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991.
992.
Data on the sedimentology, stratigraphy, palynology, coal petrography and geochemistry of the Santa Rita Coal Basin, Rio Grande do Sul, Brazil, are presented. The investigations were carried out on samples obtained from drill cores of the sedimentary rocks of Tubarão Supergroup, Lower Permian of Paraná Basin.The sequence comprises more than 10 coal layers, three sets of which — SR1, SR2 and SR3 — are correlated with the SB+MB, I1F and I2B+I3B coal seams, respectively, of the Charqueadas Coal Basin, southwest of Santa Rita. The lower, as well as the upper contacts of the sedimentary sequences are transitional and very difficult to trace.The Itararé sequences (basal group) comprise pelites, conglomerates and sandstones. The pelites are the most representative lithologies. The overlying Rio Bonito Formation comprises pelites and coal seams with subordinate para- conglomerates.Palynological analysis has unravelled a rich microfloristic association with a predominance of specimens related to the Infraturma laevigati, apiculati and cingulicavati of the Turma Triletes (Pteridophyta) either in the coal seams or in the associated rocks. Monosaccites, Disaccites and Striatiti (Gymnospermae) are accessory forms in the palynological assemblage. Botryococcus and algae-like elements are less abundant.Comparative studies of cuticular fragments collected from boreholes N3 and P4 showed better preservation and greater concentration in the latter, which may indicate that borehole N3 is located closer to the margin of the swamp.Reflectance measurements ranging from 0.43 Rr% to 0.50 Rr% allow the coal seams to be classified as sub-bituminous B and A, according to the ASTM classification. Microlithotype analyses have shown the predominance of carbominerite, trimacerite and vitrite. Vitrinite is the most prominent maceral group (20–50%), inertinite and exinite are subordinate. The mineral content is about 40%.Results from geochemical analyses, from either coal or associated pelites, show the association of boron and vanadium with the organic matter; gallium is related to the inorganic material.The available sedimentological, palaeontological and petrographical data suggest a paludal environment related to swamps and the coal seams present characteristics of “reed” moor limnotelmatic facies of an authochthonous/hypautochthonous origin.  相似文献   
993.
994.
Data are presented on rare-earth elements (REE) in prefiltered (<450 nm) near-surface and deeper groundwaters and in corresponding particulate matter (>450 nm) from the Osamu Utsumi uranium mine and the Morro do Ferro thorium-REE-deposit. Groundwaters from both sites typically contain between 1–50 μg/l of total REE, but can reach values of up to 160 μg/l in the deepest borehole F4 (U-Mine: 150–415 m). Even higher REE concentrations of up to 29 mg/l were measured in acidic, sulfate-rich near-surface waters of the same site. The chondrite-normalized REE patterns in deeper, more reducing groundwaters and in their corresponding suspended particle fractions are similar to those observed in the bedrock (phonolites), indicating that bedrock leaching and secondary mineral sorption occurred without significant fractionation between these elements, in accordance with the only small variations in the stability constants of the expected REE-sulfate complexes in these waters. Groundwaters from the unsaturated zone of both sites show a very characteristic cerium depletion (less pronounced than that observed in the corresponding suspended particulate fractions), which is most probably related to the oxidation of Ce (III) under the prevailing Eh-conditions of these waters (600 to 800 mV), and to sorption/precipitation reactions of the much less soluble Ce(IV) species. Coarse particulate matter (>450 nm), composed mainly of amorphous ferric hydrous oxides, has a strong capacity for sorption of REE. This is shown by its very high REE concentrations, in some boreholes > 8,000 μg/g (total REE), and by the calculated association ratios Ra (ml/g), which are in the order of 105 to 106. The implications of these findings for the migration behavior of REE in both environments are discussed.  相似文献   
995.
Data are presented on suspended particles and colloids in groundwaters from the Osamu Utsumi mine and the Morro do Ferro analogue study sites. Cross-flow ultrafiltration with membranes of different pore sizes (450 nm to 1.5 nm) was used to prepare colloid concentrates and ultrafiltrates for analyses of major and trace elements and U- and Th-isotopic compositions. Additional characterization of colloidal and particulate material was performed by ESCA, SEM and X-ray diffraction. The results indicate the presence of low concentrations of colloids in these waters (typically < 500 μg/l), composed mainly of iron/organic species. Minor portions of uranium and other trace elements, but significant fractions of the total concentrations of Th and REE in prefiltered waters (< 450 nm) were associated with these colloids.Suspended particles (> 450 nm), also composed mainly of hydrous ferric oxides and humic-like compounds, show the same trend as the colloids with respect to U, Th and REE associations, but elemental concentrations were typically higher by a factor of 1,000 or more. In waters of low pH and with high sulphate content, these associations are considerably lower. Due to the low concentrations of suspended particles in groundwaters from the Osamu Utsumi uranium mine (typically <0.5 mg/l), these particles carry only a minor fraction of U and the REE (<10% of the total concentrations in unfiltered groundwaters), but a significant, usually predominant fraction of Th (30–70%). The suspended particle load in groundwaters from the Morro do Ferro environment is typically higher than in those from the mine by a factor of 5 to 10. This suggests that U, Th and the REE could be transported predominantly by particulate matter. However, these particles and colloids seem to have a low capacity for migration.  相似文献   
996.
