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341.
342.
Speculations on the nature and cause of mantle heterogeneity   总被引:8,自引:0,他引:8  
Hotspots and hotspot tracks are on, or start on, preexisting lithospheric features such as fracture zones, transform faults, continental sutures, ridges and former plate boundaries. Volcanism is often associated with these features and with regions of lithospheric extension, thinning, and preexisting thin spots. The lithosphere clearly controls the location of volcanism. The nature of the volcanism and the presence of ‘melting anomalies’ or ‘hotspots’, however, reflect the intrinsic chemical and lithologic heterogeneity of the upper mantle. Melting anomalies—shallow regions of ridges, volcanic chains, flood basalts, radial dike swarms—and continental breakup are frequently attributed to the impingement of deep mantle thermal plumes on the base of the lithosphere. The heat required for volcanism in the plume hypothesis is from the core. Alternatively, mantle fertility and melting point, ponding and focusing, and edge effects, i.e., plate tectonic and near-surface phenomena, may control the volumes and rates of magmatism. The heat required is from the mantle, mainly from internal heating and conduction into recycled fragments. The magnitude of magmatism appears to reflect the fertility, not the absolute temperature, of the asthenosphere. I attribute the chemical heterogeneity of the upper mantle to subduction of young plates, aseismic ridges and seamount chains, and to delamination of the lower continental crust. These heterogeneities eventually warm up past the melting point of eclogite and become buoyant low-velocity diapirs that undergo further adiabatic decompression melting as they encounter thin or spreading regions of the lithosphere. The heat required for the melting of cold subducted and delaminated material is extracted from the essentially infinite heat reservoir of the mantle, not the core. Melting in the upper mantle does not requires the instability of a deep thermal boundary layer or high absolute temperatures. Melts from recycled oceanic crust, and seamounts—and possibly even plateaus—pond beneath the lithosphere, particularly beneath basins and suture zones, with locally thin, weak or young lithosphere. The characteristic scale lengths—150 to 600 km—of variations in bathymetry and magma chemistry, and the variable productivity of volcanic chains, may reflect compositional heterogeneity of the asthenosphere, not the scales of mantle convection or the spacing of hot plumes. High-frequency seismic waves, scattering, coda studies and deep reflection profiles are needed to detect the kind of chemical heterogeneity and small-scale layering predicted from the recycling hypothesis.  相似文献   
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A sequence of ultramafic rocks in the Lac Guyer Archean greenstone belt exhibit brecciated flow tops, pillow structures, and spinifex textures testifying to their volcanic origin. Massive, spinifex-textured and differentiated flows in the sequence have the chemical characteristics of peridotitic komatiite, with MgO ranging from 19–25 wt.%. Associated pillowed flows have compositions that straddle the conventional boundary between komatiite and komatiitic basalt with MgO contents ranging from 16 to 19 wt.% MgO and are best termed pyroxenitic komatiites. Unlike other komatiitic occurrences, the peridotitic and pyroxenitic komatiites at Lac Guyer constitute a continuous chemical spectrum with no evidence of population minimum near 18 wt.% MgO. The contrasting behaviour of highly compatible elements, such as Ni and Cr, versus incompatible elements, such as Zr, indicate that this compositional spectrum was produced by a variation in the extent of partial melting (10–40%) of a garnet lherzolite source in the Archean mantle. The pyroxenitic komatiites represent liquids produced during lower (10–20%) degrees of melting during which garnet remained in the mantle residue. However, a change in slope in the distribution of Zr vs. Y between the pyroxenitic and the peridotitic komatiites indicates that garnet was completely consumed at the more extensive degrees of melting which produced the peridotitic komatiites. The Lac Guyer volcanic rocks display a population minimum at 15 wt.% MgO separating komatiitic magmas whose compositions are controlled by partial melting from basalts whose composition is controlled by crystal fractionation. The population minimum near 18 wt.% MgO which is taken as the boundary between komatiite and komatiitic basalt may have a similar origin.  相似文献   
345.
The sulfur concentration in silicate melts at sulfide saturation (SCSS) was experimentally investigated in a temperature range from 1150 to 1450 °C and a pressure range from 500 MPa to 1 GPa in a piston-cylinder apparatus. The investigated melt compositions varied from rhyolitic to basaltic and water concentrations varied from 0 to ∼9 wt%. All experiments were saturated with FeS melt or pyrrhotite crystals. Temperature was confirmed to have a positive effect on the SCSS. Experimental oxygen fugacities were either near the carbon-carbon monoxide buffer or one log unit above the nickel-nickel oxide buffer, and found to positively affect the SCSS. Combining our results with data from the literature we constructed a model to predict the SCSS in melts ranging in composition from komatiitic to rhyolitic, with water concentrations from 0 to 9 wt%, at pressures from 1 bar to 9 GPa and oxygen fugacities between ∼2 log units below the fayalite-magnetite-quartz buffer to ∼2 log units above it. The coefficients were obtained by multiple linear regression of experimental data and the best model found for the prediction of the SCSS is:
  相似文献   
346.
