Late Holocene climatic changes in Tierra del Fuego based on multiproxy analyses of peat deposits     

Dmitri Mauquoy  Maarten Blaauw  Ana Borromei  Frank M. Chambers 《Quaternary Research》2004,61(2):148-158

A ca. 1400-yr record from a raised bog in Isla Grande, Tierra del Fuego, Argentina, registers climate fluctuations, including a Medieval Warm Period, although evidence for the ‘Little Ice Age’ is less clear. Changes in temperature and/or precipitation were inferred from plant macrofossils, pollen, fungal spores, testate amebae, and peat humification. The chronology was established using a ¹⁴C wiggle-matching technique that provides improved age control for at least part of the record compared to other sites. These new data are presented and compared with other lines of evidence from the Southern and Northern Hemispheres. A period of low local water tables occurred in the bog between A.D. 960-1020, which may correspond to the Medieval Warm Period date range of A.D. 950-1045 generated from Northern Hemisphere tree-ring data. A period of cooler and/or wetter conditions was detected between ca. A.D. 1030 and 1100 and a later period of cooler/wetter conditions estimated at ca. cal A.D. 1800-1930, which may correspond to a cooling episode inferred from Law Dome, Antarctica.  相似文献   

Hf isotope compositions and HREE variations in off-craton garnet and spinel peridotite xenoliths from central Asia   总被引：1，自引：0，他引：1  

Dmitri A. Ionov  Janne Blichert-Toft 《Geochimica et cosmochimica acta》2005,69(9):2399-2418

Garnet-facies continental mantle is poorly understood because the vast majority of mantle xenoliths in continental basalts are spinel peridotite. Peridotite xenoliths from Vitim (southern Siberia) and Mongolia provide some of the best samples of garnet and garnet-spinel facies off-craton lithospheric mantle. Garnets in those fertile to moderately depleted lherzolites show a surprisingly broad range of HREE abundances, which poorly correlate with modal and major oxide compositions. Some garnets are zoned and have Lu-rich cores. We argue that these features indicate HREE redistribution after the partial melting, possibly related to spinel-garnet phase transition on isobaric cooling. Most peridotites from Vitim have depleted to ultra-depleted Hf isotope compositions (calculated from mineral analyses: ε_Hf(0) = +17 to +45). HREE-rich garnets have the most radiogenic ε_Hf values and plot above the mantle Hf-Nd isotope array while xenoliths with normal HREE abundances usually fall within or near the depleted end of the MORB field. Model Hf isotope ages for the normal peridotites indicate an origin by ancient partial melt extraction from primitive mantle, most likely in the Proterozoic. By contrast, an HREE-rich peridotite yields a Phanerozoic model age, possibly reflecting overprinting of the ancient partial melting record with that related to a recent enrichment in Lu. Clinopyroxene-garnet Lu-Hf isochron ages (31-84 Ma) are higher than the likely eruption age of the host volcanic rocks (∼16 Ma). Garnet-controlled HREE migration during spinel-garnet and garnet-spinel phase transitions may be one explanation for extremely radiogenic ¹⁷⁶Hf/¹⁷⁷Hf reported for some mantle peridotites; it may also contribute to Hf isotope variations in sub-lithospheric source regions of mantle-derived magmas.  相似文献   

Spinel peridotite xenoliths from the Atsagin-Dush volcano, Dariganga lava plateau, Mongolia: a record of partial melting and cryptic metasomatism in the upper mantle   总被引：14，自引：0，他引：14  

