Surface complexation of neodymium at the rutile-water interface: A potentiometric and modeling study in NaCl media to 250°C     

Moira K. Ridley  Michael L. Machesky  Donald A. Palmer 《Geochimica et cosmochimica acta》2005,69(1):63-81

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New evidence for an extended occupation of the Provo shoreline and implications for regional climate change, Pleistocene Lake Bonneville, Utah, USA     

Holly S. Godsey  Donald R. Currey  Marjorie A. Chan 《Quaternary Research》2005,63(2):212-223

Lake Bonneville was a climatically sensitive, closed-basin lake that occupied the eastern Great Basin during the late Pleistocene. Ongoing efforts to refine the record of lake level history are important for deciphering climate conditions in the Bonneville basin and for facilitating correlations with regional and global records of climate change. Radiocarbon data from this and other studies suggest that the lake oscillated at or near the Provo level much longer than depicted by current models of lake level change. Radiocarbon data also suggest that the lake dropped from threshold control much more rapidly than previously supposed. These revisions to the Lake Bonneville hydrograph, coupled with independent evidence of climate change from vegetation and glacial records, have important implications for conditions in the Bonneville basin and during the Pleistocene to Holocene transition.  相似文献   

Plio-Pleistocene mammals from Mille-Logya,Ethiopia, and the post-Hadar faunal change     

Denis Geraads  Denne Reed  W. Andrew Barr  René Bobe  Peter Stamos  Zeresenay Alemseged 《第四纪科学杂志》2021,36(6):1073-1089

We describe the non-primate mammalian fauna from the late Pliocene to earliest Pleistocene deposits of Mille-Logya in the Lower Awash Valley, Ethiopia, dated to c. 2.9–2.4 Ma, and divided into three successive units: Gafura, Seraitu, and Uraitele. We identify 41 mammalian taxa (including rodents), the most diverse group being the Bovidae, with 17 taxa. While the Gafura assemblage still resembles those from the earlier Hadar Formation, the younger Seraitu assemblage documents a major turnover. While there is little change in the species present across this interval, the relative abundances of various taxa change dramatically, with suids being largely replaced by open-country bovids (Alcelaphini and Antilopini). We interpret this faunal change as reflective of an environmental shift, contemporaneous with the replacement of Australopithecus afarensis by Homo in the area.  相似文献   

Groundwater – the disregarded component in lake water and nutrient budgets. Part 2: effects of groundwater on nutrients          下载免费PDF全文

Jörg Lewandowski  Karin Meinikmann  Gunnar Nützmann  Donald O. Rosenberry 《水文研究》2015,29(13):2922-2955

Lacustrine groundwater discharge (LGD) transports nutrients from a catchment to a lake, which may fuel eutrophication, one of the major threats to our fresh waters. Unfortunately, LGD has often been disregarded in lake nutrient studies. Most measurement techniques are based on separate determinations of volume and nutrient concentration of LGD: Loads are calculated by multiplying seepage volumes by concentrations of exfiltrating water. Typically low phosphorus (P) concentrations of pristine groundwater often are increased due to anthropogenic sources such as fertilizer, manure or sewage. Mineralization of naturally present organic matter might also increase groundwater P. Reducing redox conditions favour P transport through the aquifer to the reactive aquifer‐lake interface. In some cases, large decreases of P concentrations may occur at the interface, for example, due to increased oxygen availability, while in other cases, there is nearly no decrease in P. The high reactivity of the interface complicates quantification of groundwater‐borne P loads to the lake, making difficult clear differentiation of internal and external P loads to surface water. Anthropogenic sources of nitrogen (N) in groundwater are similar to those of phosphate. However, the environmental fate of N differs fundamentally from P because N occurs in several different redox states, each with different mobility. While nitrate behaves essentially conservatively in most oxic aquifers, ammonium's mobility is similar to that of phosphate. Nitrate may be transformed to gaseous N₂ in reducing conditions and permanently removed from the system. Biogeochemical turnover of N is common at the reactive aquifer‐lake interface. Nutrient loads from LGD were compiled from the literature. Groundwater‐borne P loads vary from 0.74 to 2900 mg PO₄‐P m^?2 year^?1; for N, these loads vary from 0.001 to 640 g m^?2 year^?1. Even small amounts of seepage can carry large nutrient loads due to often high nutrient concentrations in groundwater. Large spatial heterogeneity, uncertain areal extent of the interface and difficult accessibility make every determination of LGD a challenge. However, determinations of LGD are essential to effective lake management. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Pre‐ and post‐impoundment nitrogen in the lower Missouri River          下载免费PDF全文

