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31.
S.A. Drury 《Chemical Geology》1973,11(3):167-188
The metamorphism and geochemistry of the major components of a small area of granulite facies rock are described and discussed, and a chemical model for the evolution of anomalous trace element distributions in such materials is suggested. The local complex was subjected to medium to high pressure granulite facies metamorphism between 2,900 and 2,600 m.y. All the analysed granulite facies rocks from Tiree; acid to intermediate gneisses, basic metamorphic rocks, and granitic rocks, have anomalous chemistries, being depleted in K, Rb, Nb, Y and Th, and have high K/Rb, Ba/Rb and Ca/Y ratios, and very low K/Ba and Rb/Sr ratios relative to normal portions of the upper continental crust. The gneisses seem to have been enriched in Ba and Sr.The chemical features of the rocks are considered to reflect their stable mineral assemblages in the granulite facies, and to be representative of deep-level crustal materials. The geochemical peculiarities of the complex may have been largely controlled by an upward intergranular diffusion, or “degassing” caused by high-grade metamorphism. It is suggested that such diffusion may have been active at the crust/upper mantle interface, some diffused material of mantle origin accounting for certain chemical oddities typical of Lewisian and some other Precambrian granulite facies rocks. 相似文献
32.
This study investigated how an industrial tuna fishery functions in terms of procedures, practices, governance and finance in the context of Ghana, West Africa. Tuna is Ghana’s biggest seafood export, contributing significantly to the domestic fisheries sector. A case-study approach was used to analyse relevant social and economic factors at the local scale to better understand how the global seafood industry operates in a low-income country. A value-chain framework was adopted to assess market structures, sales pathways and revenue distribution. We also investigated the role of actors engaged in the industry using secondary data, interviews, questionnaires and participant observations. The results revealed a changing organisational structure in tuna production, moving from bait-boat fishing with smaller companies to large-scale purse-seine fishing backed by consolidated Asian seafood companies. Production was found to depend significantly on local female intermediaries for access to funds through prefinancing arrangements. Considerable illegalities were identified within the value chain, highlighting the need for improved partnership and licensing negotiations, and for low-cost marine control and surveillance tools. As vertical integration increases within the industry, the influence of corporations as keystone actors becomes evident for the future social and ecological sustainability of the industry. 相似文献
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Distinction between amorphous and healed planar deformation features in shocked quartz using composite color scanning electron microscope cathodoluminescence (SEM‐CL) imaging 下载免费PDF全文
Maartje F. Hamers Gill M. Pennock Marco Herwegh Martyn R. Drury 《Meteoritics & planetary science》2016,51(10):1914-1931
Planar deformation features (PDFs) in quartz are one of the most reliable and most widely used forms of evidence for hypervelocity impact. PDFs can be identified in scanning electron microscope cathodoluminescence (SEM‐CL) images, but not all PDFs show the same CL behavior: there are nonluminescent and red luminescent PDFs. This study aims to explain the origin of the different CL emissions in PDFs. Focused ion beam (FIB) thin foils were prepared of specific sample locations selected in composite color SEM‐CL images and were analyzed in a transmission electron microscope (TEM). The FIB preparation technique allowed a direct, often one‐to‐one correlation between the CL images and the defect structure observed in TEM. This correlation shows that composite color SEM‐CL imaging allows distinction between amorphous PDFs on one hand and healed PDFs and basal Brazil twins on the other: nonluminescent PDFs are amorphous, while healed PDFs and basal Brazil twins are red luminescent, with a dominant emission peak at 650 nm. We suggest that the red luminescence is the result of preferential beam damage along dislocations, fluid inclusions, and twin boundaries. Furthermore, a high‐pressure phase (possibly stishovite) in PDFs can be detected in color SEM‐CL images by its blue luminescence. 相似文献
36.
G. M. Pennock M. Coleman M. R. Drury V. Randle 《Contributions to Mineralogy and Petrology》2009,158(1):53-67
Many physical properties of rocks are sensitive to grain size and hence to the structure of grain boundaries. Depending on
their properties, such as deformation and transport behaviour, boundaries may be divided into two broad types, namely special
and general grain boundaries. Electron backscattered diffraction (EBSD) is used to investigate the misorientation distributions
of grain boundaries and, more recently, to determine the population of grain boundary planes. Studies on metals and ceramics
suggest that the grain boundary plane, rather than the misorientation, is the key parameter when defining special and general
grain boundaries. In this study, the distribution of grain boundary plane orientations has been successfully determined using
EBSD for a slightly deformed, synthetic NaCl material containing 22 ppm water. Boundaries showed a preference for {100} planes,
which occurred with twice the frequency of a random distribution. The grain boundary plane distributions found in NaCl were
largely in agreement with studies on MgO. Grain boundaries, with a coincident site lattice (CSL) misorientation, also showed
a preference for {100} planes, rather than the planes of high coincident density associated with the CSL. Three main types
of boundary were identified, namely {100} twist boundaries, boundaries with {100}{hkl} planes and general {hkl}{hkl} boundaries.
