Theory of the libration of the moon     

Donald H. Eckhardt 《Earth, Moon, and Planets》1981,25(1):3-49

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Additional measurements of the high-latitude sunspot rotation rate     

Donald A. Landman  Jill T. Takushi 《Solar physics》1981,73(2):379-382

We report measurements of the sunspot rotation rate at high sunspot latitutdes for the years 1966–1968. Ten spots at ¦latitude¦ 28 deg were found in our Mees Solar Observatory H patrol records for this period that are suitable for such a study. On the average we find a sidereal rotation rate of 13.70 ± 0.07 deg day^-1 at 31.05 ± 0.01 deg. This result is essentially the same as that obtained by Tang (1980) for the succeeding solar cycle, and significantly larger than Newton and Nunn's (1951) results for the 1934–1944 cycle. Taken together, the full set of measurements in this latitude regime yield a rotation rate in excellent agreement with the result =14^°.37₇–2^°.77 sin², derived by Newton and Nunn from recurrent spots predominatly at lower latitudes throughout the six cycles from 1878–1944.Summer Research Assistant.  相似文献   

Amino acid composition of organic matter associated with carbonate and non-carbonate sediments     

Paul W. Carter  Richard M. Mitterer 《Geochimica et cosmochimica acta》1978,42(8):1231-1238

Amino acids comprise from 15 to 36% by weight of humic substances from carbonate and non-carbonate sediments. Humic and fulvic acids extracted from carbonate sediments are characterized by an amino acid composition consisting primarily of the acidic amino acids, aspartic and glutamic acid. Humic substances from non-carbonate sediments have a distinctly different amino acid composition consisting primarily of glycine and alanine. Amino acid analyses of various molecular weight fractions of fulvic acids extracted from carbonates show that lower molecular weight fractions have appreciably higher relative abundances of the acidic amino acids compared to higher molecular weight fractions. Based on typical values for carboxyl group content in humic substances, acidic amino acids may be a significant contributor of these functional groups. Carbonate surfaces appear to selectively adsorb aspartic acid-enriched organic matter while non-carbonates do not have this property.  相似文献   

Properties of the clouds of Venus,as inferred from airborne observations of its near-infrared reflectivity spectrum     

James B. Pollack  Donald W. Strecker  Fred C. Witteborn  Edwin F. Erickson  Betty J. Baldwin 《Icarus》1978,34(1):28-45

We have measured the shape and absolute value of Venus' reflectivity spectrum in the 1.2-to 4.0-μm spectral region with a circular variable filter wheel spectrometer having a spectral resolution of 1.5%. The instrument package was mounted on the 91-cm telescope of NASA Ames Kuiper Airborne Observatory, and the measurements were obtained at an altitude of about 41,000 feet, when Venus had a phase angle of 86°. Comparing these spectra with synthetic spectra generated with a multiple-scattering computer code, we infer a number of properties of the Venus clouds. We obtain strong confirmatory evidence that the clouds are made of a water solution of sulfuric acid in their top unit optical depth and find that the clouds are made of this material down to an optical depth of at least 25. In addition, we determine that the acid concentration is 84 ± 2% H_2SO4 by weight in the top unit optical depth, that the total optical depth of the clouds is 37.5 ± 12.5, and that the cross-sectional weighted mean particle radius lies between 0.5 and 1.4 μm in the top unit optical depth of the clouds. These results have been combined with a recent determination of the location of the clouds' bottom boundary [Marov et al., Cosmic Res.14, 637–642 (1976)] to infer additional properties about Venus' atmosphere. We find that the average volume mixing ratio of H₂SO₄ and H₂O contained in the cloud material both equal approximately 2× 10^?6. Employing vapor pressure arguments, we show that the acid concentration equals 84 ± 6% at the cloud bottom and that the water vapor mixing ratio beneath the clouds lies between 6 × 10^?4 and 10^?2.  相似文献   

Galilean satellites: 1976 radar results     

Donald B. Campbell  John F. Chandler  Steven J. Ostro  Gordon H. Pettengill  Irwin I. Shapiro 《Icarus》1978,34(2):254-267