U. Wiechert  Dmitri A. Ionov  Karl Hans Wedepohl 《Contributions to Mineralogy and Petrology》1997,126(4):345-364

Spinel peridotite xenoliths from the Atsagin-Dush volcanic centre, SE Mongolia range from fertile lherzolites to clinopyroxene(cpx)-bearing harzburgites. The cpx-poor peridotites typically contain interstitial fine-grained material and silicate glass and abundant fluid inclusions in minerals, some have large vesicular melt pockets that apparently formed after primary clinopyroxene and spinel. No volatile-bearing minerals (amphibole, phlogopite, apatite, carbonate) have been found in any of the xenoliths. Fifteen peridotite xenoliths have been analysed for major and trace elements; whole-rock Sr isotope compositions and O isotope composition of all minerals were determined for 13 xenoliths. Trace element composition and Sr-Nd isotope compositions were also determined in 11 clinopyroxene and melt pocket separates. Regular variations of major and moderately incompatible trace elements (e.g. heavy-rare-earth elements) in the peridotite series are consistent with its formation as a result of variable degrees of melt extraction from a fertile lherzolite protolith. The Nd isotope compositions of LREE (light-rare-earth elements)-depleted clinopyroxenes indicate an old (≥ 1 billion years) depletion event. Clinopyroxene-rich lherzolites are commonly depleted in LREE and other incompatible trace elements whereas cpx-poor peridotites show metasomatic enrichment that can be related to the abundance of fine-grained interstitial material, glass and fluid inclusions in minerals. The absence of hydrous minerals, ubiquitous CO₂-rich microinclusions in the enriched samples and negative anomalies of Nb, Hf, Zr, and Ti in primitive mantle-normalized trace element patterns of whole rocks and clinopyroxenes indicate that carbonate melts may have been responsible for the metasomatic enrichment. Low Cu and S contents and high δ³⁴S values in whole-rock peridotites could be explained by interaction with oxidized fluids that may have been derived from subducted oceanic crust. The Sr-Nd isotope compositions of LREE-depleted clinopyroxenes plot either in the MORB (mid-ocean-ridge basalt) field or to the right of the mantle array, the latter may be due to enrichment in radiogenic Sr. The LREE-enriched clinopyroxenes and melt pockets plot in the ocean island-basalt field and have Sr-Nd isotope signatures consistent with derivation from a mixture of the DMM (depleted MORB mantle) and EM (enriched mantle) II sources. Received: 18 January 1996 / Accepted: 23 August 1996  相似文献   

The cities of Russia: some recent trends and experience of regional and urban planning     

Dmitri Piterski 《GeoJournal》1997,43(4):385-388

The author examines the recent situation in the development of cities in Russia. Recent trends include a lack of growth and even a decrease in population; extensive economic restructuring; a grave ecological situation in cities; and recent peculiarities in the geopolitical situation and population migration. Due to the new economic, demographic, geopolitical and social situation in Russia it is necessary to re-evaluate the prospects for the development and growth of the big cities in this country. The system of basic documents for regional and city planning in the former USSR and in Russia includes different stages: from The General Scheme for the Settlement Systems of the Country and The Regional Territorial Complex Schemes of Environmental Protection in different regions to the detailed plans for the different parts of cities and towns. The shortcomings of this system and in the process of the realization of the schemes of regional planning and general plans for cities are documented.  相似文献   

Lower crustal xenoliths from Mongolia and their bearing on the nature of the deep crust beneath central Asia     

H. -G. Stosch  D. A. Ionov  I. S. Puchtel  S. J. G. Galer  A. Sharpouri   《Lithos》1995,36(3-4):227-242

Rare lower crustal xenoliths found in Cenozoic alkali basalts from the Tariat region in central Mongolia and the Dariganga Plateau in south-eastern Mongolia are the only direct samples of lower crustal material known so far from central and eastern Asia. They are two-pyroxene granulites, including some garnet granulites, as well as scarce amphibolite-facies rocks. The xenoliths are broadly basaltic to andesitic in bulk chemical composition. Their igneous protoliths appear to represent underplated fractionated liquids and cumulates from such liquids. The xenoliths yield equilibration temperatures of 840 ± 30 °C (Wells, 1977) and, for Tariat garnet granulites only, pressures of 14 ± 1.5 kbar. For central Mongolia, these estimates indicate unusually great depths of origin which, however, are in line with some geophysical models for that area.

