coastal regions causes severe constraints to water supply and economic losses to society worldwide. In the Azores archipelago, groundwater abstraction in wells drilled in coastal aquifers is very important for water supply, and quality problems have been reported. Therefore, a groundwater chemistry dataset from wells was compiled to study groundwater salinization in these aquifers. Waters are mainly of the Na–Cl type, presenting a slightly acidic to slightly alkaline character, with a pH between 5.63 and 8.50 (median 7.40). Electrical conductivity measurements range from 127 to 9,670 μS/cm (median 862), suggesting highly variable mineralization, with higher values observed on Santa Maria, São Miguel, Pico, Graciosa, and São Jorge islands. The major-ion composition reflects the contribution of seawater to the groundwater compositional evolution, which is essentially explained by seawater intrusion into wells. In many samples, exchange reactions of Na+ + K+ for Ca2+ + Mg2+ are associated with salinization. The seawater fraction in groundwater composition reaches a maximum of 22.5%. These results are extremely challenging to water managers in the Azores because failure to comply with national water quality regulations and with European Union groundwater directive requirements often occurs.  相似文献   
93.
Yael Hillman  Dina Prialnik 《Icarus》2012,221(1):147-159
Upon discovery, in November of 1892, Comet 17P/Holmes was experiencing a very strong explosion, which repeated itself on an even greater scale in October of 2007. Using a numerical scheme, based on mass and energy conservation laws, a model is presented simulating the outbursting nature of Comet 17P/Holmes by regarding the comet as a stratified sphere. The model, adopting input parameters for physical and chemical characteristics, produces output for volatile, water and dust production rates and temperature distribution. Providing the model with known properties of Comet 17P/Holmes, and then filling in the blanks based on properties of other short period comets, allowed the derivation of a specific chemical composition and thermal conductivity that produced a recurring outburst pattern every ~30 years, while within these there is a near-perihelion outburst every ~102 years. The specific composition that generated the desired results, consists of an ice-dust ratio of 0.6/0.4, and mass fractions of 0.015, 0.002 and 0.0005 for CO, CO2 and NH3 accordingly. The effective dust conductivity accompanying this composition is Kd = 0.7 W/(m K). The results are consistent with observations on multiple levels, including the various production rates during outbursts and the time span between near perihelion outbursts.  相似文献   
94.
We have undertaken a study of the common green or orange-brown spots at the surface of rough diamond specimens, which are caused by alpha particles emanating from radioactive sources outside the diamond. Richly coloured haloes represent elevated levels of structural damage, indicated by strong broadening of the main Raman band of diamond, intense strain birefringence, and up-doming of spots due to their extensive volume expansion. Green radio-colouration was analogously generated through the irradiation of diamond with 8.8 MeV helium ions. The generation of readily visible radio-colouration was observed after irradiating diamond with ≥1015 He ions per cm2. The accumulation of such a high number of alpha particles requires irradiation of the diamond from a radioactive source over long periods of time, presumably hundreds of millions of years in many cases. In the samples irradiated with He ions, amorphisation was observed in volume areas where the defect density exceeded 5 × 10?3 Å?3 (or 0.03 dpa; displacements per target atom). In contrast, graphitisation as a direct result of the ion irradiation was not observed. The green colouration transformed to brown at moderate annealing temperatures (here 450 °C). The colour transformation is associated with only partial recovery of the radiation damage. The colour change is mainly due to the destruction of the GR1 centre, explained by trapping of vacancies at A defects to form the H3 centre. An activation energy of ~2.4 ± 0.2 eV was determined for the GR1 reduction. The H3 centre, in turn, causes intense yellowish-green photoluminescence under ultraviolet illumination. Radio-colouration and associated H3 photoluminescence are due to point defects created by the ions irradiated, whereas lattice ionisation is of minor importance. This is concluded from the depth distribution of the colouration and the photoluminescence intensity (which corresponds to the defect density but not the ionisation distribution pattern). The effect of the implanted He ions themselves on the colour and photoluminescence seems to be negligible, as radio-colouration and H3 emission were analogously produced through irradiation of diamond with C ions. The photoluminescence emission becomes observable at extremely low defect densities on the order of 10?6 Å?3 (or 0.000006 dpa) and is suppressed at moderate defect densities of ~5 × 10?4 Å?3 (or ~0.003 dpa). Intensely brown-coloured diamond hence does not show the H3 emission anymore. Anneals up to 1,600 °C has reduced considerably irradiation damage and radio-colouration, but the structural reconstitution of the diamond (and its de-colouration) was still incomplete.  相似文献   
95.
96.
