Studies on the flotation of sulphides. II. The effect of urea on the flotation of zinc sulphide     

G. Brill  J.M. Pratt 《International Journal of Mineral Processing》1979,6(3):193-205

The effect of three hydrophilic non-electrolytes on the flotation of ZnS has been studied using a Fuerstenau microflotation cell. The rate of flotation increases with increasing concentrations of urea(OC(NH₂)₂), but is unaffected by thiourea and slightly decreased by sucrose. This effect of urea was observed with all samples of ZnS (synthetic and natural) studied, is unaffected by extensive purification of the urea and by the presence or absence of O₂, and is reversed by dilution. Urea also increases the rate of flotation (in a Partridge and Smith cell) in the absence of frother. Surface tension measurements showed the absence of detectable concentrations of surfactants in the urea. The presence of urea has no effect on the rate of sedimentation (i.e. on the degree of aggregation) of ZnS or on the volume of water carried over during flotation. It is suggested that the effect of urea is (at least in part) to increase the rate of bubble-particle attachment by modifying the structure of water.  相似文献   

Chemistry and mineralogy of ochreous sediments in a constructed mine drainage wetland     

W.B Gagliano  M.R Brill  F.S Jones 《Geochimica et cosmochimica acta》2004,68(9):2119-2128

The objective of this study was to examine the mineralogy and geochemical stability of ochreous sediments accumulated in a compost wetland constructed in 1990 for acid mine drainage treatment. Intact sediment cores were collected in 1996 and 2000 from an area that had accumulated 33 cm of ochre. Solids and pore waters were subsequently separated by centrifugation and analyzed using conventional methods, including X-ray diffraction, infrared spectroscopy, scanning electron microscopy, and wet chemical techniques. The solid phase had an average Fe content of 585 g/kg and was predominantly schwertmannite [Fe ₈O₈(OH)_4.8(SO₄)_1.6] in the upper portion of the sediment column, but transformed to goethite (α-FeOOH) with depth. The rate of transformation was calculated to be 30 mol/m³/yr in the initial 6 yr of sedimentation as compared to 10 mol/m³/yr for the 4-yr period from 1996 to 2000. Pore water composition was affected by this mineral transformation through production of acidity and the release of Fe and SO₄. These results demonstrate that the sediment column was not a static environment. In addition, the transformation of schwertmannite to goethite, which has been observed under laboratory conditions, also occurs in natural systems.  相似文献   

Argon and CO₂ on the race track in silicate melts: A tool for the development of a CO₂ speciation and diffusion model     

Marcus Nowak  Dominik Schreen 《Geochimica et cosmochimica acta》2004,68(24):5127-5138

We have analysed the kinetics of Argon and CO₂ diffusion in simplified iron free rhyolitic to hawaiitic melts using the diffusion couple technique. The concentration distance profiles of Ar and CO₂ were measured with electron microprobe analysis and Fourier Transform Infrared Spectroscopy, respectively. Error functions were fitted to the symmetrical concentration distance profiles to extract the diffusion coefficients.In the temperature range 1373 to 1773 K the activation energies for Ar diffusion range from 169 ± 20 to 257 ± 62 kJ mol⁻¹. Ar diffusivity increases exponentially with the degree of depolymerisation. In contrast, the mobility of total CO₂, that is identical to Ar mobility in rhyolitic melt, keeps constant with changing bulk composition from rhyolite to hawaiite. CO₂ speciation at 1623 K and 500 MPa was modeled for the range of compositions studied using the diffusion data of Ar and total CO₂ in combination with network former diffusion calculated from viscosity data. Within error this model is in excellent agreement with CO₂ speciation data extrapolated from temperatures near the glass transition temperature for dacitic melt composition. This model shows that even in highly depolymerised hawaiitic and tholeiitic melts molecular CO₂ is a stable species and contributes 70 to 80% to the total CO₂ diffusion, respectively.  相似文献   

