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71.
72.
 Carbonates of mantle origin have been found in xenoliths from Quaternary basaltic volcanoes in NW Spitsbergen. The carbonates range from dolomite to Mg-bearing calcite and have high Mg-numbers [Mg/(Mg+Fe)=(0.92–0.99)]. In some samples they occur interstitially, e.g. at triple junctions of silicate minerals and appear to be in textural and chemical equilibrium with host lherzolite. Most commonly, however, the carbonates make up fine-grained aggregates together with (Ca,Mg)-rich olivine and (Al,Cr,Ti)-rich clinopyroxene that typically replace spinel, amphibole, and orthopyroxene as well as primary clinopyroxene and olivine. Some lherzolites contain amphibole and apatite that appear to have formed before precipitation of the carbonates. In situ analyses by proton microprobe show very high contents of Sr in the clinopyroxene, carbonates and apatite; the apatite is also very rich in LREE, U, Th, Cl, Br. Disseminated amphibole in carbonate-bearing rocks is very poor in Nb and Zr, in contrast to vein amphibole and mica from carbonate-free rocks that are rich in Nb and Zr. Overall, the Spitsbergen xenoliths provide evidence both for the occurrence of primary carbonate in apparent equilibrium with the spinel lherzolites (regardless of the nature of events that emplaced them) and for the formation of carbonate-bearing pockets consistent with metasomatism by carbonate melts. Calcite and amorphous carbonate-rich materials occur in com- posite carbonate-fluid inclusions, veins and partial melting zones that appear to be related to fluid action in the mantle, heating of the xenoliths during their entrainment in basaltic magma, and to decompression melting of the carbonates. Magnesite is a product of secondary, post-eruption alteration of the xenoliths. Received: 6 October 1995/Accepted: 17 June 1996  相似文献   
73.
The oxygen fugacities of 48 mantle xenoliths from 5 localities in southern Siberia (USSR) and Mongolia have been determined. Ferric iron contents of spinels were measured by 57Fe Mössbauer spectroscopy and oxygen fugacities calculated from spinel-olivineorthopyroxene equilibrium. The samples studied represent the major types of upper mantle lithologies including spinel and garnet peridotites and pyroxenites, fertile and depleted peridotites and anhydrous and metasomatized samples which come from diverse tectonic settings. Extensive geochemical and isotope data are also available for these samples. Oxygen fugacity values for most central Asian xenoliths fall within the range observed in peridotite xenoliths from other continental regions at or slightly below the FMQ buffer. However, xenoliths from the Baikal rift zone are the most reduced among xenoliths for which Mössbauer data on spinels are available. They yield fO2 values similar to those in oceanic peridotites and MORBs, while xenoliths in other occurrences have higher fO2s. In general, the continental lithosperic mantle is more oxidized than MORB-like oceanic mantle. This difference seems to be due to incorporation of oxidized material into some parts of the subcontinental mantle as a result of subduction of oceanic crust. Garnet- and garnet-spinel lherzolites from the Baikal rift area have slightly higher oxygen fugacities than shallower spinel lherzolites. Oxygen fugacity does not appear to be correlated with the degree of depletion of peridotites, and its values in peridotites and pyroxenites are very much alike, suggesting that partial melting (at least at moderate degrees) takes place at essentially the same fO2s that are now recorded by the residual material. Modally (amphibole- and phlogopitebearing) and cryptically metasomatized xenoliths from the Baikal rift zone give the same fO2 values as depleted anhydrous peridotites, suggesting that solid-melt-fluid reactions in the continental rift mantle also take place without substantial change in redox state. This is in contrast to other tectonic environments where metasomatism appears to be associated with oxidation.  相似文献   
74.
A rapid sample preparation procedure is described to determine trace element compositions of peridotites using LA‐ICP‐MS. Peridotite powders were fused with albite in a molybdenum–graphite assembly to obtain homogeneous glasses. Best conditions for the fusion procedure (heating at 1500–1550 °C for 10–15 min with a sample‐to‐flux ratio of 1:2) were constrained with melting experiments on two USGS reference materials, PCC‐1 and DTS‐2B. Mass fractions of first series transition elements, Ba and Pb, in quenched glasses of PCC‐1 and DTS‐2B are consistent with published data within 10% RSD. Three spinel peridotite xenoliths from eastern China were analysed following both our method and conventional solution ICP‐MS. Compared with solution ICP‐MS, the relative deviations of our method for most elements were within 10%, while for the REE, Ta, Pb, Th and U, the relative deviations were within 20%. In particular, volatile elements (e.g., Pb and Zn) are retained in the glass. Compared with conventional wet chemistry digestion, our method is faster. Additional advantages are complete sample fusion, especially useful for samples with acid‐resistant minerals (spinel and rutile), and long‐term conservation of glasses allowing unlimited repeated measurements with microbeam techniques. The same approach can be used for analyses of other mantle rocks, such as eclogites and pyroxenites.  相似文献   
75.
The ring laser gyroscope ??G-Pisa?? has been taking data inside the Virgo interferometer central area with the aim of performing high sensitivity measurements of rotations in the vertical as well as in the horizontal orientation. We discuss the main characteristics of the instrument, describing its mechanical design and presenting the measured sensitivity limit. By applying a simple effective model for the laser gyroscope, we show that the stability of the sensor above 10?s of integration time is mainly limited by backscattering effects. The horizontal rotation rate signal is also compared with the signals recorded by the Virgo environmental monitoring system and by a biaxial mechanical tiltmeter rigidly fixed on top of the gyrolaser mounting frame.  相似文献   
76.
