Reliable Determination of Ge in Solid Environmental Samples Using a Chemical Preparation Procedure Developed for Si Isotopes and ICP‐MS Analysis          下载免费PDF全文

Camille Delvigne  Bernard Angeletti  Abel Guihou  Isabelle Basile‐Doelsch  Jean‐Dominique Meunier 《Geostandards and Geoanalytical Research》2018,42(1):139-149

Germanium (Ge) exists at trace levels in the Earth's crust and is a powerful geochemical tracer of the silicon (Si) cycle. This study proposes a simple and reliable method for determining Ge contents in environmental samples using ICP‐MS. As Si and Ge have very similar chemical properties, we investigated the applicability of the chemical preparation procedure developed for Si isotopes for the determination of Ge in environmental samples. Advantages of this procedure are as follows: (a) efficient removal of the matrix and main interferences affecting Ge determinations by ICP‐MS, (b) a low limit of detection (6 ng l^?1), (c) relative repeatability of approximately 3% obtained on ⁷⁴Ge and (d) robustness and accuracy based on agreement within errors with the published Ge values for rock reference materials (BHVO‐2, AGV‐2 and BCR‐2). This procedure allowed revision of the Ge values of three soil reference materials (1.67 ± 0.09 μg g^?1, 2.41 ± 0.18 μg g^?1, 1.89 ± 0.10 μg g^?1 for GBW 07401, GBW 07404 and GBW 07407, respectively) and proposal of a value for the plant reference material ERM‐CD281 (70 ± 3 μg g^?1). This method provides a convenient procedure for determining Ge mass fractions in environmental samples and opens the possibility of coupling two tracers of the Si biogeochemical cycle with a single measurement procedure.  相似文献   

Significant Li isotope fractionation in geochemically evolved rare element-bearing pegmatites from the Little Nahanni Pegmatite Group,NWT, Canada     

Elspeth M. Barnes  Dominique Weis  Lee A. Groat 《Lithos》2012

Lithium isotope signatures of whole rock pegmatite samples and mineral separates from the rare element-bearing Little Nahanni Pegmatite Group, NWT, and whole rock samples from nearby granitic intrusions were measured. Correlation of the Li isotopic values from the pegmatite dikes with whole rock trace element geochemistry, mineralogy and primary textural evidence reflect mechanisms of Li isotopic fractionation during pegmatite formation. The heavier δ⁷Li signatures within the broad range measured from whole rock LNPG samples (? 0.94‰ to + 11.36‰) are related to the consolidation of the final ~ 15% melt fraction of a volatile-rich peraluminous magma in the late stages of magmatic fractionation. Rock-forming minerals (quartz, albite, spodumene and mica) display δ⁷Li signatures that indicate consolidation of the dikes under variable, non-equilibrium conditions. Lithium isotope signatures of relatively cool, highly evolved peraluminous magmas reflect the build-up of fluxes (e.g., H₂O and F) and provide a qualitative assessment of the state of mineral/melt chemical equilibrium.  相似文献   

From oblique accretion to transpression in the evolution of the Altaid collage: New insights from West Junggar,northwestern China     

Flavien Choulet  Michel Faure  Dominique Cluzel  Yan Chen  Wei Lin  Bo Wang 《Gondwana Research》2012,21(2-3):530-547

Along active margins, tectonic features that develop in response to plate convergence are strongly controlled by subduction zone geometry. In West Junggar, a segment of the giant Palaeozoic collage of Central Asia, the West Karamay Unit represents a Carboniferous accretionary complex composed of fore-arc sedimentary rocks and ophiolitic mélanges. The occurrence of quasi-synchronous upright folds and folds with vertical axes suggests that transpression plays a significant role in the tectonic evolution of the West Junggar. Latest Carboniferous (ca. 300 Ma) alkaline plutons postdate this early phase of folding, which was synchronous with accretion of the Carboniferous complex. The Permian Dalabute sinistral fault overprints Carboniferous ductile shearing and split the West Karamay Unit ca. 100 km apart. Oblique convergence may have been provoked by the buckling of the Kazakh orocline and relative rotations between its segments. Depending upon the shape of the convergence zone, either upright folds and fold with vertical axes, or alternatively, strike–slip brittle faults developed in response to strain partitioning. Sinistral brittle faulting may account for the lateral imbrication of units in the West Junggar accretionary complex.  相似文献   

The Late Eocene and Late Miocene fronts of the Atlas Belt in eastern Maghreb: integration in the geodynamic evolution of the Mediterranean Domain     

Sami Khomsi  Dominique Frizon de Lamotte  Mourad Bédir  Oussema Echihi 《Arabian Journal of Geosciences》2016,9(15):650

Regional cross sections at the scale of the eastern Maghreb based on subsurface and field data allow presenting the structural styles related to the Middle-Late Eocene compressional events. The structural cross sections depict that the Late Eocene front of the Atlas Belt extends far through the Northern Africa plate margin comparatively to the Late Miocene front cropping out in the Eastern Tunisian Atlas. The sections allow proposing a new subsurface front for the Atlas belt encompassing a large part of the Pelagian-Sirt basins. The consequences of this particular configuration are discussed at the scale of the south Tethys margin and replaced in the frame of the geodynamic evolution of the Mediterranean Domain.  相似文献   