Radar observations of the Galilean satellites, made in late 1976 using the 12.6-cm radar system of the Arecibo Observatory, have yielded mean geometric albedos of 0.04 ± , 0.69 ± 0.17, 0.37 ± 0.09, and 0.15 ± 0.04, for Io, Europa, Ganymede, and Callisto, respectively. The albedo for Io is about 40% smaller than that obtained approximately a year earlier, while the albedos for the outer three satellites average about 70% larger than the values previously reported for late 1975, raising the possibility of temporal variation. Very little dependence on orbital phase is noted; however, some regional scattering inhomogeneities are seen on the outer three satellites. For Europa, Ganymede, and Callisto, the ratios of the echo received in one mode of circular polarization to that received in the other were: 1.61 ± 0.20 1.48 ± 0.27, and 1.24 ± 0.19, respectively, with the dominant component having the same sence of circularity as that transmitted. This behavior has not previously been encountered in radar studies of solar system objects, whereas the corresponding observations with linear polarization are “normal.” Radii determined from the 1976 radar data for Europa and Ganymede are: 1530 ± 30 and 2670 ± 50 km, in fair agreement with the results from the 1975 radar observations and the best recent optical determinations. Doppler shifts of the radar echoes, useful for the improvement of the orbits of Jupiter and some of the Galilean satellites, are given for 12 nights in 1976 and 10 nights in 1975.  相似文献   

Temperature and its control of isotope fractionation by a sulfate-reducing bacterium     

Donald E. Canfield  Claus A. Olesen  Raymond P. Cox 《Geochimica et cosmochimica acta》2006,70(3):548-561

A synthesis of previous results, which we dub the “standard model,” provides a prediction as to how isotope fractionation during sulfate reduction should respond to physiological variables such as specific rate of sulfate reduction and environmental variables such as substrate availability and temperature. The standard model suggests that isotope fractionation should decrease with increasing specific rates of sulfate reduction (rate per cell). Furthermore, the standard model predicts that low fractionations should be found at both high and low temperatures whereas the highest fractionations should be found in the intermediate temperature range. These fractionation trends are controlled, as a function of temperature, by the balance between the transfer rates of sulfate into and out of the cell and the exchange between the sulfur pools internal to the organism. We test this standard model by conducting experiments on the growth physiology and isotope fractionation, as a function of temperature, by the sulfate-reducing bacterium Desulfovibrio desulfuricans (DSMZ 642). Our results contrast with the “standard model” by showing a positive correlation between specific rates of sulfate reduction and fractionation. Also by contrast with the standard model, we found the highest fractionations at low and high temperatures and the lowest fractionations in the intermediate temperature range. We develop a fractionation model which can be used to explain both our results as well as the results of the “standard model.” Differences in fractionation with temperature relate to differences in the specific temperature response of internal enzyme kinetics as well as the exchange rates of sulfate in and out of the cell. It is expected that the kinetics of these processes will show strain-specific differences.  相似文献   

Kinetics of arsenopyrite oxidative dissolution by oxygen   总被引：1，自引：0，他引：1  

Forest P. Walker  J. Donald Rimstidt 《Geochimica et cosmochimica acta》2006,70(7):1668-1676

We used a mixed flow reactor system to determine the rate and infer a mechanism for arsenopyrite (FeAsS) oxidation by dissolved oxygen (DO) at 25 °C and circumneutral pH. Results indicate that under circumneutral pH (6.3-6.7), the rate of arsenopyrite oxidation, 10^{−10.14±0.03} mol m⁻² s⁻¹, is essentially independent of DO over the geologically significant range of 0.3-17 mg L⁻¹. Arsenic and sulfur are released from arsenopyrite in an approximate 1:1 molar ratio, suggesting that oxidative dissolution by oxygen under circumneutral pH is congruent. Slower rates of iron release from the reactor indicate that some of the iron is lost from the effluent by oxidation to Fe(III) which subsequently hydrolyzes and precipitates. Using the electrochemical cell model for understanding sulfide oxidation, our results suggest that the rate-determining step in arsenopyrite oxidation is the reduction of water at the anodic site rather than the transfer of electrons from the cathodic site to oxygen as has been suggested for other sulfide minerals such as pyrite.  相似文献   

Co-diagenesis of iron and phosphorus in hydrothermal sediments from the southern East Pacific Rise: Implications for the evaluation of paleoseawater phosphate concentrations     

Simon W. Poulton  Donald E. Canfield 《Geochimica et cosmochimica acta》2006,70(23):5883-5898