Dale W. Blevins  Donald H. Wilkison  Shelley L. Niesen 《水文研究》2014,28(4):2535-2549

Large water‐sample sets collected from 1899 through 1902, 1907, and in the early 1950s allow comparisons of pre‐impoundment and post‐impoundment (1969 through 2008) nitrogen concentrations in the lower Missouri River. Although urban wastes were not large enough to detectably increase annual loads of total nitrogen at the beginning of the 20^th century, carcass waste, stock‐yard manure, and untreated human wastes measurably increased ammonia and organic‐nitrogen concentrations during low flows. Average total‐nitrogen concentrations in both periods were about 2.5 mg/l, but much of the particulate‐organic nitrogen, which was the dominant form of nitrogen around 1900, has been replaced by nitrate. This change in speciation was caused by the nearly 80% decrease in suspended‐sediment concentrations that occurred after impoundment, modern agriculture, drainage of riparian wetlands, and sewage treatment. Nevertheless, bioavailable nitrogen has not been low enough to limit primary production in the Missouri River since the beginning of the 20^th century. Nitrate concentrations have increased more rapidly from 2000 through 2008 (5 to 12% per year), thus increasing bioavailable nitrogen delivered to the Mississippi River and affecting Gulf Coast hypoxia. The increase in nitrate concentrations with distance downstream is much greater during the post‐impoundment period. If strategies to decrease total‐nitrogen loads focus on particulate N, substantial decreases will be difficult because particulate nitrogen is now only 23% of total nitrogen in the Missouri River. A strategy aimed at decreasing particulates also could further exacerbate land loss along the Gulf of Mexico, which has been sediment starved since Missouri River impoundment. In contrast, strategies or benchmarks aimed at decreasing nitrate loads could substantially decrease nitrogen loadings because nitrates now constitute over half of the Missouri's nitrogen input to the Mississippi. Ongoing restoration and creation of wetlands along the Missouri River could be part of such a nitrate‐reduction strategy. Published 2013. This article is a U.S. Government work and is in the public domain in the USA.  相似文献   

Alteration of hydrological processes and streamflow with juniper (Juniperus virginiana) encroachment in a mesic grassland catchment          下载免费PDF全文

Chris B. Zou  Donald J. Turton  Rodney E. Will  David M. Engle  Sam D. Fuhlendorf 《水文研究》2014,28(26):6173-6182

To understand the effect of woody plant encroachment on hydrological processes of mesic grasslands, we quantified infiltration capacity in situ, the temporal changes in soil water storage, and streamflow of a grassland catchment and a catchment heavily encroached by juniper (Juniperus virginiana, eastern redcedar) in previously cultivated, non‐karst substrate grasslands in north‐central Oklahoma for 3 years. The initial and steady‐state infiltration rates under the juniper canopy were nearly triple to that of the grassland catchment and were intermediate in the intercanopy spaces within the encroached catchment. Soil water content and soil water storage on the encroached catchment were generally lower than on the grassland catchment, especially when preceding the seasons of peak rainfall in spring and fall. Frequency and magnitude of streamflow events were reduced in the encroached catchment. Annual runoff coefficients for the encroached catchment averaged 2.1%, in contrast to 10.6% for the grassland catchment. Annual streamflow duration ranged from 80 to 250 h for the encroached catchment compared with 600 to 800 h for the grassland catchment. Our results showed that the encroachment of juniper into previously cultivated mesic grasslands fundamentally alters catchment hydrological function. Rapid transformation of mesic grassland to a woodland state with juniper encroachment, if not confined, has the potential to drastically reduce soil water, streamflow and flow duration of ephemeral streams in the Southern Great Plains. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Evaluation of distributed BMPs in an urban watershed—High resolution modeling for stormwater management          下载免费PDF全文

