The Production of Methanol by Flowering Plants and the Global Cycle of Methanol   总被引：10，自引：0，他引：10  

I. E. Galbally  W. Kirstine 《Journal of Atmospheric Chemistry》2002,43(3):195-229

Methanol has been recognised as an important constituent of the background atmosphere, but little is known about its overall cycle in the biosphere/atmosphere system. A model is proposed for the production and emission to the atmosphere of methanol by flowering plants based on plant structure and metabolic properties, particularly the demethylation of pectin in the primary cell walls. This model provides a framework to extend seven sets of measurements of methanol emission rates to the global terrestrial biosphere. A global rate of release of methanol from plants to the atmosphere of 100 Tg y^–1 is calculated. A separate model of the global cycle of methanol is constructed involving emissions from plant growth and decay, atmospheric and oceanic chemical production, biomass burning and industrial production. Removal processes occur through hydroxyl radical attack in the atmosphere, in clouds and oceans, and wet and dry deposition. The model successfully reproduces the methanol concentrations in the continental boundary-layer and the free atmosphere, including the inter-hemispheric gradient in the free atmosphere. The model demonstrates a new concept in global biogeochemistry, the coupling of plant cell growth with the global atmospheric concentration of methanol. The model indicates that the ocean provides a storage reservoir capable of holding at least 66 times more methanol than the atmosphere. The ocean surface layer reservoir essentially buffers the atmospheric concentration of methanol, providing a physically based smoothing mechanism with a time constant of the order of one year.  相似文献   

Determination of Area-Averaged Water Vapour Fluxes with Large Aperture and Radio Wave Scintillometers over a Heterogeneous Surface – Flevoland Field Experiment     

W. M. L. Meijninger  A. E. Green  O. K. Hartogensis  W. Kohsiek  J. C. B. Hoedjes  R. M. Zuurbier  H. A. R. De Bruin 《Boundary-Layer Meteorology》2002,105(1):63-83

A large aperture scintillometer (LAS) andradio wave scintillometer (RWS)were installed over a heterogeneous areato test the applicability of the scintillation method.The heterogeneity in the area, whichconsisted of many plots, was mainly caused bydifferences in thermal properties ofthe crops; the variations in theaerodynamic roughness lengthwere small. The water vapour fluxesderived from the combined LAS-RWSsystem, also known as the two-wavelengthmethod, agreed fairly well with the aggregatedwater vapour fluxes derived from in-situeddy covariance measurements. The water vapourfluxes derived from a stand-alone LASare also presented. It was found that a single LASand an estimate of the area averagedavailable energy (using a simple parameterisationscheme) can provide also reasonablearea-averaged water vapour fluxes.  相似文献   

Sensitivity of modeled tropical cyclone track and structure of hurricane Irene (1999) to the convective parameterization scheme     

B. E. Prater  J. L. Evans 《Meteorology and Atmospheric Physics》2002,80(1-4):103-115

Summary The Betts-Miller and the Kain-Fritsch schemes are two of the many approaches to convective parameterization available to modelers. In the case of hurricane Irene (1999), the choice of parameterization markedly impacted the modeled track and structure of the hurricane and its subsequent extratropical transition. Specifically, in model runs using Betts-Miller, Irene recurved too early, causing the storm to weaken over the cool open ocean, delaying its transition, and changing the character of the storm. The Kain-Fritsch scheme more accurately reproduced the track of Irene and, hence, its interaction with upper-level features that caused extratropical transition and post-transition intensification. The two parameterizations produce different characteristic vertical warming profiles; the differences in warming are related to the structural differences in the simulated storm, affecting the hurricane response to its environment. Received October 13, 2001 Revised December 23, 2001  相似文献   

The surface heat flux feedback. Part II: direct and indirect estimates in the ECHAM4/OPA8 coupled GCM     