Fluxes of selected trace metals from the Seine estuary to the eastern English Channel during the period August 1994 to July 1995     

Jean-Franois Chiffoleau  Dominique Auger  Emmanuelle Chartier 《Continental Shelf Research》1999,19(15-16)

Two sampling cruises conducted in the Seine estuary (France) under low-water and flood conditions produced high resolution profiles for dissolved cadmium, lead, copper, zinc and nickel concentrations versus salinity. The distribution of dissolved trace metals differed depending on hydrologic conditions, partly because of the dilution of upstream inputs during flood periods. Daily fluxes of these dissolved trace metals were estimated for the two sampling periods (September 1994 and February 1995) by extrapolating the dilution lines observed in higher salinity waters to salinity=0 and then multiplying the effective freshwater concentrations thus obtained by the corresponding freshwater flow. Several procedures were subsequently applied to deduce each daily flux for the year studied from data for these two periods. A consensus was found among these procedures, allowing the determination of net fluxes of dissolved trace metals with a precision of 20–35%. The net fluxes thus estimated were 4 T yr⁻¹ for Cd, 4 T yr⁻¹ for Pb, 40 T yr⁻¹ for Cu, 130 T yr⁻¹ for Zn and 50 T yr⁻¹ for Ni.  相似文献   

Reconstructing fluvial incision rates based on palaeo-water tables in chalk karst networks along the Seine valley (Normandy,France)     

Carole Nehme  Andrew Farrant  Daniel Ballesteros  Dominique Todisco  Joel Rodet  Diana Sahy  J. Michael Grappone  Jean-Claude Staigre  Damase Mouralis 《地球表面变化过程与地形》2020,45(8):1860-1876

Quantifying rates of river incision and continental uplift over Quaternary timescales offer the potential for modelling landscape change due to tectonic and climatic forcing. In many areas, river terraces form datable archives that help constrain the timing and rate of valley incision. However, old river terraces, with high-level deposits, are prone to weathering and often lack datable material. Where valleys are incised through karst areas, caves and sediments can be used to reconstruct the landscape evolution because they can record the elevation of palaeo-water tables and contain preserved datable material. In Normandy (N. France), the Seine River is entrenched into an extensive karstic chalk plateau. Previous estimates of valley incision were hampered by the lack of preserved datable fluvial terraces. A stack of abandoned phreatic cave passages preserved in the sides of the Seine valley can be used to reconstruct the landscape evolution of the region. Combining geomorphological observations, palaeomagnetic and U/Th dating of speleothem and sediments in eight caves along the Lower Seine valley, we have constructed a new age model for cave development and valley incision. Six identified cave levels up to ∼100 m a.s.l. were formed during the last ~1 Ma, coeval with the incision of the Seine River. Passage morphologies indicate that the caves formed in a shallow phreatic/epiphreatic setting, modified by sediment influxes. The valley's maximum age is constrained by the occurrence of late Pliocene marine sand. Palaeomagnetic dating of cave infills indicates that the highest-level caves were being infilled prior to 1.1 Ma. The evidence from the studied caves, complemented by fluvial terrace sequences, indicates that rapid river incision occurred during marine isotope stage (MIS) 28 to 20 (0.8–1 Ma), with maximal rates of ~0.30 m ka⁻¹, dropping to ~0.08 m ka⁻¹ between MIS 20–11 (0.8–0.4 Ma) and 0.05 m ka⁻¹ from MIS 5 to the present time. © 2020 John Wiley & Sons, Ltd.  相似文献   

Depositional controls on a hypertidal barrier-spit system architecture and evolution,Pointe du Banc spit,north-western France     

Mikkel Fruergaard  Bernadette Tessier  Clément Poirier  Dominique Mouazé  Pierre Weill  Suzanne Noël 《Sedimentology》2020,67(1):502-533

Physical stratigraphy, architecture and evolution of barrier systems in hypertidal environments (tidal range above 6 m) are understudied, and depositional controls are poorly understood compared with wave-dominated barrier systems and barrier spits in microtidal, mesotidal and macrotidal settings. Based on vibracores, ground-penetrating radar, radiocarbon and optically stimulated luminescence age data, the formation and evolution of the hypertidal barrier system of Pointe du Banc, north-western France has been reconstructed. The study shows that the barrier spit has a complex composite sedimentary architecture consisting of wave-dominated and tide-dominated sedimentary bodies. A morpho-sedimentary model is presented that demonstrates how barrier-spit progradation resulting from littoral drift was the main manner of spit elongation, whereas sediment convergence caused by landward migration of swash bars and seaward migration of tidal dunes caused the spit terminus to grow in height and width. These results suggest that long-term accretion rates varied considerably in response to changes in sediment supply. Variations in storminess together with the large-scale topography of the coast controlled the sediment supply and thus the evolution of the barrier system during latest Holocene. Despite architectural complexity, hypertidal barrier systems preserve records of past climate changes.  相似文献   

