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91.
Petrological analysis of the Martian meteorites suggests that rheologically significant amounts of water are present in the Martian mantle. A bulk mantle water content of at least a few tens of ppm is thus expected to be present despite the potentially efficient degassing during accretion, magma ocean solidification, and subsequent volcanism. We examine the dynamical consequences of different thermochemical evolution scenarios testing whether they can lead to the formation and preservation of mantle reservoirs, and compare model predictions with available data. First, the simplest scenario of a homogenous mantle that emerges when ignoring density changes caused by the extraction of partial melt is found to be inconsistent with the isotopic evidence for distinct reservoirs provided by the analysis of the Martian meteorites. In a second scenario, reservoirs can form as a result of partial melting that induces a density change in the depleted mantle with respect to its primordial composition. However, efficient mantle mixing prevents these reservoirs from being preserved until present unless they are located in the stagnant lid. Finally, reservoirs could be formed during fractional crystallization of a magma ocean. In this case, however, the mantle would likely end up being stably stratified as a result of the global overturn expected to accompany the fractional crystallization. Depending on the assumed density contrast, little secondary crust would be produced and the lithosphere would be extremely cool and dry, in contrast to observations. In summary, it is very challenging to obtain a self‐consistent evolution scenario that satisfies all available constraints.  相似文献   
92.
In Northern Mexico, long-term grazing has substantially degraded semiarid landscapes. In semiarid systems, ecological and hydrological processes are strongly coupled by patchy plant distribution and biological soil crust (BSC) cover in plant-free interspaces. In this study, we asked: 1) how responsive are BSC cover/composition to a drying/wetting cycle and two-year grazing removal, and 2) what are the implications for soil erosion? We characterized BSC morphotypes and their influence on soil stability under grazed/non-grazed conditions during a dry and wet season. Light- and dark-colored cyanobacteria were dominant at the plant tussock and community level. Cover changes in these two groups differed after a rainy season and in response to grazing removal. Lichens with continuous thalli were more vulnerable to grazing than those with semi-continuous/discontinuous thalli after the dry season. Microsites around tussocks facilitated BSC colonization compared to interspaces. Lichen and cyanobacteria morphotypes differentially enhanced resistance to soil erosion; consequently, surface soil stability depends on the spatial distribution of BSC morphotypes, suggesting soil stability may be as dynamic as changes in the type of BSC cover. Longer-term spatially detailed studies are necessary to elicit spatiotemporal dynamics of BSC communities and their functional role in biotically and abiotically variable environments.  相似文献   
93.
Early Miocene transpressional wrenching yielded a series of NW–SE-elongated pull-apart basins in the Dinarides of Croatia and Bosnia and Herzegovina. They accommodated a huge lake system that gave rise to spectacular endemic mollusk radiation. Lake Sinj, moderately sized at 342 km2, flooded the south-westernmost basin of this system. Due to the karstic environment, the hard-water, alkaline, long-lived lake developed a sediment infill with an average thickness of 370 m, dominated by authigenic limestone. The studied section represents the upper third of the basinal infill and provides detailed insights into the critical period of the lake and of the basinal evolution during the final stages of its filling. It comprises two large-scale, shallowing-upward cycles, both starting with fossil-poor limestones, gradually passing into coal-bearing carbonate rocks and coal seams. The fossil-poor intervals are interpreted as phases of repetitive acidification events due to changing lake level, which induced periodic drying and flooding of the uppermost littoral zone inhabited by starfruit (Damasonium) meadows. The flooding of the aerated, limy mud plain introduced H+ ions from organic-matter decay reactions into the shallow lake. This decreased its pH level, with catastrophic consequences for its biota. The ecosystem then stabilized during the orbitally-forced, dry climate phases. Based on the mollusk record, streams still influenced the marginal lake environment and rich organic-matter production created swamps and mires. The onset of mollusk radiation in the section correlates with stabilized lake alkalinity, as indicated by the disappearance of starfruits, ongoing authigenic carbonate production and by coal seams representing textbook examples for coal formation in alkaline environments. The inferred basinal setting fits well with the pull-apart basin model, pointing to the presence of an extended shallow ramp in front of a steep, fault-induced hillside of the hinterland.  相似文献   
94.
ABSTRACT

Groundwater is used by 3?million inhabitants in the coastal urban city of Douala, Cameroon, but comprehensive data are too sparse for it to be managed in a sustainable manner. Hence this study aimed to (1) assess the potability of the groundwater; (2) evaluate the spatial variation of groundwater composition; and (3) assess the interaction and recharge mechanisms of different water bodies. Hydrogeochemical tools and methods revealed the following results in the Wouri and Nkappa formations of the Douala basin, which is beneath Douala city: 30% of water samples from hand-dug wells in the shallow Pleistocene alluvium aquifer were saline and highly mineralized. However, water from boreholes in the deeper (49–92 m depth) Palaeocene aquifer was saline-free, less mineralized and potable. Water in the shallow aquifer (0.5–22 m depth) was of Na+-K+-Cl?-NO3? type and not potable due to point source pollution, whereas Ca+-HCO3? unpolluted water dominates in the deeper aquifer. Water in the deep and shallow aquifers indicates the results of preferential flow pass and evaporative recharge, respectively. Possible hydrogeochemical processes include point source pollution, reverse ion exchange, remote recharge areas and mixing of waters with different chemical signatures.
EDITOR D. Koutsoyiannis ASSOCIATE EDITOR M.D. Fidelibus  相似文献   
95.