As the properties of these three types of boundary differ, then the transport and creep properties in wet NaCl will depend
on the fraction of the different boundary types found in the grain boundary population. 相似文献
37.
C. Franke G. M. Pennock M. R. Drury R. Engelmann D. Lattard J. F. L. Garming T. von Dobeneck M. J. Dekkers 《Geophysical Journal International》2007,170(2):545-555
In paleomagnetic and environmental magnetic studies the magnetomineralogical identification is usually based on a set of rock magnetic parameters, complemented by crystallographic and chemical information retrieved from X-ray diffraction (XRD), (electron) microscopy or energy dispersive spectroscopy (EDS) of selected samples. While very useful, each of these supplementary techniques has its limitations when applied to natural sample material which are related to low particle concentrations (down to the ppm range in marine sediments) and very fine grain sizes (down to the nm scale). Therefore, meaningful application of such techniques depends on sample quality. Electron backscatter diffraction (EBSD) of individual grains in scanning electron microscopy (SEM) enables mineralogical identification of grains down to ∼0.2 micrometer and is particularly powerful when combined with EDS. In this study, we show the merits of EBSD for rock magnetic investigations by analyzing titanomagnetites and hemoilmenites of various compositions and submicron lamella of titanomagnetite–hemoilmenite intergrowths. Such particles often occur in natural marine sediments where EDS often has a semi-quantitative character and compositionally similar intergrowths may be difficult to distinguish. With the mineralogical information provided by EBSD unambiguous identification of spinel-type and trigonal oxides is obtained. Optimal EBSD patterns are gathered from smooth, polished surfaces, but here we show that interpretable EBSD patterns can be obtained directly from the surface of unconsolidated, so called 'non-embedded' particles from marine sediments. This information enhances the interpretative value of rock magnetic parameters. 相似文献
38.
Malcolm J Drury 《Tectonophysics》1985,115(1-2)
Six new heat flow determinations are presented for Proterozoic mobile belts of the Churchill Province of the Canadian Shield, an area that was affected by several stages of the Hudsonian orogenic sequence (1.9-1.6 Ga ago). With other, previously published, values the mean of eight determinations considered reliable and representative and corrected for the effects of Pleistocene glaciation is 44 ± 7 mW m−2. Heat generation measurements have also been made; values range from 0.1–1.04 μW m−3.A linear relation between heat flow and heat production is apparent. The heat flow axis intercept is 37 mW m−2, and the scale depth is 11 km, compared with 28 mW m−2 and 13.6 km for the Archaean Superior Province. Approximately 20% of the Churchill heat flow appears to be derived from radioactive decay in the upper crust, compared with 30% for the Superior Province and shields as a whole. The observations imply that the heat flow-heat production relation for the Churchill Province should be written as Q = Qc + Qe + A0b where Qc is equivalent to the reduced heat flow for the Archaean terrain, b is similar for the two, and Qe is an additional component of heat flow in the Proterozoic mobile belts of the Churchill Province.A speculative tectonic model is presented. It is suggested that rifting along two axes of an original craton, which had lateral variations in near surface radiogenic element concentration, followed by erosion of the radiogenic layer and subsequent reconvergence of the cratonic segments, led to widespread redistribution of radioactive elements into the reactivated inter-rift crustal block. One result would be that crustal temperatures are higher in that part of the Churchill Province than in the Superior. 相似文献
39.
A. J. Bons M. R. Drury D. Schryvers H. J. Zwart 《Physics and Chemistry of Minerals》1990,17(5):402-408
The structure of grain boundaries in some very low-grade slates has been studied with transmission electron microscopy. All phyllosilicate boundaries have structural widths of less than 1 nm. A range of structural types have been observed from apparently coherent basal layer chlorite-muscovite boundaries, semi-coherent chlorite-chlorite boundaries and incoherent boundaries which are commonly defined by a thin layer, 7–10 nm thick, of crystalline second phase. Remnants of isolated fluid inclusions are only found at quartz-quartz boundaries. The cleavage microstructures suggest that a large amount of volume loss occurred during cleavage development at low temperatures. This is most likely to have been achieved by diffusion and/or advection through a fluid-filled network present along grain boundaries or grain edges. The phyllosilicate grain boundaries in their present state could not have acted as the pathways for extensive fluid-assisted mass transport. This suggests that the grain boundary structure during cleavage formation was different from the present state. An interconnected fluid network may be maintained along grain boundaries during deformation by hydrofracturing or by grain boundary migration during dehydration reactions, but as deformation and reactions cease the grain boundaries develop an equilibrium structure with very narrow structural widths and restricted fluid distribution. 相似文献
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