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111.
We observe a 1.3 kg C/net GJ variation of carbon emissions due to inertinite abundance in some commercially available bituminous coal. An additional 0.9 kg C/net GJ variation of carbon emissions is expected due to the extent of coalification through the bituminous rank stages. Each percentage of sulfur in bituminous coal reduces carbon emissions by about 0.08 kg C/net GJ. Other factors, such as mineral content, liptinite abundance and individual macerals, also influence carbon emissions, but their quantitative effect is less certain.The large range of carbon emissions within the bituminous rank class suggests that rank-specific carbon emission factors are provincial rather than global. Although carbon emission factors that better account for this provincial variation might be calculated, we show that the data used for this calculation may vary according to the methods used to sample and analyze coal. Provincial variation of carbon emissions and the use of different coal sampling and analytical methods complicate the verification of national greenhouse gas inventories.  相似文献   
112.
Summary Synoptic/diagnostic case studies have increasingly come to rely on numerical simulations started from some initial state after which the model generated fields receive no further information from observed data. The purpose of this paper is to demonstrate the use of a dynamic data assimilation technique based on nudging to create a dynamically consistent high-resolution four-dimensional data set that can be used for synoptic diagnostic studies. The nudging technique is applied in the Goddard Mesoscale Atmospheric Simulation System (GMASS) using the 3-h radiosonde data collected during GALE IOP 1. A unique aspect of this application is nudging toward data analyses for which the areal coverage shifts with time. One of the two nudging simulations assimilates surface pressure in addition to the temperature, mixing ratio, and wind components. The nudging values are determined by linear interpolation between 3-h observation times. Assuming a linear variation of the assimilated value in time leads to estimates of the nudging coefficients which take into account the accuracy of the observations.Both nudging simulations are more accurate in terms of S hand root-mean-square error (RMSE) scores than a control sunulation without successive initialization. The nudging simulation with surface pressure is more accurate than the nudging simulation without surface pressure assimilation for this case. The simulation with surface pressure nudging captures the surface cyclogenesis and the associated strong rise-fall couplet in the 500 hPa height field. It also exhibits the strongest ageostrophic flow and exit region vertical circulation associated with a jet streak on the western side of the intensifying upper-level trough.The data sets made possible by the dynamic assimilation/ simulation cycles are dynamically consistent, have high spatial and temporal resolution and are ideally suited for diagnostic studies. Examples presented include the evolution of the ageostrophic flow associated with the exit region of an upper-level jet propagating toward the base of an intensifying trough with increasing cyclonic curvature of the flow. The nudging simulation with surface pressure provides the resolution and accuracy required to depict the rapid transformation (within a 12-h period) of the exit region ageostrophic flow from predominantly cross contour to along contour as the jet streak approaches the base of the trough.With 19 Figures  相似文献   
113.
The rate of climatic change estimated from the gradient of signals recorded in lake sediments may be erroneous if post-depositional perturbations are overlooked. A smear out of a pulse signal, over a variable thickness of core section, due to physical or biological mixing, is a well known phenomena. Much less attention is paid to a possible overestimation of the rate of change when a part of record is missing due to an erosion event. In this paper we show a few examples of recent lake sediment perturbations and the resulting distortions in the time scale, as documented by short-lived radionuclides.Contribution to Clima Locarno — Past and Present Climate Dynamics; Conference September 1990, Swiss Academy of Sciences — National Climate Program  相似文献   
114.
Large volume water samples were taken at Porte du Scex and Bouveret at the mouth of the Upper Rhone River as it enters Lake Geneva. Samples were taken every two weeks during 1982 up until August 1983. Water samples were analyzed for total phosphorus (TP), and soluble reactive phosphorus (SRP) and were centrifuged in the field using a continuous flow centrifuge to recover the suspended solids following sieving at 63 µm. The < 63 µm solids were analyzed for total particulate phosphorus (TPP), organic phosphorus (OP), apatite phosphorus (AP) and non apatite inorganic phosphorus (NAIP). The > 63 µm were similarly analyzed and the weight of total solids in both size fractions recorded. Results were compared throughout the period of record to the hydrograph situated at Porte de Scex. The annual cycle of the Rhone can be divided into a low turbidity, low flow winter period (SED 1) and high flow, high turbidity summer season designated (SED 2). Turbidity is well related to discharge. The > 63 µm sediment is mobilized at 200 m3 s–1 and thereafter increases in concert with, though at a faster rate than, the < 63 µm fraction. The coarse fraction contains significant quantities of phosphorus and in 1982 accounted for 26% of the TPP loading. OP and NAIP are higher in SED 1 than in SED 2 though AP remains constant throughout the year. OP is believed to be driven primarily from point sources whereas NAIP, in addition to point sources, has secondary sources in spring and summer due to sheet erosion from the agricultural soils of the valley. Loadings of phosphorus were calculated by four methods which showed internal consistency though they were higher than previous estimates. Bioavailable phosphorus (BAP) was estimated to account for some 20% of the total phosphorus loading of some 1500 tonnes; BAP is here taken to be the sum of SRP and NAIP and is that portion of the phosphorus load believed to be available to generate phytoplankton growth.  相似文献   
115.
