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131.
Christian Hirt Martin Schmitz Uwe Feldmann-Westendorff Gerhard Wübbena Cord-Hinrich Jahn Günter Seeber 《GPS Solutions》2011,15(2):149-159
The method of geometric-astronomical leveling is presented as a suited technique for the validation of GNSS (Global Navigation
Satellite System) heights. In geometric-astronomical leveling, the ellipsoidal height differences are obtained by combining
conventional spirit leveling and astronomical leveling. Astronomical leveling with recently developed digital zenith camera
systems is capable of providing the geometry of equipotential surfaces of the gravity field accurate to a few 0.1 mm per km.
This is comparable to the accuracy of spirit leveling. Consequently, geometric-astronomical leveling yields accurate ellipsoidal
height differences that may serve as an independent check on GNSS height measurements at local scales. A test was performed
in a local geodetic network near Hanover. GPS observations were simultaneously carried out at five stations over a time span
of 48 h and processed considering state-of-the-art techniques and sophisticated new approaches to reduce station-dependent
errors. The comparison of GPS height differences with those from geometric-astronomical leveling shows a promising agreement
of some millimeters. The experiment indicates the currently achievable accuracy level of GPS height measurements and demonstrates
the practical applicability of the proposed approach for the validation of GNSS height measurements as well as the evaluation
of GNSS height processing strategies. 相似文献
132.
Vitreous materials are quite routinely found in natural settings. Most of them are aluminosilicates, which often occur in large deposits. Considering the geological formations in which naturally occurring vitreous aluminosilicates are found, they have generally remained stable for more than 1 Ma on the earth's surface, even in different geological and climatic environments. These non-crystalline solids played a very important role in the development of ancient human civilizations, long before the introduction of metallic tools. Today, however, the properties of natural glasses are of interest to mankind for completely different reasons. For example, industrial glasses are used today for encapsulating toxic wastes, especially radioactive waste, which remains active for centuries or more, in order to prevent the unwanted transfer of harmful materials to the environment. The chemical compositions of industrially produced glasses are in large part different from the compositions of natural glasses. Little is quantitatively known about the stability of industrial glasses over very long periods of time (>10,000 years). However, the physical and chemical stability of natural aluminosilicate glasses is known to extend over very long periods of time.The advancement of technological design to prevent or at least minimize the melt down of toxic waste during the encapsulation process is currently a major challenge, using glasses of natural chemical composition. Brecciated glass, which is found frequently in natural settings, provides a special clue to the possibility of producing vitreous solids by sintering glass fragments without melting the cullets. It is essential to prevent melting of the cullets because the melt has the potential of chemically reacting with the toxic waste.This paper summarizes the geological, chemical, and physical facts concerning naturally produced glasses, and seeks to establish a recognized database for further research in the domain of understanding the glass-forming processes that occur in nature. Furthermore, the authors hope to stimulate research into the utilization of natural resources that to solve the problem of storing of toxic waste safely.Major and trace element data have been collected over the past 100 years. These data constitute a sufficient basis for the chemical characterization of natural glasses. More information about the major elements is not required, in order to understand the chemical properties of these materials. On the other hand, large gaps in compositional data exist where other related components are concerned: e.g., in the case of “water-species”, with its different forms of bonding in silicates or oxygen (oxygen fugacity), CO2-, sulphur - or hydrocarbons (methane)-, hydrogen-, chlorine-and fluorine-species. All these components have a significant impact on the properties of glasses, even when present only in minor quantities. Glass textures and crystal morphologies reflect the processes of nucleation and crystal growth in a glass-forming matrix during the cooling and reheating cycles which are currently not thoroughly understood. In nature, the processes that led to the formation of vitreous materials are very different from those used in the production of industrial glasses. The different genetic conditions under which glass formation occurs permit differentiation between magmatic and metamorphic vitreous solids. Sedimentary and biogenetic processes also contribute to the formation of non-crystalline solids. 相似文献
133.