Extensive to complete kelyphitisation has affected the garnets where originally present in the Tariat suite; nevertheless, the kelyphite has largerly preserved the major element and REE compositions of the original garnet. Mineral and whole-rock Sm-Nd data obtained for three samples from Tariat and Dariganga indicate, within large errors, low or zero ages. These may either indicate that the rocks are young (Cenozoic) or that ambient temperatures in the lower crust were high enough to permit continuous isotopic equilibration on a mineral-to-mineral scale.  相似文献   

Sulfate-coated dust particles in the free troposphere over Japan   总被引：1，自引：0，他引：1  

Tomoko Kojima  Peter R. Buseck  Yasunobu Iwasaka  Atsushi Matsuki  Dmitri Trochkine   《Atmospheric Research》2006,82(3-4):698

Airborne aerosol collections were performed over Wakasa bay (36°00′N, 135°30′E) in March and Kumano open sea (34°00′N, 136°50′E) and Seto (35°10′N, 137°10′E) in July 2001 at altitudes between 1.0 and 5.8 km. The particles were individually analyzed using transmission electron microscopy (TEM). Relatively large mineral-dust (mostly clay) particles were abundant in the March samples. They also dominated in July in the mid-troposphere higher than 4 km altitude, whereas sea salt and ammonium sulfate were more abundant at lower altitudes. Ca-coated grid samples show many traces of aqueous sulfate droplets. The proportions of former sulfate droplets to the total collected particles apparently increased with increasing relative humidity at the time of sampling. TEM analysis revealed that a significant fraction of these former droplets enclose mineral-dust particles as well as sea salt, soot, and fly ash. Some enclose mixtures of mineral-dust, sea-salt, soot, and fly ash particles. The results provide evidence that mineral dust from the Asian continent could acquire coatings of sulfate while being transported in the free troposphere. The mineral-dust particles probably acquired the sulfate coatings either through heterogeneous uptake of gaseous SO₂ and subsequent oxidation or through coagulation with cloud or fog droplets. The presence of the mixed particles in sulfate droplets also indicates that aggregation of particles of different origins occurred through cloud processing. Such sulfate-coated dust particles would affect cloud formation, precipitation, and chemistry of the free troposphere.  相似文献   

Trace element distribution in peridotite xenoliths from Tok, SE Siberian craton: A record of pervasive, multi-stage metasomatism in shallow refractory mantle     

Dmitri A. Ionov  Gilles Chazot  Claude Merlet 《Geochimica et cosmochimica acta》2006,70(5):1231-1260

Spinel peridotite xenoliths in alkali basalts at Tok, SE Siberian craton range from fertile lherzolites to harzburgites and wehrlites; olivine-rich (70-84%) rocks are dominant. REE patterns in the lherzolites range from nearly flat for fertile rocks (14-17% cpx) to LREE-enriched; the enrichments are positively correlated with modal olivine, consistent with high-permeability of olivine-rich rocks during melt percolation. Clinopyroxene in olivine-rich Tok peridotites typically has convex-upward trace element patterns (La/Nd_PM < 1 and Nd/Yb_PM ? 1), which we consider as evidence for equilibration with evolved silicate liquids (with higher REE and lower Ti contents than in host basalts). Whole-rock patterns of the olivine-rich xenoliths range from convex-upward to LREE-enriched (La/Nd_PM > 1); the LREE-enrichments are positively correlated with phosphorus abundances and are mainly hosted by accessory phosphates and P-rich cryptocrystalline materials. In addition to apatite, some Tok xenoliths contain whitlockite (an anhydrous, halogen-poor and Na-Mg-rich phosphate), which is common in meteorites and lunar rocks, but has not been reported from any terrestrial mantle samples. Some olivine-rich peridotites have generations of clinopyroxene with distinct abundances of Na, LREE, Sr and Zr. The mineralogical and trace element data indicate that the lithospheric mantle section represented by the xenoliths experienced a large-scale metasomatic event produced by upward migration of mafic silicate melts followed by percolation of low-T, alkali-rich melts and fluids. Chromatographic fractionation and fractional crystallisation of the melts close to the percolation front produced strong LREE-enrichments, which are most common in the uppermost mantle and are related to carbonate- and P₂O₅-rich derivatives of the initial melt. Reversal and gradual retreat of the percolation front during thermal relaxation to ambient geotherm (“retrograde” metasomatism) caused local migration and entrapment of small-volume residual fluids and precipitation of volatile-rich accessory minerals. A distinct metasomatic episode, which mainly produced “anhydrous” late-stage interstitial materials was concomitant with the alkali basaltic magmatism, which brought the xenoliths to the surface.  相似文献   