Transport of the environmental radionuclides in an alpine watershed     

J. Dominik  D. Burrus  J.-P. Vernet 《Earth and Planetary Science Letters》1987,84(2-3)

The radionuclides¹³⁷Cs,²¹⁰Pb and⁷Be have been examined in the alpine Rhoˆne watershed (Switzerland) during a period of two years in order to evaluate their usefulness as tracers of the removal and transport rate of top-soil particles and particle-reactive contaminants of atmospheric origin. The specific activities of the radionuclides in fluvial suspension show a distinct seasonal pattern which depends on the hydrologic regime of the stream and the sources of the suspended matter. Input-output budgets based on the atmospheric deposition and fluvial removal of three radionuclides in the alpine Rhoˆne watershed are used to estimate their erosional residence times. The simplest one box model yields mean residence times of about 800 and 1400 years for¹³⁷Cs and²¹⁰Pb, respectively. The removal rate of short-lived⁷Be suggests that a part of the watershed (0.6–2.3% of the total surface) is exposed to a rapid erosion, in which the mean residence time of the radionuclides is in the range of 1–220 days. This has little influence on the calculated residence time of¹³⁷Cs but increases the estimated residence time of²¹⁰Pb in soil to over 1800 years. The use of²¹⁰Pb-⁷Be pair in fluvial output may be very helpful in the assessment of the impact of atmospheric pollutants on the water quality in rivers and lakes.  相似文献   

Changing moisture sources over the last 330,000 years in Northern Oman from fluid-inclusion evidence in speleothems     

Dominik Fleitmann  Stephen J BurnsUlrich Neff  Augusto ManginiAlbert Matter 《Quaternary Research》2003,60(2):223-232

Speleothems from Hoti Cave in northern Oman provide a record of continental pluvial periods over the last 330,000 yr. Periods of rapid speleothem deposition occurred from 6000 to 10,500, 78,000 to 82,000, 120,000 to 135,000, 180,000 to 200,000, and 300,000 to 330,000 yr ago, with little or no growth during the intervening periods. During each of these five pluvial periods, δD values of water extracted from speleothem fluid inclusions (δD_FI) are between −60 and −20‰ (VSMOW) and δ¹⁸O values of speleothem calcite (δ¹⁸O_C) are between −12 and −4‰ to (VPDB). These values are much more negative than modern rainfall (for δD) or modern stalagmites (for δ¹⁸O). Previous work on the isotopic composition of rainfall in Oman has shown that northern and southern moisture sources are isotopically distinct. Combined measurements of the δD values of fluid-inclusion water with calculated δ¹⁸O values from peak interglacial speleothems indicate that groundwater was predominantly recharged by the southern (Indian Ocean) moisture source, when the monsoon rainfall belt moved northward and reached Northern Oman during each of these periods.  相似文献   

New insights into Southern Caucasian glacial–interglacial climate conditions inferred from Quaternary gastropod fauna     

Christiane Richter  Daniel Wolf  Frank Walther  Stefan Meng  Lilit Sahakyan  Hayk Hovakimyan  Tilmann Wolpert  Markus Fuchs  Dominik Faust 《第四纪科学杂志》2020,35(5):634-649

In the present study, we performed gastropod analyses on loess–palaeosol sequences from northeast Armenia (Southern Caucasia) covering at least three glacial–interglacial cycles. The elaborated ecostratigraphy shows significant patterns of species composition related to the succession of pedocomplexes and loess, respectively. Pedocomplexes included species that can be associated with high-grass to forest-steppe biomes, indicating increased humidity for these sections compared to the loess layers. In contrast, loess layers that relate to glacial periods are associated with gastropod species of semidesert environments with shrub- and shortgrass-steppes, indicating semiarid to arid conditions. Furthermore, the loess deposits do not show any evidence for cold-adapted gastropod species. Therefore, we suggest that average July temperatures in the study area were above 10 °C, even during periods of loess deposition. Consequently, we propose that the limiting factor for tree growth during glacial periods was aridity, rather than temperature. In addition, we observe environmental differences between the various glacial times, with our results indicating a trend towards steadily increasing aridity in Southern Caucasia across the Middle to Late Pleistocene.  相似文献   