Sea surface height anomalies observed by satellites in 1992–2010 are combined with monthly climatologies of temperature and salinity to estimate circulation in the southern Bering Sea. The estimated surface and deep currents are consistent with independent velocity observations by surface drifters and Argo floats parked at 1,000?m. Analysis reveals 1–3-Sv interannual transport variations of the major currents with typical intra-annual variability of 3–7?Sv. On the seasonal scale, the Alaskan Stream transport is well correlated with the Kamchatka (0.81), Near Strait (0.53) and the Bering Slope (0.37) currents. Lagged correlations reveal a gradual increase of the time the lags between the transports of the Alaskan Stream, the Bering Slope Current and the Kamchatka Current, supporting the concept that the Bering Sea basin is ventilated by the waters carried by the Alaskan Stream south of the Aleutian Arc and by the flow through the Near Strait. Correlations of the Bering Sea currents with the Bering Strait transport are dominated by the seasonal cycle. On the interannual time scale, significant negative correlations are diagnosed between the Near Strait transport and the Bering Slope and Alaskan Stream currents. Substantial correlations are also diagnosed between the eddy kinetic energy and Pacific Decadal Oscillation.  相似文献   
77.
Partial melting and reactive melt transport may change the composition, microstructures, and physical properties of mantle rocks. Here we explore the relations between deformation and reactive melt transport through detailed microstructural analysis and crystallographic orientation measurements in spinel peridotite xenoliths that sample the shallow lithospheric mantle beneath the southeastern rim of the Siberian craton. These xenoliths have coarse-grained, annealed microstructures and show petrographic and chemical evidence for variable degrees of reaction with silicate melts and fluids, notably Fe-enrichment and crystallization of metasomatic clinopyroxene (cpx). Olivine crystal preferred orientations (CPO) range from strong to weak. [010]-fiber patterns, characterized by a point concentration of [010] normal to the foliation and by dispersion of [100] in the foliation plane with a weak maximum parallel to the lineation, predominate relative to the [100]-fiber patterns usually observed in lithospheric mantle xenoliths and peridotite massifs. Variations in olivine CPO patterns or intensity are not correlated with modal and chemical compositions. This, together with the analysis of microstructures, suggests that reactive melt percolation postdated both deformation and static recrystallization. Preferential crystallization of metasomatic cpx along (010) olivine grain boundaries points to an influence of the preexisting deformation fabrics on melt transport, with higher permeability along the foliation. Similarity between orthopyroxene (opx) and cpx CPO suggests that cpx orientations may be inherited from those of opx during melt-rock reaction. As observed in previous studies, reactive melt transport does not weaken olivine CPO and seismic anisotropy in the upper mantle, except in melt accumulation domains. In contrast, recovery and selective grain growth during static recrystallization may lead to development of [010]-fiber olivine CPO and, if foliations are horizontal, result in apparent isotropy for vertically propagating SKS waves, but strong anisotropy for horizontally propagating surface waves.  相似文献   
78.
Izvestiya, Atmospheric and Oceanic Physics - The results of 5-year (2013–2017) measurements of organic (OC) and elemental (EC) carbon aerosol fractions observed at the atmospheric monitoring...  相似文献   
79.
Izvestiya, Atmospheric and Oceanic Physics - Total column amounts (TCAs) of various climatically important atmospheric gases have been determined in Peterhof for the period between 2009 and 2018....  相似文献   
80.
Borehole guided waves that are excited by explosive sources outside of the borehole are important for interpreting borehole seismic surveys and for rock property inversion workflows. Borehole seismograms are typically modelled using numerical methods of wave propagation. In order to benchmark such numerical algorithms and partially to interpret the results of modelling, an analytical methodology is presented here to compute synthetic seismograms. The specific setup is a wavefield emanating from a monopole point source embedded within a homogeneous elastic medium that interacts with a fluid‐filled borehole and a free surface. The methodology assumes that the wavelength of the seismic signal is much larger than the borehole radius. In this paper, it is supposed that there is no poroelastic coupling between the formation and the borehole. The total wavefield solution consists of P, PP, and PS body waves; the surface Rayleigh wave; and the low‐frequency guided Stoneley wave (often referred as the tube wave) within the borehole. In its turn, the tube wave consists of the partial responses generated by the incident P‐wave and the reflected PP and PS body waves at the borehole mouth and by the Rayleigh wave, as well as the Stoneley wave eigenmode. The Mach tube wave, which is a conic tube wave, additionally appears in the Mach cone in a slow formation with the tube‐wave velocity greater than the shear one. The conditions of appearance of the Mach wave in a slow formation are formulated. It is shown that the amplitude of the Mach tube wave strongly depends on Poisson's ratio of the slow surrounding formation. The amplitude of the Mach tube wave exponentially decreases when the source depth grows for weakly compressible elastic media with Poisson's ratio close to 0.5 (i.e., saturated clays and saturated clay soils). Asymptotic expressions are also provided to compute the wavefield amplitudes for different combinations of source depth and source‐well offset. These expressions allow an approximate solution of the wavefield to be computed much faster (within several seconds) than directly computing the implicit integrals arising from the analytical formulation.  相似文献   
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