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The Neupert effect is the name given to the correlation observed in many flares between the time-integrated microwave and hard X-ray emissions and the soft X-ray emission light curve. We have used hard X-ray data from the Hard X-Ray Burst Spectrometer (HXRBS) on the Solar Maximum Mission (SMM) and soft X-ray data from the detector on GOES to determine what fraction of all events show this correlation and how the correlation changes from the impulsive to the gradual phase. We have found that of 66 HXRBS events observed in 1980 with a peak rate of > 1000 counts s-1, 58 (80%) showed good correlations with peaks in the GOES time derivative plot corresponding to peaks in the hard X-ray (HXR) plots to within ±20 s. In 20 of these good-correlation cases (30%), the soft X-ray (SXR) time derivative stays high after the HXR emission has decreased suggesting that the later emissions result from energy release in a loop already affected by the initial energy release. In 8 of the 13 flares that showed poor correlation, the SXR time derivative shows no peak corresponding to the initial HXR impulsive peak that has structure on a time scale of 1 s. This suggests that in these events the initial impulsive energy release results primarily in electron acceleration, and that the secondary plasma heating from the accelerated electrons contributes relatively little compared to the more gradual plasma heating already taking place at the same time. The more gradually varying events, commonly referred to as type C flares, tend to show poorer correlation between the SXR time derivative and the HXR time profile. Of 26 GOES X1 or greater flares recorded between 1980 and 1989 with HXR peaks lasting over 10 rain, 13 (50%) showed poor correlation with the gradual HXR peaks either not registering at all in the SXR time derivative plots or showing up as very broad peaks. In one case, on 1981 April 26, the SXR time derivative peak was delayed by 13 rain. Only 17 (65%) of the 26 X-flares had an earlier, impulsive component and of those, 12 (71%) showed good correlation between the impulsive peaks. 相似文献
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The authenticity of hydroxychlorophyll derivatives in sediments has been verified by subjecting pure chlorophyll preparations to the extraction method used for sediments. Model studies of chlorophyll autoxidation reveal hydroxychlorophyll as the major product formed in the presence of hydrogen peroxide. Its stability to further oxidation implies that hydroxychlorophyll derivatives are not precursors of aetioporphyrins and are more likely to produce cycloalkanoporphyrins via the processes of diagenesis. The occurrence of 132-hydroxyphaeophytin a throughout a sediment core from Loch Ness confirms it to be a widespread chlorophyll oxidation product formed during early diagenesis. Profiles of hydroxychlorophyll derivatives in a sediment core from an Antarctic lake demonstrate their potential for use as markers of oxidation processes in palaeoenvironmental assessment. 相似文献
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The analysis presented below suggests that the following equation models monodentate binding to negatively-charged oxygen donor atoms with no distinction between phenolic, carboxylic or inorganic hydroxide functional groups: log KML = αO log KHL + βO; where KML is the metal-ligand formation constant, KHL is the corresponding proton-ligand formation constant, and αO and βO are termed the Irving-Rossotti slope and intercept, respectively. Linear free energy relationships (LFERs) of this type are presented for 24 different metal ions complexing to negatively-charged oxygen donor atoms. Ligands selected for use in LFERs meet the following criteria: (i) they contain negatively-charged oxygen donor atoms (e.g., carboxylic acids and phenols), (ii) they are capable of only monodentate binding to metal ions, (iii) steric hindrances are not expected to influence the extent of metal-ligand binding, and (iv) the negatively-charged oxygen donor atom is the only functional group that imparts charge. The intercept of all LFERs was nearly zero for all metal ions investigated (βO ≈ 0). The magnitude of αO indicates the relative preference of metal binding to negatively-charged oxygen donor atoms and to the proton. Values of αO can be used in QSARs (quantitative structure activity relationships) to estimate metal-NOM (natural organic matter) binding constants employed in the Windermere Humic Aqueous Model (WHAM) version V. 相似文献
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Attempts to quantify the numbers of migrants generated by changes in climate have commonly been calculated by projecting physical climate changes on an exposed population. These studies generally make simplistic assumptions about the response of an individual to variations in climate. However, empirical evidence of environmentally induced migration does not support such a structural approach and recognises that migration decisions are usually both multi-causal and shaped through individual agency. As such, agent-based modelling offers a robust method to simulate the autonomous decision making process relating to environmental migration. The Theory of Planned Behaviour provides a basis that can be used to effectively break down the reasoning process relating to the development of a behavioural intention. By developing an agent-based model of environmental migration for Burkina Faso from the basis of a combination of such theoretical developments and data analysis we further investigate the role of the environment in the decision to migrate using scenarios of future demographic, economic, social, political, and climate change in a dryland context. We find that in terms of climate change, it can be seen that that change to a drier environment produces the largest total and international migration fluxes when combined with changes to inclusive and connected social and political governance. While the lowest international migration flows are produced under a wetter climate with exclusive and diverse governance scenarios. In summary this paper illustrates how agent-based models incorporating the Theory of Planned Behaviour can be used to project evidence based future changes in migration in response to future demographic, economic social and climate change. 相似文献
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Permeability, k, and porosity, φ, were measured in mixtures of fine, medium, and coarse sand, where the volume fraction of each of the three components was systematically varied. The k was modeled well by the Kozeny‐Carman equation for three‐component mixtures by using a representative grain size parameter, d, computed by averaging the grain diameters of components recursively, with averaging methods based on whether finer components exist in sufficient volume to fill the pores within coarser components. The φ was modeled well by using linear interpolation with piecewise‐planar models. We explored the use of differing numbers of piecewise‐planar elements in the model, and illustrate the trade‐off between the increased accuracy and the increased data requirements that both come from adding more elements. The k model is a function of both d and φ, but more sensitive to d. The k model gave results consistent with measured values when computed using either measured φ values, or values from any of the φ models. 相似文献
40.
We demonstrate evidence that past composite based studies centred around the onset of Forbush decrease (FD) events may have improperly isolated the maximal galactic cosmic ray (GCR) decrease associated with the FD events. After an adjustment of the composite to account for such shortcomings we find indications of anomalous cloud cover decreases (of around 3%) located in the upper levels of the troposphere at high southern latitudes. These cloud changes are detectable after latitudinal averaging, suggesting the possibility of a second order relationship between the rate of GCR flux and cloud cover in this region. The maximal cloud change is observed in advance of the maximal GCR decrease; this implies that if the observed cloud changes bear a causal relationship to the rate of GCR flux, then cloud properties may be sensitive to changes in GCR conditions rather than the maximal deviations themselves. 相似文献