Origin and post-glacial evolution of surface cracks: A case study from the area of the Last Glaciation,north-eastern Poland     

Tomasz Karasiewicz  Anna Hrynowiecka  Piotr Weckwerth  Lucyna Tobojko  Dominik Pawłowski  Wojciech Wysota  Arkadiusz Krawiec  Michał Dąbrowski 《地球表面变化过程与地形》2024,49(2):525-548

The analysis of LiDAR-based digital elevation models revealed the existence of groups of longitudinal fractures in the ground in northern Poland at the limit of the ice sheet's extent during its last maximum. Our research on the closed elongated depressions (CEDs) of the Jedwabno test field (Szuć site, north-east Poland) focuses on explaining their origins and their post-glacial history. This region was covered by an ice sheet and glacitectonically active during the Vistulian, and at least some surface fractures are possible witnesses to this activity. Using geomorphological mapping, sedimentological and geophysical research, we assumed it was related that the origin of these features here is associated with groundwater migration at the end of the Vistulian glaciation or later when groundwater flow intensified due to a rapid climate warming that caused permafrost to melt. The thawing of permafrost caused to transition from continuous permafrost to discontinuous, which in turn created groundwater flow that was probably responsible for the development of the surface cracks (fractures). Radiocarbon, palaeobiological (pollen, Cladocera) and geochemical studies allowed for an estimation of the formation time of these unique surface cracks in the Older Dryas. Prevailing conditions were also reconstructed for the later dynamic changes of the end of the Late Vistulian glaciation and in the Late Holocene until the Subatlantic Period (Megalayan stage). The surface cracks with steep slopes, despite their small area, are extraordinary sedimentation traps that have, in a special way, retained an almost complete record of the environmental and climate changes of the Late Glacial. There are sedimentological gaps in the Holocene, especially after the Preboreal (old part of the Greenlandian Stage), caused by changes in water levels, aeolian processes and human activity.  相似文献   

Magnetic aggregation: II. Laboratory and microgravity experiments     

Henrik Nübold  Torsten Poppe  Carsten Dominik 《Icarus》2003,165(1):195-214

In a previous publication (Dominik and Nübold, 2002, Icarus 157, 173-186), we presented analytical expressions and theoretical considerations concerning preplanetary dust aggregation with magnetized grains in the solar nebula. The present work is dedicated to the experimental study of magnetic aggregation in a ground-based laboratory as well as under microgravity conditions on parabolic flights. We conducted aggregation experiments with dust analogues in order to study the temporal evolution and the structural outcome of grain growth processes dominated by or comprising exclusively magnetic grains. Within aggregation times ranging from a couple of seconds to a few minutes only, formation of huge chain-like and/or web-like dust aggregates was observed. After aggregate retrieval we were able to study the sizes and structures of the aggregates in great detail. We established the fractal dimension of the aggregates as D_fs=1.20±0.05 for single chains and D_fc=1.50±0.21 for inter-connected web-like structures. This is considerably lower than for non-magnetic grain growth. The dynamic exponent z for the mass increase with time according to t^z was found to be z=2.7 from in-situ video images of the microgravity aggregation runs. The results are compared with the theoretical considerations presented earlier as well as with previous experimental work on the same and on related topics, respectively.  相似文献   

On the large-angle anomalies of the microwave sky   总被引：1，自引：0，他引：1  

Craig J. Copi  Dragan Huterer  Dominik J. Schwarz  Glenn D. Starkman 《Monthly notices of the Royal Astronomical Society》2006,367(1):79-102

  相似文献   

Revealing stellar brightness profiles by means of microlensing fold caustics     

M. Dominik 《Monthly notices of the Royal Astronomical Society》2004,353(1):118-132

  相似文献