Timothy J. Fry  Reed M. Maxwell 《水文研究》2017,31(15):2700-2712

The urban environment modifies the hydrologic cycle resulting in increased runoff rates, volumes, and peak flows. Green infrastructure, which uses best management practices (BMPs), is a natural system approach used to mitigate the impacts of urbanization onto stormwater runoff. Patterns of stormwater runoff from urban environments are complex, and it is unclear how efficiently green infrastructure will improve the urban water cycle. These challenges arise from issues of scale, the merits of BMPs depend on changes to small‐scale hydrologic processes aggregated up from the neighborhood to the urban watershed. Here, we use a hyper‐resolution (1 m), physically based hydrologic model of the urban hydrologic cycle with explicit inclusion of the built environment. This model represents the changes to hydrology at the BMP scale (~1 m) and represents each individual BMP explicitly to represent response over the urban watershed. Our study varies both the percentage of BMP emplacement and their spatial location for storm events of increasing intensity in an urban watershed. We develop a metric of effectiveness that indicates a nonlinear relationship that is seen between percent BMP emplacement and storm intensity. Results indicate that BMP effectiveness varies with spatial location and that type and emplacement within the urban watershed may be more important than overall percent.  相似文献   

Magma mixing induced by particle settling     

Christian J. Renggli  Sebastian Wiesmaier  Cristina P. De Campos  Kai-Uwe Hess  Donald B. Dingwell 《Contributions to Mineralogy and Petrology》2016,171(11):96

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The Relationship Between Shoreline Armoring and Adjacent Submerged Aquatic Vegetation in Chesapeake Bay and Nearby Atlantic Coastal Bays     

Christopher J. Patrick  Donald E. Weller  Micah Ryder 《Estuaries and Coasts》2016,39(1):158-170

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<Emphasis Type="Italic">Deepwater Horizon</Emphasis> Oil Spill Impacts on Salt Marsh Fiddler Crabs (<Emphasis Type="Italic">Uca</Emphasis> spp.)     

Scott Zengel  Steven C. Pennings  Brian Silliman  Clay Montague  Jennifer Weaver  Donald R. Deis  Michelle O. Krasnec  Nicolle Rutherford  Zachary Nixon 《Estuaries and Coasts》2016,39(4):1154-1163

The Deepwater Horizon oil spill was the largest marine oil spill in US waters to date and one of the largest worldwide. Impacts of this spill on salt marsh vegetation have been well documented, although impacts on marsh macroinvertebrates have received less attention. To examine impacts of the oil spill on an important marsh invertebrate and ecosystem engineer, we conducted a meta-analysis on fiddler crabs (Uca spp.) using published sources and newly available Natural Resources Damage Assessment (NRDA) and Gulf of Mexico Research Initiative (GoMRI) data. Fiddler crabs influence marsh ecosystem structure and function through their burrowing and feeding activities and are key prey for a number of marsh and estuarine predators. We tested the hypothesis that the spill affected fiddler crab burrow density (crab abundance), burrow diameter (crab size), and crab species composition. Averaged across multiple studies, sites, and years, our synthesis revealed a negative effect of oiling on all three metrics. Burrow densities were reduced by 39 % in oiled sites, with impacts and incomplete recovery observed over 2010–2014. Burrow diameters were reduced from 2010 to 2011, but appeared to have recovered by 2012. Fiddler crab species composition was altered through at least 2013 and only returned to reference conditions where marsh vegetation recovered, via restoration planting in one case. Given the spatial and temporal extent of data analyzed, this synthesis provides compelling evidence that the Deepwater Horizon spill suppressed populations of fiddler crabs in oiled marshes, likely affecting other ecosystem attributes, including marsh productivity, marsh soil characteristics, and associated predators.  相似文献