Mario Schirmer Frido Reinstorf Sebastian Leschik Andreas Musolff Ronald Krieg Gerhard Strauch John W. Molson Marion Martienssen Kristin Schirmer 《Environmental Earth Sciences》2011,64(3):607-617
Urban areas are the focus of major ecological, social and economical activity. They are thus also prime locations of increasing conflict with regard to water use and water protection. As a direct and/or indirect consequence of urban land use and human activity, urban water systems are frequently polluted with organic contaminants including waste water-born xenobiotics such as pharmaceuticals, personal care products (collectively known as PPCPs) and endocrine-active substances. This study reviews new integrated methodologies including flux calculations as well as chemical investigations for determining the impact of human activities on urban water systems and on processes within the urban watershed. The use of indicator substances, representing different contaminant sources and pathways, integral pumping tests and mass balance approaches are suitable alternatives within these environments. The issues are explored using contaminant mass balance examples from Halle/Saale and Leipzig, Germany. 相似文献
134.
Varved sediments of Lake Yoa (Ounianga Kebir,Chad) reveal progressive drying of the Sahara during the last 6100 years 总被引:1,自引:0,他引:1
Pierre Francus Hans von Suchodoletz Michael Dietze Reik V. Donner Frédéric Bouchard Ann‐Julie Roy Maureen Fagot Stefan Kröpelin 《Sedimentology》2013,60(4):911-934
The sedimentological and geochemical properties of a 7·47 m long laminated sequence from hypersaline Lake Yoa in northern Chad have been investigated, representing a unique, continuous 6100 year long continental record of climate and environmental change in the eastern Central Sahara. These data were used to reconstruct the Mid to Late Holocene history of this currently hyper‐arid region, in order to address the question of whether the Mid Holocene environmental transition from a humid to a dry Sahara was progressive or abrupt. This study involved a suite of analyses, including petrographic and scanning electron microscope examination of thin sections, X‐ray diffraction, X‐radiography, granulometry, loss on ignition and magnetic susceptibility. The potential of micro‐X‐ray fluorescence core scanning was tested at very high resolution. Detailed microscopic investigation revealed the sedimentary processes responsible for the formation of the fine laminations, identified the season during which they were formed, and confirmed their annually rhythmic nature. High‐resolution X‐ray fluorescence core scanning allowed the distinction of each individual lamination over the entire record, opening new perspectives for the study of finely laminated sediment sequences. Geochemical and mineralogical data reveal that, due to decreasing monsoon rainfall combined with continuous and strong evaporation, the hydrologically open and fresh Mid Holocene Lake Yoa slowly evolved into the present‐day hypersaline brine depleted in calcium, which has existed for about the past 1050 years. During the oldest part of the investigated period, Lake Yoa probably contained a permanently stratified lower water column that was nevertheless disrupted relatively frequently by mixing events. Deep‐water anoxia became more stable because of increased salinity‐driven density stratification. In parallel, the sediment grain‐size proxies record a progressive increase of aeolian input in the course of the last 6100 years. Altogether, all geochemical and sedimentological indicators point to a progressive drying of the eastern Central Sahara, strengthening previous conclusions based on palaeoecological indicators. 相似文献
135.
Multiple intertidal bars are common features of wave‐dominated sandy beaches, yet their short‐term (<1 month) and small‐scale (<1 km) morphology and dynamics remain poorly understood. This study describes the morphodynamics of multiple intertidal bars in North Lincolnshire, England, during single and lunar tidal cycles under two contrasting conditions – first when significant wave height was <0·5 m and second when significant wave height frequently exceeded 1 m. The relative importance of swash, surf and shoaling processes in determining morphological change was examined using detailed field observations and a numerical model. The beach featured four intertidal bars and both cross‐shore and longshore bar morphology evolved during the field investigation, particularly under medium to high wave‐energy conditions. Numerical modelling suggests shoaling processes are most common on the seaward two bars under calm wave conditions (Hs < 0·5 m) and that surf zone processes become more common during neap tides and under more energetic (Hs < 0·5 m) conditions. Surf processes dominate the inner two bars, though swash influence increases in a landward direction. The numerical modelling results combined with low tide survey data and high‐resolution morphological measurements strongly suggest changes in the intertidal bar morphology are accomplished by surf zone processes rather than by shoaling wave or swash processes. This is because shoaling waves do not induce significant sediment transport to have any morphological effect, whereas swash action generally does not have enough scope to act as the swash zone is much narrower than the surf zone. It was found, however, that the absolute rate of morphological change under swash action and surfzone processes are of similar magnitudes and that swash action may induce a significant amount of local morphological change when the high tide mark is located on the upper bar, making this process important for bar morphodynamics. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
136.