C. Frankignoul  E. Kestenare  J. Mignot 《Climate Dynamics》2002,19(8):649-655

The surface heat flux feedback in the Atlantic Ocean is estimated in the ECHAM4/OPA8 coupled model. The net heat flux feedback is negative everywhere, mostly ranging between 15 and 35 W m^-2 K^-1, but reaching up to 50 W m^-2 K^-1 in the tropics, so that it damps existing sea surface temperature anomalies. The bulk of it is due to the turbulent flux, although in the tropics the radiation feedback also strongly contributes. The turbulent heat flux feedback is strongest in fall and winter at extra-tropical latitudes, and in spring and summer near the equator. At mid-latitudes, the radiation feedback remains small in each season, but it can be strongly negative in parts of the tropics. At extra-tropical latitudes the model feedback compares rather well with estimates derived in Part I from the COADS observations and the NCEP reanalysis, but in the tropical Atlantic the negative heat flux feedback is much too strong. An indirect estimation of the model heat flux feedback is also attempted in regions of small mean surface current, based on the difference in decay time of sea surface temperature and salinity anomalies. The inferred negative heat flux feedback is qualitatively correct, but the seasonal changes in the mixed-layer depth are too large for the method to be accurate at high latitudes.  相似文献   

The operational weather radar of Fossalon di Grado (Gorizia, Italy): accuracy of reflectivity and differential reflectivity measurements     

R. Bechini  E. Gorgucci  G. Scarchilli  S. Dietrich 《Meteorology and Atmospheric Physics》2002,79(3-4):275-284

Summary The error structure of radar measurements should be accurately known in order to provide reliable estimates for a number of quantitative meteorological applications, from rainfall rate estimation to cloud microphysics. The aim of this paper is to give a detailed characterization of Z _H and Z _DR measurements obtained by the weather radar of Fossalon di Grado (Gorizia, Italy). Vertical-looking observations are used to determine the system bias on differential reflectivity and to estimate the measurement error on both Z _H and Z _DR in the rain medium. It is estimated that no bias is affecting Z _DR and the accuracy of Z _H and Z _DR is 0.8 and 0.1 dB, respectively. A similar evaluation is done in the rain medium at larger ranges with the antenna pointing at low elevation angles. The long time stability of the absolute reflectivity calibration is also established by radar-rain gage inter-comparison over almost 200 hours of precipitation data collected during nearly two years. Received June 21, 2001 Revised November 13, 2001  相似文献   

Particle size dependent response of aerosol counters     

A. Ankilov  A. Baklanov  M. Colhoun  K. -H. Enderle  J. Gras  Yu. Julanov  D. Kaller  A. Lindner  A. A. Lushnikov  R. Mavliev  F. McGovern  T. C. O'Connor  J. Podzimek  O. Preining  G. P. Reischl  R. Rudolf  G. J. Sem  W. W. Szymanski  A. E. Vrtala  P. E. Wagner  W. Winklmayr  V. Zagaynov 《Atmospheric Research》2002,62(3-4)

During an international workshop at the Institute for Experimental Physics of the University of Vienna, Austria, which was coordinated within the Committee on Nucleation and Atmospheric Aerosols (IAMAS-IUGG), 10 instruments for aerosol number concentration measurement were studied, covering a wide range of methods based on various different measuring principles. In order to investigate the detection limits of the instruments considered with respect to particle size, simultaneous number concentration measurements were performed for monodispersed aerosols with particle sizes ranging from 1.5 to 50 nm diameter and various compositions.The instruments considered show quite different response characteristics, apparently related to the different vapors used in the various counters to enlarge the particles to an optically detectable size. A strong dependence of the 50% cutoff diameter on the particle composition in correlation with the type of vapor used in the specific instrument was found. An enhanced detection efficiency for ultrafine hygroscopic sodium chloride aerosols was observed with water operated systems, an analogous trend was found for n-butanol operated systems with nonhygroscopic silver and tungsten oxide particles.  相似文献   

Electrical aerosol spectrometer of Tartu University     

H. Tammet  A. Mirme  E. Tamm   《Atmospheric Research》2002,62(3-4)

The electrical aerosol spectrometer (EAS) of the parallel measuring principle at Tartu University is an efficient instrument for rapid measurement of the unstable size spectrum of aerosol particles. The measuring range from 10 nm to 10 μm is achieved by simultaneously using a pair of differential mobility analyzers with two different particle chargers. The particle spectrum is calculated and measurement errors are estimated in real time by using a least-squares method. Experimental calibration ensures reliability of measurement. The instrument is well suited for continuous monitoring of atmospheric aerosol.  相似文献   