Thirty two cores were collected from Lake Geneva sediments along one longitudinal and eight transverse profiles. Rates of sedimentation determined by137Cs vary from 0.01 to 1.86 g cm−2 y−1. The average deposition rates in coastal and slope areas amounts to 0.37 g cm−2 y−1 in the Upper Lake (Grand Lac) and 0.12 g cm−2 y−1 in the Lower Lake (Petit Lac). In the deep basins, average rates of 0.13 and 0.05 g cm−2 y−1 were found for the Grand Lac and Petit Lac, respectively. The estimated mass of sediment deposited yearly outside of the principal deltas and turbidity current depositional areas is about 1.0 million tons (about 13% of the estimated total river load). One turbidite is clearly identified in the deepest, central lake area. There is little variation of surface sediment texture (mean grain size about 8–9μm) with the exception of delta areas. Since the beginning of the twentieth century, both carbonate and organic matter have increased as a result of lake eutrophication.  相似文献   
116.
117.
Sedimentation rates were determined by210Pb in three sediment cores from the main basin of Lake Constance. Rates vary from 0.094 to 0.133 g cm?2y?1, in agreement with previous determinations. A constant radionuclide flux (CR) model reveals long-term, quasi-synchronous fluctuations of sedimentation rate on the basin-wide scale. On average, the rate of sedimentation remains much the same from the beginning of this century indicating little effect of human activity in the watershed on fine-silt sediment supply. The anthropogenic fluxes of Zn, Pb, and Cd in the three cores are compared and the application of210Pb as a heavy metal tracer in Lake Constance is examined. It seems to be a very good tracer for Pb, moderately good for Zn and Cu, and not useful for Cd.  相似文献   
118.
119.
In modern geoscience, understanding the climate depends on the information about the oceans. Covering two-thirds of the Earth, oceans play an important role. Oceanic phenomena are, for example: oceanic circulation; water exchanges between atmosphere, land, and ocean; or temporal changes of the total water volume. All these features require new methods in constructive approximation, since they are regionally bounded and not globally observable. This article deals with a new and alternative method of handling data with locally supported basis functions, modeling them in a multiscale scheme involving a wavelet approximation and presenting the main results for the dynamic topography and the geostrophic flow, e.g., in the Northern Atlantic. Further, it is demonstrated that compressional rates of the occurring wavelet transforms can be achieved by using of locally supported wavelets and investigating the signal distribution within different frequency bands.  相似文献   
120.
Microbial activity has the potential to alter all cultural heritage in mining and metallurgy, due to metal mobilization by leaching. This communication shows the consequences of the bioleaching ability of two natural enrichments on copper slag samples from a historic ore smelting site in Sangerhausen (Mansfeld, Südharz, Saxony-Anhalt, Germany). Enrichment cultures gained from mine drainage were dominated by either the iron and sulfur-oxidizing Acidithiobacillus ferrivorans, or by the iron-oxidizing Leptospirillum. During 35 days of bioleaching in media containing copper slag pulp, inoculated with these enrichments, the change in pH and solubilized metal concentrations of the systems were monitored. Both bacterial strains were completely different from each other in their pattern of pH variation and rates of metal solubilization. The maximum removal of Cu (1725 mg/l) and Zn (715 mg/l) from copper slag substrate was achieved with enrichment culture of A. ferrivorans SCUT-1. However, maximum Mn (207 mg/l), Pb (86 mg/l), and Ni (75 mg/l) removal was observed with enrichment culture of Leptospirillum strain YQP-1. Implications for metal mobilization along with alteration of artifacts from not only historic mining areas but also aspects of decontamination and remediation are discussed.  相似文献   
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