We present a detailed study of the co-diagenesis of Fe and P in hydrothermal plume fallout sediments from ∼19°S on the southern East Pacific Rise. Three distal sediment cores from 340-1130 km from the ridge crest, collected during DSDP Leg 92, were analysed for solid phase Fe and P associations using sequential chemical extraction techniques. The sediments at all sites are enriched in hydrothermal Fe (oxyhydr)oxides, but during diagenesis a large proportion of the primary ferrihydrite precipitates are transformed to the more stable mineral form of goethite and to a lesser extent to clay minerals, resulting in the release to solution of scavenged P. However, a significant proportion of this P is retained within the sediment, by incorporation into secondary goethite, by precipitation as authigenic apatite, and by readsorption to Fe (oxyhydr)oxides. Molar P/Fe ratios for these sediments are significantly lower than those measured in plume particles from more northern localities along the southern East Pacific Rise, and show a distinct downcore decrease to a depth of ∼12 m. Molar P/Fe ratios are then relatively constant to a depth of ∼35 m. The Fe and P speciation data indicate that diagenetic modification of the sediments is largely complete by a depth of 2.5 m, and thus depth trends in molar P/Fe ratios can not solely be explained by losses of P from the sediment by diffusion to the overlying water column during early diagenesis. Instead, these sediments are likely recording changes in dissolved P concentrations off the SEPR, possibly as a result of redistribution of nutrients in response to changes in oceanic circulation over the last 10 million years. Furthermore, the relatively low molar P/Fe ratios observed throughout these sediments are not necessarily solely due to losses of scavenged P by diffusion to the overlying water column during diagenesis, but may also reflect post-depositional oxidation of pyrite originating from the volatile-rich vents of the southern East Pacific Rise. This study suggests that the molar P/Fe ratio of oxic Fe-rich sediments may serve as a proxy of relative changes in paleoseawater phosphate concentrations, particularly if Fe sulfide minerals are not an important component during transport and deposition.  相似文献   

Effect of hydrogen limitation and temperature on the fractionation of sulfur isotopes by a deep-sea hydrothermal vent sulfate-reducing bacterium     

Joost Hoek  Anna-Louise Reysenbach  Donald E. Canfield 《Geochimica et cosmochimica acta》2006,70(23):5831-5841

The fractionation of sulfur isotopes by the thermophilic chemolithoautotrophic Thermodesulfatator indicus was explored during sulfate reduction under excess and reduced hydrogen supply, and the full temperature range of growth (40-80 °C). Fractionation of sulfur isotopes measured under reduced H₂ conditions in a fed-batch culture revealed high fractionations (24-37‰) compared to fractionations produced under excess H₂ supply (1-6‰). Higher fractionations correlated with lower sulfate reduction rates. Such high fractionations have never been reported for growth on H₂. For temperature-dependant fractionation experiments cell-specific rates of sulfate reduction increased with increasing temperatures to 70 °C after which sulfate-reduction rates rapidly decreased. Fractionations were relatively high at 40 °C and decreased with increasing temperature from 40-60 °C. Above 60 °C, fractionation trends switched and increased again with increasing temperatures. These temperature-dependant fractionation trends have not previously been reported for growth on H₂ and are not predicted by a generally accepted fractionation model for sulfate reduction, where fractionations are controlled as a function of temperature, by the balance of the exchange of sulfate across the cell membrane, and enzymatic reduction rates of sulfate. Our results are reproduced with a model where fractionation is controlled by differences in the temperature response of enzyme reaction rates and the exchange of sulfate in and out of the cell.  相似文献   

Correlations in aftershock and seismicity patterns     

Robert Shcherbakov  Jordan Van Aalsburg  John B. Rundle  Donald L. Turcotte   《Tectonophysics》2006,413(1-2):53

Correlations in space and time play a fundamental role in earthquake processes. One direct manifestation of the effects of correlations is the occurrence of aftershocks due to the stress transfer in the vicinity of a main shock. Less obvious and more speculative changes in correlations may occur in the background seismicity before large earthquakes. Using statistical physics it is possible to introduce a measure of spatial correlations through a correlation length. This quantity characterizes how local fluctuations can influence the occurrence of earthquakes over distances comparable with the correlation length. In this work, the physical basis of spatial correlations of earthquakes is discussed in the context of critical phenomena and the percolation problem. The method of two-point correlation function is applied to the seismicity of California. Well defined variations in time of the correlation length are found for aftershock sequences and background seismicity. The scaling properties of our obtained distributions are analyzed with respect to changes in several scaling parameters such as lower magnitude cutoff of earthquakes, the maximum time interval between earthquakes, and the spatial size of the area considered. This scaling behavior can be described in a unified manner by utilizing the multifractal fit. Utilizing the percolation approach the time evolution of clusters of earthquakes is studied with the correlation length defined in terms of the radius of gyration of clusters. This method is applied to the seismicity of California.  相似文献