Methane exchange between coal-bearing basins and the atmosphere: the Ruhr Basin and the Lower Rhine Embayment, Germany 总被引:1,自引:0,他引:1
Thomas Thielemann Andreas Lücke Gerhard H. Schleser Ralf Littke 《Organic Geochemistry》2000,31(12):121
A precise knowledge of methane exchange processes is required to fully understand the recent rise of atmospheric methane concentration. Three of these processes take place at the lithosphere/atmosphere boundary: bacterial consumption of methane and emission of bacterial or thermogenic methane. This study was initiated to quantify these processes on a regional scale in the Ruhr Basin and the Lower Rhine Embayment. Since these areas are subject to bituminous coal and lignite mining, natural and anthropogenically-induced methane exchange processes could be studied. The methane emission and consumption rates and their carbon isotope signal were measured at the lithosphere/atmosphere boundary using flux chambers. On most of the soils studied, methane consumption by bacteria was identified. Thermogenic methane was released only at some of the natural faults examined. In active and abandoned bituminous coal mining areas methane emissions were restricted to small areas, where high emission rates were measured. The carbon isotope composition of methane at natural faults and in mining subsidence troughs was typical of thermogenic methane (−45 to −32 ‰ δ13C). Methane exchange balancing revealed that natural methane emissions from these two basins represent no source of atmospheric importance. However, methane release by upcast mining shafts dominates the methane exchange processes and is by about two orders of magnitude greater than methane consumption by bacterial oxidation in the soils. 相似文献
137.
138.
Electrical conductivity of the earth's crust and upper mantle 总被引:1,自引:0,他引:1
Gerhard Schwarz 《Surveys in Geophysics》1990,11(2-3):133-161
This review summarizes recent results of electrical resistivity studies of the earth's crust and upper mantle. Where available, the data are discussed in the context of further regional geophysical information. Electrical resistivity is very sensitive to a wide range of petrological and physical parameters, e.g., to carbon, fluids, volatiles and enhanced temperatures, making electrical resistivity methods a powerful tool in crust and upper mantle investigations. Yet, the general increase in resistivity data of the crust and mantle has not ended the battle of explanations for anomalous crustal conductivities. 相似文献
139.
岩石样品中低含量铂族元素和锇同位素比值的高精度测量方法 总被引:9,自引:1,他引:9
铂族元素(Os,Ir,Pt,Ru,Rh,Pd)具有强亲铁性和强亲铜性,为一组地球化学性质相近的相容元素,铂族元素包含两个同位素衰变体系(^190Pt-^186Os和^187Re-^187Os)。近年来,铂族元素和Re-Os同位素在研究各类不同地持作用过程中,尤其是在地幔岩石的研究中,作用独特,效果显著。由于地幔岩石的铂族元素含量较低,因此高精度,高灵敏度的分析测试方法的研究就显得十分重要。以往的分析方法(如常规的ICP-MS和中子活化分析方法),对含10^-9-10^012级低含量铂族元素的产品分析精度一般较差(>15%-100%)。所采用的分析流程通常也无法同时获得样品的铂族元素含量和Os同位素比值。本文采用新的熔样方法(HAP-S高温高压釜酸溶法),新的化学流程(溶剂萃取和阴离子交换树脂柱)和新的分析仪器(多接收等离子体质谱MC-ICPMS和负离子热电离质谱N-TIMS)。用同位素稀释法对低含量地幔橄榄岩样品同时测定的铂族元素含量和Os同位素比值,获得了高精度的分析结果。对所分析的地橄榄样品中的铂族元素分配曲线和Os同位素组成的地质意义进行了初步探讨。 相似文献
140.