This paper describes the integration of results from different feature extraction algorithms using spectral and spatial attributes to detect specific urban features. Methodology includes segmentation of IKONOS data, computing attributes for creating image objects and classifying the objects with fuzzy logic and rule-based algorithms. Previous research reported low class accuracies for two specific classes – dark and grey roofs. A modified per-field approach was employed to extract urban features. New rule-sets were used on image objects having similar or near-similar spectral and spatial characteristics. Different algorithms using spectral and spatial attributes were developed to extract specific urban features from a time-series of Multi-Spectral Scanner (MSS) (4 m × 4 m) IKONOS data. The modified approach resulted in a remarkable improvement in the accuracy of classes that registered low spectral seperability and therefore low accuracy. The spectral and spatial based classification model may be useful in mapping heterogeneous and spectrally similar urban features.  相似文献   
96.
Current climate change models for the southeast UK predict changing rainfall patterns, with increased incidence of extreme events. The chalk aquifer in the UK and northern France is susceptible to groundwater‐induced flooding under such conditions. In this methodological study we apply a frequency domain analysis approach to the chalk aquifer to derive a transfer function between effective rainfall and groundwater level from 7 years of monitoring data from the North Heath Barn site, near Brighton. The derived transfer function was calibrated and validated against monitoring data and then used to predict groundwater level for rainfall models for high, medium and low emission scenarios from the UKCP09 database. The derived transfer function is most closely comparable to the linear aquifer model, despite evidence for both matrix and fracture or karst water flow in the chalk, with transmissivity and unconfined storativity at the catchment scale of 1548 m2 day?1 and 1.6 × 10?2. The application of the transfer function to UKCP09 rainfall data suggests that groundwater‐induced flooding may be about four times more frequent by 2040–2069 compared with 1961–1990 and seven times more frequent by 2070–2099. The model data also suggest an increase in the duration of groundwater minima relative to the reference period. Compared to deterministic modelling which requires detailed knowledge of aquifer heterogeneity and processes, the transfer function approach, although with limitations, is simpler, incorporating these factors into the analysis through frequency and phase coefficients, and thus may have the potential for groundwater risk assessment in other areas. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   
97.
The principle of subsurface iron removal for drinking water supply is that aerated water is periodically injected into the aquifer through a tube well. On its way into the aquifer, the injected O2-rich water oxidizes adsorbed Fe2+, creating a subsurface oxidation zone. When groundwater abstraction is resumed, the soluble Fe2+ is adsorbed and water with reduced Fe concentrations is abstracted for multiple volumes of the injection water. In this article, Fe accumulation deposits in the aquifer near subsurface treatment wells were identified and characterized to assess the sustainability of subsurface iron removal regarding clogging of the aquifer and the potential co-accumulation of other groundwater constituents, such as As. Chemical extraction of soil samples, with Acid-Oxalate and HNO3, showed that Fe had accumulated at specific depths near subsurface iron removal wells after 12 years of operation. Whether it was due to preferred flow paths or geochemical mineralogy conditions; subsurface iron removal clearly favoured certain soil layers. The total Fe content increased between 11.5 and 390.8 mmol/kg ds in the affected soil layers, and the accumulated Fe was found to be 56-100% crystalline. These results suggest that precipitated amorphous Fe hydroxides have transformed to Fe hydroxides of higher crystallinity. These crystalline, compact Fe hydroxides have not noticeably clogged the investigated well and/or aquifer between 1996 and 2008. The subsurface iron removal wells even need less frequent rehabilitation, as drawdown increases more slowly than in normal production wells. Other groundwater constituents, such as Mn, As and Sr were found to co-accumulate with Fe. Acid extraction and ESEM-EDX showed that Ca occurred together with Fe and by X-ray Powder Diffraction it was identified as calcite.  相似文献   
98.
In this study, the annual and seasonal variations of all-sky and clear-sky surface solar radiation (SSR) in the eastern and central Tibetan Plateau (TP) during the period 1960–2009 are investigated, based on surface observational data, reanalyses and ensemble simulations with the global climate model ECHAM5-HAM. The mean annual all-sky SSR series shows a decreasing trend with a rate of ?1.00 Wm?2 decade?1, which is mainly seen in autumn and secondly in summer and winter. A stronger decrease of ?2.80 Wm?2 decade?1 is found in the mean annual clear-sky SSR series, especially during winter and autumn. Overall, these results confirm a tendency towards a decrease of SSR in the TP during the last five decades. The comparisons with reanalysis show that both NCEP/NCAR and ERA-40 reanalyses do not capture the decadal variations of the all-sky and clear-sky SSR. This is probably due to a missing consideration of aerosols in the reanalysis assimilation model. The SSR simulated with the ECHAM5-HAM global climate model under both all-sky and clear-sky conditions reproduce the decrease seen in the surface observations, especially after 1980. The steadily increasing aerosol optical depth (AOD) at 550 nm over the TP in the ECHAM5-HAM results suggests transient aerosol emissions as a plausible cause.  相似文献   
99.
100.
We introduce versatile spectral analysis (VESPA): a new method which aims to recover robust star formation and metallicity histories from galactic spectra. VESPA uses the full spectral range to construct a galaxy history from synthetic models. We investigate the use of an adaptative parametrization grid to recover reliable star formation histories on a galaxy-by-galaxy basis. Our goal is robustness as opposed to high-resolution histories, and the method is designed to return high time resolution only where the data demand it. In this paper we detail the method and we present our findings when we apply VESPA to synthetic and real Sloan Digital Sky Survey (SDSS) spectroscopic data. We show that the number of parameters that can be recovered from a spectrum depends strongly on the signal-to-noise ratio, wavelength coverage and presence or absence of a young population. For a typical SDSS sample of galaxies, we can normally recover between two and five stellar populations. We find very good agreement between VESPA and our previous analysis of the SDSS sample with MOPED.  相似文献   
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