Merk  Rainer  Prialnik  Dina 《Earth, Moon, and Planets》2003,92(1-4):359-374
Early evolution of trans-Neptunian objects,commonly known as Kuiper Belt objects (KBOs),is the result of heating due to radioactive decay, the most important sourcebeing 26Al. Several studiesare reviewed, dealing with the long-termevolution of KBO models, calculatedby means of 1-D numerical codesthat solve the heat and mass balanceequations on a fixed spherically symmetric grid. It is shown that, depending on parameters, the interior may reachquite high temperatures. The modelsthus suggest that KBOs are likely to lose the ices of very volatile species during early evolution; ices of less volatile species are retained in the cold subsurface layer. As the initially amorphous ice isshown to crystallize in the interior, some objects may also lose part of the volatiles trapped in amorphous ice. Generally, the outer layers are far less affected than the inner part, resulting in a stratified composition and altered porosity distribution. It is further shown that the thermal evolution of KBOs cannot be treated separately from their accretional evolution, as the processes occur in parallel. A systematic attempt to calculate accretion and thermal evolution simultaneously is presented, based on a numerical moving grid scheme. The accretion rate is obtained from the solution of the coupled coagulation equations for gravitationally interacting planetesimals. The effect of planetesimal velocities on the accretion scheme is included by a simplified equipartition argument. The time dependent accretion rates serve as input for the numerical solution of the heat transport equation for growing bodies mainly heated by radioactive decay of 26Al, allowing for phase transitions. Calculations carried out over the parameter space [heliocentric distance; final radius; ice fraction] lead to conclusions regarding the structure of KBOs, such as melt fraction, or extent of crystalline ice region.  相似文献   
97.
We study the structure of protoneutron stars within the finite-temperature Brueckner–Bethe–Goldstone many-body theory. If nucleons, hyperons, and leptons are present in the stellar core, we find that neutrino trapping stiffens considerably the equation of state, because hyperon onsets are shifted to larger baryon density. However, the value of the critical mass turns out to be smaller than the “canonical” value 1.44M . We find that the inclusion of a hadron-quark phase transition increases the critical mass and stabilizes it at about 1.5–1.6M .   相似文献   
98.
In Mexico, open dumps that are maintained by the municipality but provide no covering of waste are not uncommon. Further, disposal at these sites is often performed by burning. The aim of this study was to determine the leachate plume from an open dump located in a depositional deltaic environment, with arid climate, low rainfall and where the water table is about 2 m below the surface. The methodology comprised analysis of groundwater monitoring wells and geophysical and geochemical prospecting techniques. The 3D geoelectric interpretation shows a typical area of these depositional environments with low resistive values (10–20 Ω-m) associated with the presence of sands and clays interbedded. However, there is a very low resistivity zone associated with the dump’s impact which reaches values below 5 Ω-m, and it is located where the disposal and burning of wastes occurred. Another zone with values above 16 Ω-m appears as a limit for the advance of the saline. This is interpreted as a sandy lenses area. These sandy lenses with higher porosity transport aquifer’s water. Thus the dump is in direct contact by this conduct with clean groundwater. Piper diagrams constructed with the chemical data analysis reveal that the groundwater in the area corresponds to the chlorinated and/or sulfated sodium type, showing the impact caused by the dump. The monitoring well (NP8, on-site) with the highest dissolved solids content behaves anomalously and belongs to the more conductive zone according to the geoelectric profiles. The subsoil geochemical behavior is influenced by the seasonal water table variations provoking the dissolution of burned and unburned wastes, but the effects of slow flows in the direction of the regional flow are not discarded. Although the most impacted area within the dump is characterized to a depth of 10 m, there is a slow flow in the direction of the regional flow that has been moving pollutants out of the dumpsite during its almost 20 years of operation. The results of this study provide valuable information for the authorities to carry out an appropriate restoration project.  相似文献   
99.
100.
We present a new stellar evolution code and a set of results, demonstrating its capability at calculating full evolutionary tracks for a wide range of masses and metallicities. The code is fast and efficient, and is capable of following through all evolutionary phases, without interruption or human intervention. It is meant to be used also in the context of modelling the evolution of dense stellar systems, for performing live calculations for both normal star models and merger products.
The code is based on a fully implicit, adaptive-grid numerical scheme that solves simultaneously for structure, mesh and chemical composition. Full details are given for the treatment of convection, equation of state, opacity, nuclear reactions and mass loss.
Results of evolutionary calculations are shown for a solar model that matches the characteristics of the present sun to an accuracy of better than 1 per cent; a  1 M  model for a wide range of metallicities; a series of models of stellar Populations I and II, for the mass range 0.25 to  64 M  , followed from pre-main-sequence to a cool white dwarf or core collapse. An initial–final mass relationship is derived and compared with previous studies. Finally, we briefly address the evolution of non-canonical configurations, merger products of low-mass main-sequence parents.  相似文献   
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