Compositional variations and heterogeneity in fertile lithospheric mantle: peridotite xenoliths in basalts from Tariat,Mongolia     

Dmitri A. Ionov 《Contributions to Mineralogy and Petrology》2007,154(4):455-477

Clinopyroxene-rich, poorly metasomatised spinel lherzolites are rare worldwide but predominate among xenoliths in five Quaternary basaltic eruption centres in Tariat, central Mongolia. High-precision analyses of the most fertile Tariat lherzolites are used to evaluate estimates of primitive mantle compositions; they indicate Mg#_PM = 0.890 while lower Mg# in the mantle are likely related to metasomatic enrichments in iron. Within a 10 × 20 km area, and between ~45 and ≥60 km depth, the sampled xenoliths suggest that the Tariat mantle does not show km-scale chemical heterogeneities and mainly consists of residues after low-degree melt extraction at 1–3 GPa. However, accessory (<1%) amphibole and phlogopite are unevenly distributed beneath the eruption centres. Ca abundances in olivine are controlled by temperature whereas Al and Cr abundances also depend on Cr/Al in coexisting spinel. Comparisons of conventional and high-precision analyses obtained for 30 xenoliths show that high-quality data, in particular for whole-rocks and olivines, are essential to constrain the origin of mantle peridotites. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

Global photometric analysis of Galactic HII regions     

Anastasiia Topchieva  Dmitri Wiebe  Maria S.Kirsanova 《天文和天体物理学研究(英文版)》2018,(8)

Total infrared fluxes are estimated for 99 HII regions around massive stars. The following wavebands have been used for the analysis: 8 and 24 μm, based on data from the Spitzer Space Telescope(IRAC and MIPS, respectively); 70, 160, 250, 350 and 500 μm, based on data from the Herschel Space Observatory(PACS and SPIRE). The estimated fluxes are used to evaluate the polycyclic aromatic hydrocarbon(PAH) mass fraction(qPAH) and the intensity of ultraviolet emission in the studied objects.It is shown that the PAH mass fraction, qPAH, is much lower in these objects than the average Galactic value, implying effective destruction of aromatic particles in HII regions. Estimated radiation field intensities(U) are close to those derived for extragalactic HII complexes. Color indices [F_(24)/F_8], [F_(70)/F_(24)],[F_(160)/F_(24)] and [F_(160)/F_(70)] are compared to criteria proposed to distinguish between regions of ionized hydrogen and planetary nebulae. Also, we relate our results to analogous color indices for extragalactic complexes of ionized hydrogen.  相似文献   

Regional space monitoring of nitrogen dioxide in the troposphere     

D. V. Ionov  Yu. M. Timofeev 《Izvestiya Atmospheric and Oceanic Physics》2009,45(4):434-443

Satellite instruments for the routine global monitoring of NO₂ in the atmosphere—the Global Ozone Monitoring Experiment (GOME) on the ERS-2 satellite, the Scanning Imaging Absorption Spectrometer for Atmospheric Chartography (SCIAMACHY) on the ENVISAT satellite, the Ozone Monitoring Instrument (OMI) on the AURA satellite, and the GOME-2 on the MetOp satellite—are briefly described. It is shown that the error of measuring the NO₂ total column amount (∼10% for the background conditions in the troposphere) substantially increases in regions subject to anthropogenic pollution. Examples of practically using multiyear satellite measurements for the regional monitoring of NO₂ in the troposphere are presented, including mapping the tropospheric NO₂ in Russia, identifying the weekly and annual cycles in tropospheric NO₂ variations for megalopolises (St. Petersburg, Moscow, Paris), and estimating the long-term linear trend in 1995–2007.  相似文献