The coefficientsC 21 andS 21 are usually considered to be zero in theory (e.g. the axis of earth rotation was used as the principal axis of inertia). However, satellite measurements show thatC 21 as well asS 21 are non-zero, indicating that the axis of rotation of the earth is not the principal axis of inertia. This work determines the angles by which the principal axes of inertia must be rotated in relation to the geocentric coordinate system (where theZ axis coincides with the rotating axis of the earth).  相似文献   
997.
The analytical development of a uniaxial test for the seismic qualification of electrical equipment is presented. This method comprises a single test using a uniaxial excitation having certain minimum intensity applied at the base of the test package in a predetermined optimal direction. It is anticipated that the proposed procedure would be more economical and less time consuming than, but functionally equivalent to, presently employed series of multiaxial tests. The test is shown to be superior to the symmetric tests. The determination of the minimum intensity of the optimal orientation of the base excitation requires a preliminary frequency response test which is a slightly more elaborate version of the sine sweep test presently employed to determine the resonance frequencies of the test package. A simulated test is presented to compare the proposed method with the uncorrelated triaxial test and the symmetric uniaxial test.  相似文献   
998.
Synthetic aluminum-substituted maghemite samples, -(Al y Fe1-y )2O3 with y=0, 0.032, 0.058, 0.084, 0.106 and 0.151 have been studied by Mössbauer spectroscopy at 8 K and in the range 80 K to 475 K at steps of 25 K. The spectra have been analysed as a superposition of two sextets composed of asymmetrical Lorentzians. The A- and B-site isomer shifts were constrained as: A=B-0.12 mm/s. From the temperature dependence of B it was possible to determine the characteristic Mössbauer temperature and the intrinsic shift. Both quantities clearly increase with increasing Al content, at least up to 10 mole%. The temperature dependence of the A-and B-sites hyperfine fields could be satisfactorily reproduced using the molecular-field theory assuming an antiparallel spin configuration. The exchange integrals were found as: J AB =-25 K; J AA =-18 K and J BB = -3 K. The hyperfine fields show a crossing in the vicinity of 300 K as a result of the relatively strong A-A interaction. The Curie temperature for the non-substituted sample was calculated to be 930 K and decreases to 765 K for the sample with 15 mol% Al. The gradual decrease of the saturation value of the A-site hyperfine field with increasing Al substitution and the constancy of this quantity for the B sites, suggest that the Al cations occupy the B sites.Research Director, National Fund for Scientific Research, Belgium  相似文献   
999.
Some classic expansions of the elliptic motion — cosmE and sinmE — in powers of the eccentricity are extended to highly eccentric orbits, 0.6627...<e<1. The new expansions are developed in powers of (ee*), wheree* is a fixed value of the eccentricity. The coefficients are given in terms of the derivatives of Bessel functions with respect to the eccentricity. The expansions have the same radius of convergence (e*) of the extended solution of Kepler's equation, previously derived by the author. Some other simple expansions — (a/r), (r/a), (r/a) sinv, ..., — derived straightforward from the expansions ofE, cosE and sinE are also presented.  相似文献   
1000.
Silva  Adriana V. R.  Gary  Dale E.  White  Stephen M.  Lin  R. P.  de Pater  Imke 《Solar physics》1997,175(1):157-173
We present here the first images of impulsive millimeter emission of a flare. The flare on 1994 August 18 was simultaneously observed at millimeter (86 GHz), microwave (1-18 GHz), and soft and hard X-ray wavelengths. Images of millimeter, soft and hard X-ray emission show the same compact ( 8) source. Both the impulsive and the gradual phases are studied in order to determine the emission mechanisms. During the impulsive phase, the radio spectrum was obtained by combining the millimeter with simultaneous microwave emission. Fitting the nonthermal radio spectra as gyrosynchrotron radiation from a homogeneous source model with constant magnetic field yields the physical properties of the flaring source, that is, total number of electrons, power-law index of the electron energy distribution, and the nonthermal source size. These results are compared to those obtained from the hard X-ray spectra. The energy distribution of the energetic electrons inferred from the hard X-ray and radio spectra is found to follow a double power-law with slope 6–8 below 50 keV and 3–4 above those energies. The temporal evolution of the electron energy spectrum and its implication for the acceleration mechanism are discussed. Comparison of millimeter and soft X-ray emissions during the gradual phase implies that the millimeter emission is free-free radiation from the same hot soft X-ray emitting plasma, and further suggests that the flare source contains multiple temperatures.  相似文献   
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