Immobilization of Cr(VI) by sulphate green rust and sulphidized nanoscale zerovalent iron in sand media: batch and column studies     

Digiacomo  Flavia  Tobler  Dominique J.  Held  Thomas  Neumann  Thomas 《Geochemical transactions》2020,21(1):1-22

The study presented in this work emerged as a result of a multiyear regional geochemical survey based on low-density topsoil sampling and the ensuing geochemical atlas of Croatia. This study focuses on the Dinaric part of Croatia to expound the underlying mechanisms controlling the mobilities and variations in distribution of potentially harmful elements as observed from different environmental angles. Although serious environmental degradation of the vulnerable karst soil landscapes was expected to occur chiefly through the accumulation of various heavy metals, the most acute threat materialized through the soil acidification (Al-toxicity) affecting the entire Dinaric karst area. This picture surfaced from the analysis of all three investigated discriminant function models employing the abovementioned environmental criteria selected autonomously with respect to the evaluated soil geochemistry, namely, geologic setting, regional placement and land use. These models are presented by not only the characteristic discriminant-function diagrams but also a set of appropriate mathematically derived geochemical maps disclosing the allocations of potential threats to the karst soil landscapes posed by soil acidity.  相似文献   

Seasonal changes in phosphatase activities in Toulon Bay (France)     

Boge G  Jean N  Jamet JL  Jamet D  Richard S 《Marine environmental research》2006,61(1):1-18

We studied the characteristics of the phosphatase activity (Km and Vmax) in total seawater and in particulate material of the three main plankton classes (0.25-5, 5-90 and >90 microm) in a coastal marine ecosystem of Toulon Bay (French Mediterranean Sea). The measurement of the hydrolysis of sodium paranitrophenylphosphate (pNPP), a substrate of phosphatase, revealed low and high affinity components in unfiltered seawater and in particulate matter. In unfiltered seawater, the low affinity activity was predominant from October to March during phytoplankton development. The high affinity activity dominated from April to June and was significantly correlated with the bacterial abundances. The phosphatase behaviour in the particulate material differs from that in the unfiltered seawater. The activity of the three particulate classes was generally much lower than that of unfiltered seawater, particularly the low affinity activity. The >90 microm size fraction consisted in greater part of zooplankton. In this size class, the activity (nmol l(-1) h(-1)) of the low affinity component was predominant from May to August, when the abundance of the larvae of copepods (copepodites) was highest. Its high specific activity (Activity/Protein concentration as nmol l(-1) h(-1) microg(-1)) was particularly elevated during this period. The 5-90 microm fraction consisted of phytoplankton cells, especially Dinoflagellates. Between September and January, the activity (nmol l(-1) h(-1)) of this size class was mostly supported by the low affinity component. The specific activity (nmol l(-1) h(-1) microg(-1)) of the high affinity component was highest in June and August. No significant correlation was found between phosphatase activities and chlorophyll a or total cell abundance. In return temporary relationships with specific taxa exist in particular with Ceratium spp., Gymnodinium spp. and Protoperidinium spp. The contribution of the 0.25-5 microm size class exceeded rarely 20% of the total particulate activity. Between June and August, high specific activities (nmol l(-1) h(-1) microg(-1)) were observed for its high affinity component. In autumn, strong rainfall increased the phosphate and nitrate concentrations and led to a drop in salinity, which probably explains the low phosphatase activities (nmol l(-1) h(-1)) and cell densities observed during this period.  相似文献   

Exploring the past through lynchet landscapes in the Vosges Mountains and the Lorraine Plateau (France)     

Benjamin Keller  Robin Vincent  Dominique Schwartz  Damien Ertlen 《Geoarchaeology》2024,39(3):300-319

Lynchets are ridges formed by erosion and sediment accumulation downstream of agricultural plots and offer valuable insights into past agricultural activity. These microtopographies cover vast areas and serve as indicators of historical changes in land use. As a result, their ubiquity across Europe makes them particularly interesting. In this study, we propose a geoarchaeological approach to analyze six lynchets, four in the Vosges Mountains and two on the Lorraine Plateau (France). The lynchets can be considered soil archives with no stratigraphic organization or chronological sequence from bottom to top, making it difficult to determine the age of the lynchets and identify changes in land use over time. To this end, we propose the analysis of historical and geo-historical archives combined with the “pedosedimentary” archives of lynchets through charcoal identification and dating combined with near-infrared spectroscopy to determine the age, vegetation, and past land use changes associated with lynchet landscapes. By combining these multiple data sources, we are better able to show the chronological development of these ancient agricultural systems and uncover valuable information on landscape history. Charcoal dating suggests a higher frequency of fires from the Middle Ages. The dating aligns with the regional dynamics of anthropogenic fires, indicating a potential use of fire for cultural purposes. We also demonstrate the difficulty of extrapolating the dating of a lynchet to the entire lynchet system. Our results highlight the difficulties of interpreting the formation and dating of lynchets and the lynchet system on the sole basis of charcoal analysis. However, we highlight the value of applying pedoanthracology to lynchets to determine the dynamics of land use change in former fields.  相似文献