Chemical composition of stars in the galactic halo     

S. V. Ermakov  V. G. Klochkova  V. E. Panchuk  G. Zhao 《Astronomy Reports》2002,46(11):874-886

The chemical compositions of the atmospheres of six metal-poor stars are analyzed. Spectra with signal-to-noise ratios of no less than 100 and a resolution of R≈17 000 were obtained using the 6-m telescope of the Special Astrophysical Observatory of the Russian Academy of Sciences. The abundances of Li, O, α-process elements (Mg, Si, Ca, Ti), Na, K, Sc, iron-peak elements (Cr, Mn, Fe, Ni, Cu, Zn), and s-process elements (Y, Ba) are derived. The star G251-54 ([Fe/H]=?1.55, T _eff=5541 K, logg=3.58) is deficient in some elements compared to both stars with similar metallicities and the Sun. The atmosphere of G251-54 has the following elemental abundances relative to iron: [O/Fe]=+0.47, [α/Fe]≈?0.3, [Na/Fe]=?0.60, [Sc/Fe]=?0.57, [Cr, Ni, Fe]≈0, [Zn/Fe]=+0.16, [Cu/Fe]=?0.66, [Y/Fe]=?0.70, and [Ba/Fe]=?1.35. The remaining five stars have metallicities in the range ?1.6<[Fe/H]相似文献   

Discussion on "Mississippi Valley-type lead–zinc deposits through geological time: implications from recent age-dating research" by D.L. Leach, D. Bradley, M.T. Lewchuk, D.T.A. Symons, G. de Marsily, and J. Brannon (2001) Mineralium Deposita 36:711–740     

Stephen E. Kesler  Charles W. Carrigan 《Mineralium Deposita》2002,37(8):800-802

  相似文献   

Constraints on the timing of granite emplacement, deformation and metamorphism in the Shamva area, Zimbabwe     

S. Siegesmund  H. Jelsma  J. Becker  G. Davies  P. Layer  E. van Dijk  L. Kater  M. Vinyu 《International Journal of Earth Sciences》2002,91(1):20-34

In order to constrain the temporal relationship between granite (sensu lato) emplacement and metamorphism, isotope work was carried out on the minerals zircon and apatite (U-Pb), garnet (Pb-Pb) and hornblende (Ar-Ar) from wall rock samples in the Shamva area in Zimbabwe. The area, encompassing parts of the Chinamora and Murehwa batholiths and a wedge-shaped greenstone belt segment in between, is commonly quoted in the literature as an example illustrating pluton emplacement processes and deformational models for the Archean. New U-Pb dating of apatite from a boudinaged pegmatite within mafic schists in the batholith-greenstone contact zone has yielded an age of 2619 +28/-24 Ma. This age is interpreted as the best estimation of the intrusion age of this unit, depending on the assumed closure temperature, and provides an upper age limit for the syntectonic emplacement of the now gneissic granites. Pb-Pb dating of late kinematic garnets in cordierite-bearing rocks within the greenstone belt wall rocks gives an age of 2623NJ Ma. Together, this timing of relatively late, syntectonic plutonism and metamorphic mineral growth at ca. 2.62 Ga compares well with existing zircon crystallization ages for felsic volcanics (2645dž Ma, 2643NJ Ma) and post-tectonic porphyritic monzogranites (2601ᆢ Ma). Ar-Ar hornblende ages for mafic schists from different areas within the greenstone belt wall rocks range between 2621 and 2498 Ma and have been interpreted to indicate mixing between metamorphic ages and cooling ages. The data support a geological model whereby volcanism and sedimentation are associated with an early phase of regional deformation at ca. 2.64 Ga, which may have started earlier and lasted longer, and evolves into the voluminous emplacement of granites (now gneissic granites) in the batholiths at approximately 2.62 Ga. Emplacement of post-tectonic tabular monzogranites takes place at ca. 2.60 Ga.  相似文献