Natural resource planning at all scales demands methods for assessing the impacts of resource development and use, and in particular it requires standardized methods that yield robust and unbiased results. Building from existing probabilistic methods for assessing the volumes of energy and mineral resources, we provide an algorithm for consistent, reproducible, quantitative assessment of resource development impacts. The approach combines probabilistic input data with Monte Carlo statistical methods to determine probabilistic outputs that convey the uncertainties inherent in the data. For example, one can utilize our algorithm to combine data from a natural gas resource assessment with maps of sage grouse leks and piñon-juniper woodlands in the same area to estimate possible future habitat impacts due to possible future gas development. As another example: one could combine geochemical data and maps of lynx habitat with data from a mineral deposit assessment in the same area to determine possible future mining impacts on water resources and lynx habitat. The approach can be applied to a broad range of positive and negative resource development impacts, such as water quantity or quality, economic benefits, or air quality, limited only by the availability of necessary input data and quantified relationships among geologic resources, development alternatives, and impacts. The framework enables quantitative evaluation of the trade-offs inherent in resource management decision-making, including cumulative impacts, to address societal concerns and policy aspects of resource development.  相似文献   
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The relationships between the major terrestrial volatile reservoirs are explored by resolving the different components in the Xe isotope signatures displayed by Harding County and Caroline CO2 well gases and mid-ocean ridge basalts (MORB). For the nonradiogenic isotopes, there is evidence for the presence of components enhanced in the light 124–128Xe/130Xe isotope ratios with respect to the terrestrial atmosphere. The observation of small but significant elevations of these ratios in the MORB and well gas reservoirs means that the nonradiogenic Xe in the atmosphere cannot be the primordial base composition in the mantle. The presence of solar-like components, for example U–Xe, solar wind Xe, or both, is required.For radiogenic Xe generated by decay of short-lived 129I and 244Pu, the 129Xerad/136Xe244 ratios are indistinguishable in MORB and the present atmosphere, but differ by approximately an order of magnitude between the MORB and well gas sources. Correspondence of these ratios in MORB and the atmosphere within the relatively small uncertainties found here significantly constrains possible mantle degassing scenarios. The widely held view that substantial early degassing of 129Xerad and 136Xe244 from the MORB reservoir to the atmosphere occurred and then ended while 129I was still alive is incompatible with equal ratios, and so is not a possible explanation for observed elevations of 129Xe/130Xe in MORB compared to the atmosphere. Detailed degassing chronologies constructed from the isotopic composition of MORB Xe are therefore questionable.If the present estimate for the uranium/iodine ratio in the bulk silicate Earth (BSE) is taken to apply to all interior volatile reservoirs, the differing 129Xerad/136Xe244 ratios in MORB and the well gases point to two episodes of major mantle degassing, presumably driven by giant impacts, respectively  20–50 Ma and  95–100 Ma after solar system origin assuming current values for initial 129I/127I and 244Pu/238U. The earlier time range, for degassing of the well gas source, spans Hf–W calculations for the timing of a moon-forming impact. The second, later impact further outgassed the upper mantle and MORB source. A single event that degassed both the MORB and gas well reservoirs at the time of the moon-forming collision would be compatible with their distinct 129Xerad/136Xe244 ratios only if the post-impact iodine abundance in the MORB reservoir was about an order of magnitude lower than current estimates. In either case, such late dates require large early losses of noble gases, so that initial inventories acquired throughout the Earth must have been substantially higher.The much larger 129Xerad/136Xe244 ratio in the well gases compared to MORB requires that these two Xe components evolve from separate interior reservoirs that have been effectively isolated from each other for most of the age of the planet, but are now seen within the upper mantle. These reservoirs have maintained distinct Xe isotope signatures despite having similar Ne isotope compositions that reflect similar degassing histories. This suggests that the light noble gas and radiogenic Xe isotopes are decoupled, with separate long-term storage of the latter. However, without data on the extent of heterogeneities within the upper mantle, this conclusion cannot be easily reconciled with geophysical observations without significant re-evaluation of present noble gas models. Nevertheless the analytic evidence that two different values of 129Xerad/136Xe244 exist in the Earth appears firm. If the uranium/iodine ratio is approximately uniform throughout the BSE, it follows that degassing events from separate reservoirs at different times are recorded in the currently available terrestrial Xe data.  相似文献   
349.
Sixteen basic and intermediate composition igneous glacial erratics from Anglian (pre-423,000 years) deposits in Hertfordshire and Buckinghamshire, southern Britain, were selected for chemical and petrographic analysis in order to determine their original source outcrops. Major and trace element compositions suggest that seven samples (plus two uncertain) originated in the Lower Carboniferous volcanics of the Scottish Midland Valley (SMV), four came from the Upper Carboniferous quartz dolerite association which crops out in Scotland, northern England (Whin Sill) and extends to Norway, and one came from the northern England Cleveland Dyke. One sample of altered dolerite is ambiguous but has some similarity to the Old Red Sandstone (Devonian) age lavas of the SMV, and one meta-basalt sample may be from southwest Scotland or Scandinavia. These results identify specific outcrops which provided glacial erratics within currently accepted ice trails in the United Kingdom, and provide the first supporting evidence based on geochemistry, rather than petrography, for these ice movements. The distribution and provenance of glacial erratics are of importance in archaeological studies, because erratics provided a potential source of raw material for stone implement production. There is a marked geographical correlation between the distribution of prehistoric stone implements of quartz dolerite in the United Kingdom, and directions of ice movements from quartz dolerite outcrops within Britain. This correlation lends support to the hypothesis that prehistoric man made extensive use of glacial erratics for implement manufacture, as an alternative to quarrying at outcrops and subsequent long-distance trade. © 1999 John Wiley & Sons, Inc.  相似文献   
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